Advanced Search

Citation: CHEN Shijie, TANG Xiaojun, CHEN Xi, LI Yingjie, GAO Lidi, WANG Peng. Efficiency and Mechanism of Photocatalytic Oxidation of Norfloxacin in Wastewater by C/Fe-Bi2WO6[J]. Chinese Journal of Applied Chemistry, ;2017, 34(8): 936-945. doi: 10.11944/j.issn.1000-0518.2017.08.170019 shu

Efficiency and Mechanism of Photocatalytic Oxidation of Norfloxacin in Wastewater by C/Fe-Bi2WO6

  • a.

    College of Chemistry and Chemical Engineering, Qiqihar University Qiqihar, Heilongjiang 161006, China

  • b.

    School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China

  • Corresponding author: LI Yingjie, lyj310@163.com
  • Received Date: 18 January 2017
    Revised Date: 2 March 2017
    Accepted Date: 2 May 2017

    Fund Project: Research Business Special Fund of Heilongjiang Provincial Education Department No.135109209Supported by Research Business Special Fund of Heilongjiang Provincial Education Department(No.135109209)

Figures(9)

  • The C/Fe-Bi2WO6 photocatalyst was prepared by a two-step method, involving resin carbonization and hydrothermal reaction process. Comparative research on photoactivities of different catalysts was carried out. Influence of condition factors on photocatalytic oxidation degradation of norfloxacin(NOR) solution under simulated sunlight irradiation was investigated. The degrading reaction fits the first-order kinetics well under experimental conditions. After irradiation under a 500 W Xenon lamp for 60 min, NOR completely decomposed with the first order reaction rate constant(Kapp) of 0.0751 min-1 under the conditions that the initial concentration of NOR is 10 mg/L, the C/Fe-Bi2WO6 loading is 0.75 g/L, and the concentration of H2O2 is 200 mg/L at pH 7.0. The OH formation in C/Fe-Bi2WO6 photocatalytic oxidation was studied via molecular fluorescence spectrum, and the possible photocatalytic oxidation mechnasim and the degradation paths and intermediate products of NOR were proposed.
  • 加载中
    1. [1]

      Duong H A, Pham N H, Nguyen H T. Occurrence, Fate and Antibiotic Resistance of Fluoroquinolone Antibacterials in Hospital Wastewaters in Hanoi, Vietnam[J]. Chemosphere, 2008,72(6):968-973. doi: 10.1016/j.chemosphere.2008.03.009

    2. [2]

      Seifrtov M, Pena A, Lino C M. Determination of Fluoroquinolone Antibiotics in Hospital and Municipal Waste-waters in Coimbra by Liquid Chromatography with Amonolithic Column and Fluorescence Detection[J]. Anal Bioanal Chem, 2008,391(3):799-805. doi: 10.1007/s00216-008-2020-1

    3. [3]

      Golet E M, Alder A C, Giger W. Environmental Exposure and Risk Asesssment of Fluoroquinolone Antibacterial Agents in Wastewater and Fiver Water of the Glatt Valley Watershed, Switzerland[J]. Environ Sci Technol, 2002,36(17):3645-3651. doi: 10.1021/es0256212

    4. [4]

      Wang C Y, Zhang H, Li F. Degradation and Mineralization of Bisphenol A by Mesoporous Bi2WO6 under Simulated Solar Light Irradiation[J]. Environ Sci Technol, 2010,44(17):6843-6848. doi: 10.1021/es101890w

    5. [5]

      Navarro S, Fenoll J, Vela N. Removal of Ten Pesticides from Leaching Water at Pilot Plant Scale by Photo-Fenton Treatment[J]. Chem Eng J, 2011,167(1):42-49. doi: 10.1016/j.cej.2010.11.105

    6. [6]

      Sun J H, Song M K, Feng J L. Highly Efficient Degradation of Ofloxacin by UV/Oxone/Co2+ Oxidation Process[J]. Environ Sci Pollut Res, 2012,19(5):1536-1543. doi: 10.1007/s11356-011-0654-6

    7. [7]

      WEI Hong, LI Juan, LI Kebin. Degradation of Levofloxacin by Sonolysis-assisted H2O2 in Aqueous Solution[J]. China Environ Sci, 2013,33(2):257-262.

    8. [8]

      Niu H Y, Zhang D, Zhang S X. Humic Acid Coated Fe3O4 Magnetic Nanoparticles as Highly Efficient Fenton-like Catalyst for Complete Mineralization of Sulfathiazole[J]. J Hazard Mater, 2011,190(1/2/3):559-565.

    9. [9]

      Murcia-López S, Hidalgo M C, Navío J A. Photocatalytic Activity of Single and Mmixed Nanosheet-like Bi2WO6 and TiO2 for Rhodamine B Degradation under Sunlike and Visible Illumination[J]. Appl Catal A-Gen, 2012,423(1):34-41.

    10. [10]

      Liu S W, Yu J G. Cooperative Self-Construction and Enhanced Optical Absorption of Nanoplates-assembled Hierarchical Bi2WO6 Flowers[J]. J Solid State Chem, 2008,181(5):1048-1055. doi: 10.1016/j.jssc.2008.01.049

    11. [11]

      Fu H B, Zhang L W, Yao W Q. Photocatalytic Properties of Nanosized Bi2WO6 Catalysts Synthesized via a Hydrothermal Process[J]. Appl Catal B:Environ, 2006,66(1/2):100-110.

    12. [12]

      Guo Y D, Zhang G K, Gan H H. Synthesis, Characterization and Visible Light Photocatalytic Properties of Bi2WO6/Rectorite Composites[J]. J Colloid Interface Sci, 2012,369(1):323-329. doi: 10.1016/j.jcis.2011.11.066

    13. [13]

      Chen M J, Chu W. Efficient Degradation of an Antibiotic Norfloxacin in Aqueous Solution via a Simulated Solar-Light-Mediated Bi2WO6 Process[J]. Ind Eng Chem Res, 2012,51(13):4887-4893. doi: 10.1021/ie300146h

    14. [14]

      Shang M, Wang W Z, Sun S M. Efficient Visible Light-Induced Photocatalytic Degradation of Contaminant by Spindle-Like PANI/BiVO4[J]. J Phys Chem C, 2009,113(47):20228-20233. doi: 10.1021/jp9067729

    15. [15]

      Gumy D, Morais C, Bowen P. Catalytic Activity of Commercial of TiO2 Powders for the Abatement of the Bacteria(E.coli) under Solar Simulated Light:Influence of the Isoelectric Point[J]. Appl Catal B:Environ, 2006,63(1/2):76-84.

    16. [16]

      Cho I H, Zoh K D. Photocatalytic Degradation of Azo Dye(Reactive Red 120) in TiO2/UV System:Optimization and Modeling Using a Response Surface Methodology(RSM) Based on the Central Composite Design[J]. Dyes Pigm, 2007,75(3):533-543. doi: 10.1016/j.dyepig.2006.06.041

    17. [17]

      Su M H, He C, Sharma V K. Mesoporous Zinc Ferrite:Synthesis, Characterization, and Photocatalytic Activity with H2O2/Visible Light[J]. J Hazard Mater, 2012,211/212(1):95-103.

    18. [18]

      Mao Y, Schoneich C, Asmus K D. Identification of Organic Acids and Other Intermediates in Oxidative Degradation of Chlorinated Ethanes on TiO2 Surfaces En Route to Mineralization. A Combined Photocatalytic and Radiation Chemical Study[J]. J Phys Chem, 1991,95(24):10080-10089. doi: 10.1021/j100177a085

    19. [19]

      Chen S J, Li Y J, Lv R J. Preparation, Characterization of C/Fe-Bi2WO6 Nanosheet Composite and Degradation Application of Norfloxacin in Water[J]. J Nanosci Nanotechnol, 2013,13(8):5624-5630. doi: 10.1166/jnn.2013.7486

    20. [20]

      Wang D J, Xue G L, Zhen Y Z. Monodispersed Ag Nanoparticles Loaded on the Surface of Spherical Bi2WO6 Nanoarchitectures with Enhanced Photocatalytic Activities[J]. J Mater Chem, 2012,22(11):4751-4758. doi: 10.1039/c2jm14448d

    21. [21]

      An T C, Yang H, Song W H. Mechanistic Considerations for the Advanced Oxidation Treatment of Fluoroquinolone Pharmaceutical Compounds using TiO2 Heterogeneous Catalysis[J]. J Phys Chem A, 2010,114(7):2569-2575. doi: 10.1021/jp911349y

    22. [22]

      Paul T, Miller P L, Strathmann T J. Visible-Light-Mediated TiO2 Photocatalysis of Fluoroquinolone Antibacterial Agents[J]. Environ Sci Technol, 2007,41(13):4720-4727. doi: 10.1021/es070097q

  • 加载中
    1. [1]

      Minna Ma ,  Yujin Ouyang ,  Yuan Wu ,  Mingwei Yuan ,  Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093

    2. [2]

      Xin Zhou ,  Zhi Zhang ,  Yun Yang ,  Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi2MoO6 Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008

    3. [3]

      Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

    4. [4]

      Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu2O/Bi2MoO6 Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435

    5. [5]

      Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi2O3 pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256

    6. [6]

      Xiutao Xu ,  Chunfeng Shao ,  Jinfeng Zhang ,  Zhongliao Wang ,  Kai Dai . Rational Design of S-Scheme CeO2/Bi2MoO6 Microsphere Heterojunction for Efficient Photocatalytic CO2 Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031

    7. [7]

      Yi Yang ,  Xin Zhou ,  Miaoli Gu ,  Bei Cheng ,  Zhen Wu ,  Jianjun Zhang . S型ZnO/CdIn2S4光催化剂制备H2O2偶联苄胺氧化的超快电子转移飞秒吸收光谱研究. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-. doi: 10.1016/j.actphy.2025.100064

    8. [8]

      Xuejiao Wang ,  Suiying Dong ,  Kezhen Qi ,  Vadim Popkov ,  Xianglin Xiang . Photocatalytic CO2 Reduction by Modified g-C3N4. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005

    9. [9]

      Qianqian Liu ,  Xing Du ,  Wanfei Li ,  Wei-Lin Dai ,  Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb2O6/Nitrogen-Enriched C3N5 S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016

    10. [10]

      Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

    11. [11]

      Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014

    12. [12]

      Zijian Jiang ,  Yuang Liu ,  Yijian Zong ,  Yong Fan ,  Wanchun Zhu ,  Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101

    13. [13]

      Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO2 reduction performance of Z-scheme Ag-Cu2O/BiVO4 photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434

    14. [14]

      Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH2 supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317

    15. [15]

      Zhuoyan Lv ,  Yangming Ding ,  Leilei Kang ,  Lin Li ,  Xiao Yan Liu ,  Aiqin Wang ,  Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuOx/TiO2 Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015

    16. [16]

      Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346

    17. [17]

      Zhiquan Zhang ,  Baker Rhimi ,  Zheyang Liu ,  Min Zhou ,  Guowei Deng ,  Wei Wei ,  Liang Mao ,  Huaming Li ,  Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO2 Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029

    18. [18]

      . 

      CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化

      . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.

    19. [19]

      Jianyin He ,  Liuyun Chen ,  Xinling Xie ,  Zuzeng Qin ,  Hongbing Ji ,  Tongming Su . ZnCoP/CdLa2S4肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030

    20. [20]

      Xianghai Song ,  Xiaoying Liu ,  Zhixiang Ren ,  Xiang Liu ,  Mei Wang ,  Yuanfeng Wu ,  Weiqiang Zhou ,  Zhi Zhu ,  Pengwei Huo . 氮掺杂显著提升BiOBr光催化还原CO2性能研究. Acta Physico-Chimica Sinica, 2025, 41(6): 100055-. doi: 10.1016/j.actphy.2025.100055

Get Citation
PDF
XML
Metrics
  • PDF Downloads(4)
  • Abstract views(1362)
  • HTML views(215)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return