Citation: LI Jiting, HU Bingcheng, YU Chuanming, LIU Cheng. Synthesis and Properties of Pyridyl Dithienylethene Axially Coordinated to Mn (Ⅱ)-Porphyrin[J]. Chinese Journal of Applied Chemistry, ;2017, 34(4): 402-407. doi: 10.11944/j.issn.1000-0518.2017.04.160291 shu

Synthesis and Properties of Pyridyl Dithienylethene Axially Coordinated to Mn (Ⅱ)-Porphyrin

School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Corresponding author: HU Bingcheng, hubc@mail.njust.edu.cn
Received Date: 13 July 2016
Revised Date: 23 August 2016
Accepted Date: 10 October 2016

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Organic photochromic materials have bottleneck problems including low photon yield, poor fatigue resistance and destruction of recorded information after read-out in practical application. In this paper the pyridyl dithienylethene axially coordinated to Mn (Ⅱ)-porphyrin was synthesized by 1-(5-chloro-2-methylthien-3-yl)-2-[5-pyridyl-2-methylthien-3-yl]cyclopentene via halogenation, Friedel-Crafts acylation, McMurry coupling, Suzuki coupling by using 2-methyl-thiophene as the starting material coordinating with Mn (Ⅱ)-porphyrin. Photochromic properties and fatigue resistance of the target compound were investigated by ultraviolet-visible (UV-Vis) spectrum, and the function of nondestructive readout was also researched by fluorescence spectrum. The experimental results indicate that the target compound possesses good photochromic properties and fatigue resistance, and the "write-read-erase" process can be achieved by using the light of 254 nm, 490 nm, and 550 nm, respectively, without concomitant loss of data which is expected to be used in binary storage devices.
- pyridyl dithienylethene,
- Mn (Ⅱ)-porphyrin,
- photochromism,
- fatigue resistance,
- nondestructive readout
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