Citation: LI Jianfa, CHEN Xiaoli. Synthesis, Structure and Properties of Binuclear Zinc Complex[Zn(dna)(phen)(H₂O)][J]. Chinese Journal of Applied Chemistry, ;2017, 34(8): 912-917. doi: 10.11944/j.issn.1000-0518.2017.08.160462 shu

Synthesis, Structure and Properties of Binuclear Zinc Complex[Zn(dna)(phen)(H₂O)]

LI Jianfa ^b ,
CHEN Xiaoli ^a,,

a.
Shaanxi Key Laboratory of Chemical Reaction Engineering, Department of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
b.
Department of Chemical Engineering, Yulin Vocational and Technical College, Yulin, Shaanxi 719000, China

Corresponding author: CHEN Xiaoli, chenxiaoli003@163.com
Received Date: 16 November 2016
Revised Date: 27 December 2016
Accepted Date: 12 February 2017

Fund Project: Yulin Science and Technology Project No.GY13-23the National Natural Science Foundation of China No.21101133Supported by the National Natural Science Foundation of China(No.21101133), Yulin Science and Technology Project(No.GY13-23)

Figures(6)

A new complex[Zn(dna)(phen)(H₂O)] based on 5, 5'-dithiobis(2-nitrobenzoic acid)(H₂dna) and 1, 10-phenanthroline(phen), has been hydrothermally synthesized and structurally characterized by elemental analysis, Fourier transform infrared spectrometer, X-ray single crystal diffraction and powder X-ray diffraction. Crystal structural analysis reveals that it crystallizes in monoclinic, space group P2₁/n, a=1.5312(3) nm, b=1.16054(18) nm, c=1.5609(3) nm, β=110.451(2)°, V=2.5990(7) nm³, Z=4. There is a binuclear ring structure in the complex, and the neighboring binuclear rings are linked into 1D supramolecular chain through hydrogen bonding interaction. The adjacent supramolecular chains are further interconnected by S‥‥O and C-H‥‥π weak interactions resulting a 3D supramolecular structure. The complex after dehydration remains relatively stable until 245~450℃. Then ligands begin to decompose, which shows good thermal stability. The complex displays a strong fluorescence emission maximum at ca. 440 nm upon excitation at 280 nm. The emission peaks of H₂dna ligand and the complex are similar. Compared with H₂dna ligand, the fluorescence intensity of complex is significantly enhanced.
- zinc complex,
- crystal structure,
- hydrothermal synthesis
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Structure and Properties of Binuclear Zinc Complex[Zn(dna)(phen)(H2O)]

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Structure and Properties of Binuclear Zinc Complex[Zn(dna)(phen)(H₂O)]