Citation: GONG Wenpeng, CHEN Dan, YANG Shuijin. Adsorption of Methyl Violet by an Anionic Metal-Organic Framework Cu(BDC-NH₂)(4, 4'-Bipy)_0.5 (BDC=Terephthalicacid, Bipy=Bipyridine)[J]. Chinese Journal of Applied Chemistry, ;2017, 34(11): 1321-1328. doi: 10.11944/j.issn.1000-0518.2017.11.170015 shu

Adsorption of Methyl Violet by an Anionic Metal-Organic Framework Cu(BDC-NH₂)(4, 4'-Bipy)_0.5 (BDC=Terephthalicacid, Bipy=Bipyridine)

Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, College of Chemistry and Chemical Engineering, Hubei Normal University, Huangshi, Hubei 435002, China

Corresponding author: YANG Shuijin, yangshuijin@163.com
Received Date: 11 January 2017
Revised Date: 28 February 2017
Accepted Date: 14 April 2017

Fund Project: Postgraduate Innovation Scientific Research Foundation of Hubei Normal University 20160107Supported by the National Natural Science Foundation of China(No.21171053), Natural Science Foundation of Hubei Province(No.2014CFA131), Postgraduate Innovation Scientific Research Foundation of Hubei Normal University(No.20160107)Natural Science Foundation of Hubei Province 2014CFA131the National Natural Science Foundation of China 21171053

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2-Aminoterephthalic acid and 4, 4'-bipyridine ligand with Cu²⁺ ion was used to prepared three-dimensional(3D) anionic metal-organic framework, namely Cu(BDC-NH₂)(4, 4'-Bipy)_0.5(BDC=terephthalicacid, Bipy=bipyridine)by hydrothermal method. By X-ray powder diffraction pattern(XRD), Fourier transform infrared spectrum(FT-IR), scanning electron micrographs(SEM), thermogravimetry(TG), N₂ absorption-desorption experiment, the composition, structure, morphology, stability and toleration of Cu(BDC-NH₂)(4, 4'-Bipy)_0.5 were characterized. The adsorption property of the composites on methyl violet(MV) from aqueous solution was investigated. The effects of experimental parameters including the temperature, initial pH value and initial concentration of MV solution were discussed. The experiment data could be well described by the Langmuir equations with pseudo-second-order kinetic model. Thermodynamic parameters ΔG < 0, ΔH < 0 and ΔS < 0 indicate that the MV adsorption onto Cu(BDC-NH₂)(4, 4'-Bipy)_0.5 is spontaneous and endothermic, and the maximum adsorption capacity value reaches 60.09 mg/g at 193 K and pH=9, indicating that the adsorption ability of Cu(BDC)(4, 4'-Bipy)_0.5 towards dyes can be improved by using amino modification..
- three-dimensional metal organic frameworks,
- methyl violetadsorption,
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Adsorption of Methyl Violet by an Anionic Metal-Organic Framework Cu(BDC-NH2)(4, 4'-Bipy)0.5 (BDC=Terephthalicacid, Bipy=Bipyridine)

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通讯作者: 陈斌, bchen63@163.com

Adsorption of Methyl Violet by an Anionic Metal-Organic Framework Cu(BDC-NH₂)(4, 4'-Bipy)_0.5 (BDC=Terephthalicacid, Bipy=Bipyridine)