Citation: HU Xiaoshuang, WANG Yanmei, WANG Yan, LI Yanying, YANG Yanhong, CHI Yuxian, JIN Jing, NIU Shuyun. Syntheses, Structures and Near Infrared Luminescence of a Series of Ln (Ⅲ) Coordination Polymers[J]. Chinese Journal of Applied Chemistry, ;2017, 34(4): 486-488. doi: 10.11944/j.issn.1000-0518.2017.04.160366 shu

Syntheses, Structures and Near Infrared Luminescence of a Series of Ln (Ⅲ) Coordination Polymers

School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Corresponding author: CHI Yuxian, yxchi@lnnu.edu.cn
Received Date: 12 September 2016
Revised Date: 10 October 2016
Accepted Date: 5 December 2016

Fund Project: the National Natural Science Foundation of China 21133005Scientific Research Project of Liaoning Provincial University L2011193Scientific Research Project of Liaoning Provincial University L2014424

Figures(4)

Five novel Ln (Ⅲ) coordination polymers, {[Ln₂(1, 3-bdc)₃(H₂O)₄](DMF (H₂O}_n(Ln=Pr (1), Nd (2), Gd (3)) and {[Ln₄(1, 3-bdc)₆(H₂O)₄(DMF)](DMF (2H₂O}_n(Ln=Er (4), Ho (5))(1, 3-bdc=isophthalic acid, DMF=N, N-dimethyl formamide), have been synthesized by hydrothermal methods and characterized by single-crystal X-ray diffraction, infrared spectroscopy (IR), ultraviolet-visible-near infrared (UV-Vis-NIR) and fluorescence spectroscopy. The results show that coordination polymers 1 to 3 are isomorphous and crystallized in the monoclinic with space group P2(1)/n, and coordination polymers 4 and 5 are isomorphous and belong to the triclinic system with space group P-1. Polymers present multidimensional structures due to versatile coordination modes of 1, 3-bdc^2- in crystals. Except for coordination polymer 4, others exhibit NIR luminescent properties that are associated with UV-Vis-NIR absorption spectra.
- Ln (Ⅲ) coordination polymer,
- crystal structure,
- near infrared luminescence
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