Citation: SHANG Jiguang, SUN Guoxin. Extraction of Fe(Ⅲ) from Aluminum Chloride[J]. Chinese Journal of Applied Chemistry, ;2018, 35(1): 75-81. doi: 10.11944/j.issn.1000-0518.2018.01.170040 shu

Extraction of Fe(Ⅲ) from Aluminum Chloride

SHANG Jiguang ,
SUN Guoxin ^,

School of Chemistry and Chemical Engineering, University of Ji'nan, Ji'nan 250022, China

Corresponding author: SUN Guoxin, chm_sungx@ujn.edu.cn
Received Date: 22 February 2017
Revised Date: 28 May 2017
Accepted Date: 28 May 2017

Fund Project: Supported by the National Natural Science Foundation of China(No.21077044)the National Natural Science Foundation of China 21077044

Figures(6)

The extraction behaviors of Fe(Ⅲ) in the preparation of high purity aluminum chloride with N, N, N', N'-tetrabutyl malonamide(TBMA), N, N, N', N'-tetraoctyl-3-oxy-glutaramide(TODGA) and methyl isobutyl ketone(MIBK) have been investigated. The results show that the extraction efficiency of Fe(Ⅲ) with TBMA or MIBK is 90% when the concentration of hydrochloric acid in the aluminum chloride solution is 4 mol/L. TODGA shows an excellent separation performance. When the concentrations of Al³⁺, Fe³⁺, and HCl are 2.0 mol/L, 0.0036 mol/L(0.2 g/L), and 1.2 mol/L, respectively, in the solution of aluminum chloride, the extraction efficiency of Fe³⁺ is more than 99.9% with 0.20 mol/L TODGA in cyclohexane or n-dodecane. After several extractions, the iron impurities in the aluminum chloride can be deeply removed and the iron content in the solution is lower than 0.01 mg/L, indicating that it has potential application in industrial production.
- high purity aluminum chloride,
- purification,
- extraction,
- Fe (Ⅲ),
- N, N, N', N'-tetraoctyl-3-oxy-glutaramide
1. [1]
  Cui L, Cheng F Q, Zhou J F. Preparation of High Purity AlCl₃·6H₂O Crystals from Coal Mining Waste Based on Iron(Ⅲ) Removal Using Undiluted Ionic Liquids[J]. Sep Purif Technol, 2016,167:45-54. doi: 10.1016/j.seppur.2016.04.046
2. [2]
  Kim, Su Tae. Method for Simultaneously Preparing High Purity Aluminum Chloride and Zinc:WO 2014208944 A1[P]. 2014-12-31.
3. [3]
  Shiroishi Akihiro, Sanuki Sumiko, Takikawa Shinichiro, et al. Method and Apparatus for Manufacturing High Purity Aluminum:JP 2004203713A[P]. 2004-07-22.
4. [4]
  GUO Yujie, LUAN Zhaokun, FAN Bin. Preparation Solution of Polymeric Aluminum Chloride with High Concentration of Al₁₃[J]. Chinese J Inorg Chem, 2007,23(1):63-69.
5. [5]
  Mishra R K, Rout P C, Sarangi K. Solvent Extraction of Fe(Ⅲ) from the Chloride Leach Liquor of Low Grade Iron ore Tailings Using Aliquat 336[J]. Hydrometallurgy, 2011,108:93-99. doi: 10.1016/j.hydromet.2011.03.003
6. [6]
  Zhu Z, Zhang W, Cheng C Y. A Synergistic Solvent Extraction System for Separating Copper from Iron in High Chloride Concentration Solutions[J]. Hydrometallurgy, 2012,113/114:155-159. doi: 10.1016/j.hydromet.2011.12.016
7. [7]
  WEI Cundi, GUO Zhaohua, DONG Hong, et al. A Method for Extracting Iron from Aluminum Chloride Slurry:CN 103435080B[P]. 2015-12-09(in Chinese).
8. [8]
  Mishra R K, Rout P C, Sarangi K. A Comparative Study on Extraction of Fe(Ⅲ) from Chloride Leach Liquor Using TBP, Cyanex 921 and Cyanex 923[J]. Hydrometallurgy, 2010,104:298-303. doi: 10.1016/j.hydromet.2010.07.003
9. [9]
  Wang X Y, Ma C, Liu J. Studies of Selective Removal of Iron(Ⅲ) from the Simulated Bauxite Hydrochloric Acid Leaching Liquor by Solvent Extraction[J]. Adv Mater Res, 2013,746:31-33. doi: 10.4028/www.scientific.net/AMR.746
10. [10]
  Li M Y, He Z M, Zhou L. Removal of Iron from Iindustrial Grade Aluminum Sulfate by Primary Amine Extraction System[J]. Hydrometallurgy, 2011,106:170-174. doi: 10.1016/j.hydromet.2010.12.018
11. [11]
  Paiva A P, Costa M C. Application of N, N'-Tetrasubstituted Malonamides to the Recovery of Iron(Ⅲ) from Chloride Solutions[J]. Hydrometallurgy, 2005,77:103-108. doi: 10.1016/j.hydromet.2004.10.014
12. [12]
  Zhu Z W, Karol Tulpatowicz, Yoko Pranolo. Fe(Ⅲ) Removal from a Synthetic Chloride Leach Solution of Nickel Laterite by N, N-Diethyldodecanamide[J]. Miner Eng, 2014,61:47-53. doi: 10.1016/j.mineng.2014.03.008
13. [13]
  LV Zijian, JIANG Yinshan, GUO Zhaohua, et al. A Method for Removing Iron from Aluminum Chloride Solution:CN101838004A[P]. 2010-09-22(in Chinese).
14. [14]
  KOU Xiaokang, GUO Zhaohua, FAN Wenmin, et al. Method for Removing Iron from Iron Containing Aluminum Chloride Solution:CN105016368A[P]. 2015-11-04(in Chinese).
15. [15]
  WU Xingke. Sublimation of Anhydrous Aluminum Chloride Under Vacuum Condition[J]. Fine Chem, 1988,5:27-30.
16. [16]
  FENG Yuebin, DAI Yongnian, LIU Yongcheng. The Production Process and Application of Anhydrous Aluminum Chloride and Aluminum Chloride Crystal[J]. Chinese J Vac Sci Technol, 2008,29(5):336-339.
17. [17]
  JIANG Tao, SU Yuanfu. Removal of Iron from Zinc Chloride Solution by Solvent Extraction[J]. J East China Inst Chem Technol, 1988,14(5):537-543.
18. [18]
  ZHAO Hongli, JU Xingsong, ZHAO Lixin. Preparation of High Purity Fe₂O₃ by Methyl Isobutyl Methanol Extraction[J]. J Hefei Univ Technol, 2006,29(9):1132-1135.
19. [19]
  YANG Quanning. Study on the Extraction of Iron and Rare Earth and Its Kinetics in Malonamide Hydrochloride[D]. Ji'nan:Ji'nan University, 2016(in Chinese).
20. [20]
  WEI Bing. Study on Kinetics of Extraction of Rare Earth Elements by TODGA in HNO₃[D]. Ji'nan:Ji'nan University, 2016(in Chinese).
21. [21]
  HANG Zhizhong, LUO Liubao, ZHANG Shiyu. Improvement on the Determination of Iron Condition by the Method of Phenanthroline[J]. Sci Technol Chem Ind, 2008,16(6):50-53.
22. [22]
  LI Sihong, GUO Youhong. An Experimental Study on the Determination of Trace Iron by Phenanthroline[J]. Strait Pharm J, 2013,25(8):82-85.
23. [23]
  GB/T 3049-2006/ISO 6685:General Method for the Determination of Iron Content of Chemical Products Industry[S].1982(in Chinese).
24. [24]
  Zhang G Z, Chen D S, Wei G Y. Extraction of Iron(Ⅲ) from Chloride Leaching Liquor with High Acidity Using Tri-n-butyl Phosphate and Synergistic Extraction Combined with Methyl Isobutyl Ketone[J]. Sep Purif Technol, 2015,150:132-138. doi: 10.1016/j.seppur.2015.07.001
25. [25]
  Cai X C, Han J X, Pang M P. Structural Effect of Diamide Extractants on the Extraction Behaviour of Fe(Ⅲ) from Hydrochloric Acid[J]. Hydrometallurgy, 2016,164:48-53. doi: 10.1016/j.hydromet.2016.05.009
26. [26]
  CAI Xucan. Study on the Synthesis and Extraction Performance of Bisamide Extractant[D]. Ji'nan:Ji'nan University, 2016(in Chinese).
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