Citation: CHEN Peizhen, LIU Ruilai, ZHAO Jinyun, RAO Ruiye. Fabrication of Succinic Acid Anhydride Grafted Cellulose Nanofiber Membrane and Its Adsorption of Heavy Metal Ions[J]. Chinese Journal of Applied Chemistry, ;2017, 34(8): 891-898. doi: 10.11944/j.issn.1000-0518.2017.08.160299 shu

Fabrication of Succinic Acid Anhydride Grafted Cellulose Nanofiber Membrane and Its Adsorption of Heavy Metal Ions

CHEN Peizhen ^a,, ,
LIU Ruilai ^a,b ,
ZHAO Jinyun ^a ,
RAO Ruiye ^a

a.
Fujian Provincial Key laboratory of Eco-Industrial Green Technology, College of Ecological and Resources Engineering, Wuyi University, Wuyishan, Fujian 354300, China
b.
Fujian Provincial Key Laboratory of Polymer Materials, College of Material Science and Engineering, Fujian Normal University, Fuzhou 350007, China

Corresponding author: CHEN Peizhen, npcpz@163.com
Received Date: 22 July 2016
Revised Date: 20 September 2016
Accepted Date: 14 October 2016

Fund Project: JK Project of Fujian Educational Bureau No 2014052the National Natural Science Foundation of China No.51406141Natural Science Foundation of Nanping Science and Technology Bureau No.2011DJ10JK Project of Fujian Educational Bureau No.2012055Supported by the National Natural Science Foundation of China(No.51406141), JK Project of Fujian Educational Bureau(No 2014052, No.2012055), Natural Science Foundation of Nanping Science and Technology Bureau(No.2011DJ10)

Figures(8)

Triacetate cellulose(TCA) porous nanofiber membranes(Cell) with diameter of (110±28) nm were successfully prepared by thermally induced phase separation. Succinic acid anhydride grafted cellulose(Cell-g-SAA) nanofiber membranes were obtained through hydrolyzation and grafting of TCA nanofibers. The Cell and Cell-g-SAA membranes were used for the adsorption of Cu²⁺ and Pb²⁺. The adsorption kinetics and thermodynamics were studied and found to fit pseudo-second-order and Langmuir model. Compared with cellulose membranes, the max adsorption capacity of Cell-g-SAA membranes for Cu²⁺ and Pb²⁺ increases from 51.73 and 34.29 mg/g to 116.41 and 51.73 mg/g, respectively. The adsorptions of Cu²⁺ and Pb²⁺ on the Cell and Cell-g-SAA membranes are more agreeable with monolayer adsorption mode via mainly chemical interactions.
- succinic acid anhydride,
- grafting,
- nanofibers,
- heavy metal,
- adsorption
1. [1]
  Fu F L, Wang Q. Removal of Heavy Metal Ions from Wastewaters:A Review[J]. J Environ Manage, 2011,92(3):407-418. doi: 10.1016/j.jenvman.2010.11.011
2. [2]
  Meena A K, Mishra G K, Rai P K. Removal of Heavy Metal Ions from Aqueous Solutions Using Carbon Aerogel as an Adsorbent[J]. J Hazard Mater, 2005,122(1):161-170.
3. [3]
  Yang S, Fu S, Liu H. Hydrogel Beads Based on Carboxymethyl Cellulose for Removal Heavy Metal Ions[J]. J Appl Polym Sci, 2011,119(2):1204-1210. doi: 10.1002/app.v119:2
4. [4]
  CHEN Zhao'an, YE Zhen, CHEN Yong. Studies on Preparation of Cellulose Diacetate Membrane for Microfiltration by Two-step Phase Separation Method[J]. Membr Sci Technol, 2003,23(3):11-15.
5. [5]
  HUANG Ye, SI Youyin. Preparation of Cellulose Acetate Microsphere and Its Adsorption Properties and Heavy Metals[J]. Technol Water Treat, 2013,39(2):42-45.
6. [6]
  Tian Y, Wu M, Liu R G. Electrospun Membrane of Cellulose Acetate for Heavy Metal Ion Adsorption in Water Treatment[J]. Carbohydr Polym, 2013,83(2):743-748.
7. [7]
  Stephen M, Catherine N, Brenda M. Oxolane-2, 5-dione Modified Electrospun Cellulose Nanofibers for Heavy Metals Adsorption[J]. J Hazard Mater, 2011,192(2):922-927. doi: 10.1016/j.jhazmat.2011.06.001
8. [8]
  Liu R L, Ye H Y, Xiong X P. Fabrication of TiO₂/ZnO Composite Nanofibers by Electrospinning and Their Photocatalytic Property[J]. Mater Chem Phys, 2010,121(3):432-439. doi: 10.1016/j.matchemphys.2010.02.002
9. [9]
  Ye S, Zhang D, Liu H. ZnO Nanocrystallites/Cellulose Hybrid Nanofibers Fabricated by Electrospinning and Solvothermal Techniques and Their Photocatalytic Activity[J]. J Appl Polym Sci, 2011,121(3):1757-1764. doi: 10.1002/app.33822
10. [10]
  Bhattacharyya R, Ray S K. Kinetic and Equilibrium Modeling for Adsorption of Textile Dyes in Aqueous Solutions by Carboxymethyl Cellulose/Poly(acrylamide-co-hydroxyethy methacrylate) Semi-interpenetrating Network Hydrogel[J]. Polym Eng Sci, 2013,53(11):2439-2453. doi: 10.1002/pen.v53.11
11. [11]
  Li H, Bi S, Liu L. Separation and Accumulation of Cu(Ⅱ), Zn(Ⅱ) and Cr(Ⅵ) from Aqueous Solution by Magnetic Chitosan Modified with Diethylenetriamine[J]. Desalination, 2011,278(2):397-404.
12. [12]
  Yang G, Han H, Du C. Facile Synthesis of Melamine-based Porous Polymer Networks and Their Application for Removal of Aqueous Mercury Ions[J]. Polymer, 2010,51(26):6193-6202. doi: 10.1016/j.polymer.2010.10.052
13. [13]
  Liu X, Hu Q, Fang Z. Magnetic Chitosan Nanocomposites:A Useful Recyclable Tool for Heavy Metal Ion Removal[J]. Langmuir, 2008,25(1):3-8.
14. [14]
  ZHAO Jinyun, JIANG Huihua, CHEN Liangbi. Fabricaiton of Porous Acteate Cellulose Nanofibers and Their Adsorptivity[J]. Chinese J Environ Eng, 2015,9(12):5801-5806. doi: 10.12030/j.cjee.20151225
15. [15]
  El-Reash Y G A, Otto M, Kenawy I M. Adsorption of Cr(Ⅵ) and As(Ⅴ) Ions by Modified Magnetic Chitosan Chelating Resin[J]. Int J Biol Macromol, 2011,49(4):513-522. doi: 10.1016/j.ijbiomac.2011.06.001
16. [16]
  Liu J, Ma Y, Xu T. Preparation of Zwitterionic Hybrid Polymer and Its Application for the Removal of Heavy Metal Ions from Water[J]. J Hazard Mater, 2010,178(1):1021-1029.
17. [17]
  Yan G, Viraraghavan T. Heavy Metal Removal in a Biosorption Column by Immobilized M.Rouxii Biomass[J]. Bioresour Technol, 2001,78(3):243-249. doi: 10.1016/S0960-8524(01)00020-7
18. [18]
  Na C K, Park H J. Defluoridation from Aqueous Solution by Lanthanum Hydroxide[J]. J Hazard Mater, 2010,183(1):512-520.
19. [19]
  HU Jiapeng, ZHAO Shengyu, XIAO Liying. Ammonia-Nitrogen Adsorption on Coagulation Sludge Pretreated by High-Temperature[J]. CIESC J, 2013,64(11):4105-4113.
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