Citation: LI Shuailong, LIU Xiaoming, TANG Xinghua, FENG Jingchun, XIE Weijie. Synthesis and Luminescence Properties of Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺ Single Phase White-emitting Phosphor[J]. Chinese Journal of Applied Chemistry, ;2017, 34(10): 1186-1194. doi: 10.11944/j.issn.1000-0518.2017.10.160495 shu

Synthesis and Luminescence Properties of Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺ Single Phase White-emitting Phosphor

Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China

Corresponding author: LIU Xiaoming, xmliu2014@163.com
Received Date: 5 December 2016
Revised Date: 6 February 2017
Accepted Date: 29 March 2017

Fund Project: the Postgraduate Innovation Foundation of Nanchang Hangkong University YC2015009the Natural Science Foundation of the Jiangxi Province of China 20152ACB20011Supported by the Natural Science Foundation of the Jiangxi Province of China(No.20152ACB20011), the Postgraduate Innovation Foundation of Nanchang Hangkong University(No.YC2015009)

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A series of Dy³⁺ and/or Eu³⁺ doped Ba₃Y(PO₄)₃ phosphors was prepared via a traditional high temperature solid state reaction to investigate how the luminescent properties of Dy³⁺ doped Ba₃Y(PO₄)₃ phosphor can be tuned by co-doping Eu³⁺ ions into the host lattice. X-ray diffraction(XRD), photoluminescence and fluorescence lifetime were used to characterize the as-prepared samples. The results show that all the samples have Ba₃Y(PO₄)₃ eulytite cubic structure. Under the excitation of near-UV light, the Ba₃Y(PO₄)₃:Dy³⁺ phosphor shows cool-white emission and the Ba₃Y(PO₄)₃:Eu³⁺ phosphor presents an orange-red emission. For Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺ phosphor, warm-white emission with high color rendering index and appropriate correlated color temperature has been obtained by combining red emission of Eu³⁺with cool-white emission of Dy³⁺. The luminescence mechanism of Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺ phosphor has been tentatively proposed and the prepared Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺ phosphor has potential application in white-light-emitting-diodes(WLEDs) filed.
- Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺,
- white-emitting phosphor,
- energy transfer
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Synthesis and Luminescence Properties of Ba3Y(PO4)3:Dy3+, Eu3+ Single Phase White-emitting Phosphor

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Luminescence Properties of Ba₃Y(PO₄)₃:Dy³⁺, Eu³⁺ Single Phase White-emitting Phosphor