Citation: TANG Xiaohua, PAN Jiao, KANG Xiaoxiao, ZHA Fei, ZHOU Yousan, NIU Keyan. Amberlyst-15 Catalyzed Oxidation of Butanone to Methyl Ethyl Ketone Peroxide[J]. Chinese Journal of Applied Chemistry, ;2017, 34(4): 408-413. doi: 10.11944/j.issn.1000-0518.2017.04.160287 shu

Amberlyst-15 Catalyzed Oxidation of Butanone to Methyl Ethyl Ketone Peroxide

TANG Xiaohua ^a ,
PAN Jiao ^a ,
KANG Xiaoxiao ^a ,
ZHA Fei ^a,*,, ,
ZHOU Yousan ^b ,
NIU Keyan ^b

a.
College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, China
b.
Lanzhou Auxiliary Agent Plant, Lanzhou 730070, China

Corresponding author: ZHA Fei, zhafei@nwnu.edu.cn
Received Date: 12 July 2016
Revised Date: 30 August 2016
Accepted Date: 8 October 2016

Fund Project: Supported by the National Natural Science Foundation of China No.21161017

Figures(3)

Ion exchange resin, as a new green catalyst, can replace traditional catalysts used in series of organic reaction. In this paper, methyl ethyl ketone peroxides (MEKP) were synthesized by oxidation of methyl ethyl ketone using 30% hydrogen peroxide as oxidant, dibutyl phthalate as diluent and Amberlyst-15 as catalyst. Under the conditions that the molar ratio of hydrogen peroxide to methyl ethyl ketone is of 1.0, mass ratio of Amberlyst-15 to methyl ethyl ketone is of 0.06, the reaction temperature at 27℃ and reaction time for 55 min, the yield of methyl ethyl ketone peroxide can reach 86%, and activated oxygen content is 12.9%. Amberlyst-15 still keep good stability after recycling for 8 times. This study shows that Amberlyst-15 has the advantages of high catalytic activity, good repeated utilization, cleaning and low corrosivity. The method developed can be a new way for the production of MEKP.
- amberlyst-15,
- butanone,
- methyl ethyl ketone peroxide,
- catalysis oxidation
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