Citation: CHENG Hongyu, HU Xiaoxia, ZHAO Lin, WANG Fang, LI Rong, XING Yanjun. Microwave-assisted Preparation and the Visible-light Photocatalytic Properties of Nickel Zirconium Phosphate[J]. Chinese Journal of Applied Chemistry, ;2017, 34(4): 414-422. doi: 10.11944/j.issn.1000-0518.2017.04.160295 shu

Microwave-assisted Preparation and the Visible-light Photocatalytic Properties of Nickel Zirconium Phosphate

CHENG Hongyu ^a ,
HU Xiaoxia ^a ,
ZHAO Lin ^a ,
WANG Fang ^b ,
LI Rong ^c ,
XING Yanjun ^a,*,,

a.
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
b.
School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hu'nan 421001, China
c.
National Engineering Research Center for Dyeing & Finishing of Textiles, Donghua University, Shanghai 201620, China

Corresponding author: XING Yanjun, yjxing@dhu.edu.cn
Received Date: 15 July 2016
Revised Date: 12 September 2016
Accepted Date: 9 November 2016

Fund Project: Supported by the National Science and Technology Ministry No.2012BAK30B03Fundamental Research Funds for the Central Universities No.2232013A3-05, No.CUSF-DH-D-2014036

Figures(8)

ZrOCl₂, NiCl₂ and NaH₂PO₄ were used as raw materials to prepare nickel zirconium phosphate (NiZr (PO₄)₂·4H₂O, NiZrPs) by a microwave-assisted method at lower temperature and atmospheric pressure. The influence of three different kinds of surfactants on the phase, particle size and morphology of NiZrPs was studied. The results show that the addition of surfactant can reduce the particle size. Compared with sodium dodecyl sulfate (SDS), polyvinylpyrrolidone K30(PVP-K30) and hexadecyltrimethyl ammonium bromide (CTAB) can restrain the growth of particles more efficiently, resulting in a smaller average particle size. Moreover, the visible-light photocatalytic property of NiZrPs was studied based on methylene blue (MB) as a simulated wastewater. As a result, the visible-light apparent dye decolorization efficiency of NiZrP prepared with PVP-K30 is 49.0% which is much higher than that of the other two products. This work developed a new method for the preparation and application of new type zirconium phosphate complex salt.
- nickel zirconium phosphate,
- microwave-assisted preparation,
- surfactant,
- visible-light photocatalysis,
- dye degradation
1. [1]
  Lei Y Q, Wang G H, Guo P R. Silver Phosphate Based Plasmonic Photocatalyst:Highly Active Visible-Light-Enhanced Photocatalytic Property and Photosensitized Degradation of Pollutants[J]. Funct Mater Lett, 2012,5(4):1250047(1)-1250047(5). doi: 10.1142/S1793604712500476
2. [2]
  Wu Q, Wang P F, Niu F T. Facile Synthesis of Ag₃PO₄/AlPO₄-5 Composite Photocatalyst with Enhanced Visible-Light-Responded Photocatalytic Activities[J]. J Taiwan Inst Chem Eng, 2016,60:532-537. doi: 10.1016/j.jtice.2015.09.018
3. [3]
  HU Xiaoxia, ZHAO Lin, ZHAO Shuyu. Microwave-Assisted Preparation of Copper Hydroxyphosphate and Characterization of Photocatalysis under Visible Light[J]. J Inorg Mater, 2016,31(4):421-426.
4. [4]
  YU Ruimin, JI Lei, WANG Haoren. Hydrothermal Synthesis of Phosphate and Its Photocatalytic Performance Evaluation[J]. Chem Res Appl, 2015,27(8):1104-1111.
5. [5]
  LI Xinling, HU Xiaoxia, LI Rong. Preparation and Characterization of Zirconium Phosphate by Microwave-Assisted Method[J]. Guangzhou Chem Ind, 2014,42(24):56-60. doi: 10.3969/j.issn.1001-9677.2014.24.023
6. [6]
  Yi Z G, Ye J H, Kikugawa N. An Orthophosphate Semiconductor with Photo Oxidation Propertie under Visible-Light Irradiation[J]. Nat Mater, 2010,9(7):559-564. doi: 10.1038/nmat2780
7. [7]
  Pan C S, Zhu Y F. New Type of BiPO₄ Oxy-Acid Salt Photocatalyst with High Photocatalytic Activity on Degradation of Dye[J]. Environ Sci Technol, 2010,44(14):5570-5574. doi: 10.1021/es101223n
8. [8]
  Rhajipour A, Karimi H, Masti A. Acetylation of Alcohols and Phenolsunder Solvent-Free Conditions Using Iron Zirconium Posphate[J]. Chinese J Catal, 2015,35(12):1982-1989.
9. [9]
  Piccirillo C, Dunnill C W, Pullar R C. Calcium Phosphate-Based Materials of Natural Origin Sowing Photocatalytic Activity[J]. J Mater Chem A, 2013,1(21):6452-6461. doi: 10.1039/c3ta10673j
10. [10]
  Hajipour A R, Karimi H, Koohi A. Selective Oxidation of Alcohols Over Nickel Zirconium Phosphate[J]. Chinese J Catal, 2015,35(7):1109-1116.
11. [11]
  Rajesh K, Mukundan P, Krishna P P. High-Surface-Area Nanocrystalline Cerium Phosphate Through Aqueous Sol-Gel Route[J]. Chem Mater, 2004,16(14):2700-2705. doi: 10.1021/cm0499139
12. [12]
  Sun Z G, Liu Z M, Xu L. Hydrothermal Synthesis and Characterization of Microporous Crystals of Trivalent Metal-Containing Zirconium Phosphates[J]. Catal Today, 2004,93/94/95(3):639-643.
13. [13]
  Afanasiev P. Preparation of Mixed Phosphates in Molten Alkali Metal Nitrates[J]. Chem Mater, 1999,11(8):1999-2007. doi: 10.1021/cm9807440
14. [14]
  Cao Z, Sun L X, Cao X Q. Synthesis and Characterization of the Layered Zirconium Phosphate and Its Intercalation Study[J]. Adv Mater Res, 2011,233/234/235(5):1809-1813.
15. [15]
  Zhang Q R, Du W, Pan B C. A Comparative Study on Pb²⁺, Zn²⁺ and Cd²⁺ Sorption onto Zirconium Phosphate Supported by a Cation Exchanger[J]. J Hazard Mater, 2008,152(2):469-475. doi: 10.1016/j.jhazmat.2007.07.012
16. [16]
  Kappe C O, Stadler A. Microwaves in Organicand Medicinal Chemistry[M]. WileyVCH:Weinheim, 2005.
17. [17]
  Su W, Li R, Xing Y J. Preparation and Characterization of Hollow Carambola-Shaped Silver Sulfide Microspheres Using a Microwave-Assisted Template-Free Method[J]. Chinese Chem Lett, 2016,27(3):451-453. doi: 10.1016/j.cclet.2015.12.009
18. [18]
  Myers H P. Introductory Solid State Physics[M]. London:Taylor & Francis, 2002.
19. [19]
  GU Zhihua, WANG Huifeng, WANG Houzhi. Influence of Different Surface Active Agents on the Preparation of Nanometer ZnO/ZrO₂ and the Desulphurization Properties[J]. J Synth Cryst, 2007,36(3):642-645.
20. [20]
  Matienzo L J, Yin L I, Grim S O. X-Ray Photoelectron Spectroscopy of Nickel Compounds[J]. Inorg Chem, 1973,12(12):2762-2769. doi: 10.1021/ic50130a005
21. [21]
  Guerrero-Ruiz A, Rodriguez-Ramos I, Fierro J L G. Catalytic Activity of Layered α-(Tin or Zirconium) Phosphates and Chromia-Pillared Derivatives for Isopropyl Alcohol Decomposition[J]. Appl Catal A, 1992,92(2):81-92. doi: 10.1016/0926-860X(92)80308-Y
22. [22]
  Franke R, Chasse T, Streubel P. Auger Parameters and Relaxation Energies of Phosphorus in Solid Compounds[J]. J Electron Spectrosc, 1991,56(4):381-388. doi: 10.1016/0368-2048(91)85035-R
23. [23]
  Shi L J, Li Z, Yu L. Effects of Surfactants and Lipids on the Preparation of Solid Lipid Nanoparticles Using Double Emulsion Method[J]. J Dispersion Sci Technol, 2011,32(32):254-259.
24. [24]
  LIU Xin, LV Xiuyang, CAI Lei. Review on Water-Tolerant Solid Acid Catalysts[J]. Mod Chem, 2004,24(S1):14-17.
25. [25]
  Joseph N A, Ho S Y, Hwan O T. PVP Assisted Synthesis of Hydroxyapatite Nanorods with Tunable Aaspect Ratio and Bioactivity[J]. J Nanomater, 2015,2015:621785(1)-621785(9).
26. [26]
  LOU Xiangdong, WANG Tianxi, LIU Shuangzhi. Study on the Photocatalytic Degradation of Reactive Dyes by Fe₂O₃[J]. Tech Equip Environ Pollut Control, 2006,7(4):97-99.
27. [27]
  Liu X, Wu X L, Long Z. Photodegradation of Imidacloprid in Aqueous Solution by the Metal-Free Catalyst Graphitic Carbon Nitride Using an Energy-Saving Lamp[J]. J Agric Food Chem, 2015,63(19):4754-4760. doi: 10.1021/acs.jafc.5b01105
1. [1]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
2. [2]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
3. [3]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
4. [4]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
5. [5]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
6. [6]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
7. [7]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
8. [8]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
9. [9]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
10. [10]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
11. [11]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
12. [12]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
13. [13]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
14. [14]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
15. [15]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
16. [16]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . 调节O,S共掺杂C₃N₄中的活性氧生成以促进光催化降解微塑料. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-. doi: 10.1016/j.actphy.2025.100052
17. [17]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
18. [18]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
19. [19]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
20. [20]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(446)
HTML views(53)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142