Citation: XIE Dandan, YAN Liang, YIN Yuli, ZHANG Zhaohui, WANG Jing. Preparation and Application of Magnetic Multi-ion Imprinted Polymers Based on Multiwalled Carbon Nanotubes[J]. Chinese Journal of Applied Chemistry, ;2017, 34(4): 456-463. doi: 10.11944/j.issn.1000-0518.2017.04.160268 shu

Preparation and Application of Magnetic Multi-ion Imprinted Polymers Based on Multiwalled Carbon Nanotubes

XIE Dandan ^a ,
YAN Liang ^a ,
YIN Yuli ^a,b ,
ZHANG Zhaohui ^a,b,c,*,, ,
WANG Jing ^a,b

a.
College of Chemistry and Chemical Engineering, Jishou University, Jishou, Hu'nan 416000, China
b.
Key Laboratory of Mineral Cleaner Production and Exploit of Green Functional Materials in Hu'nan Province, Jishou University, Jishou, Hu'nan 416000, China
c.
State Key Laboratory of Chemo Biosensing and Chemometrics, Hu'nan University, Changsha 410082, China

Corresponding author: ZHANG Zhaohui, zhaohuizhang77@163.com
Received Date: 29 June 2016
Revised Date: 9 October 2016
Accepted Date: 16 November 2016

Fund Project: the National Natural Science Foundation of China 21267010Open Foundation of Hunan Province Laboratory of Mineral Cleaner Production and Green Functional Materials, and Science MCPEGFM-200602the National Natural Science Foundation of China 21565014

Figures(8)

Novel magnetic multi-ion imprinted polymers (MⅡPs) were synthesized using magnetic multi-walled carbon nanotubes as the supporting materials, Co²⁺, Cu²⁺ and Cd²⁺ as the multi-template and dopamine as the functional monomer. The MⅡPs were characterized with Fourier-transform infrared spectrometry, transmission electron microscope, scanning electron microscope and vibrating sample magnetometer in details. Adsorption performance of the MⅡPs was investigated by magnetic solid phase extraction and atomic absorption spectroscopy. The results reveal that the MⅡPs have outstanding magnetic property, high adsorption capacity, high selectivity and fast binding kinetics toward Cu²⁺, Co²⁺and Cd²⁺ with the maximum adsorption capacity of 46.08 mg/g, 36.35 mg/g and 30.65 mg/g, respectively. Combined with atomic absorption spectroscopy, MⅡPs were successfully used to separate and enrich Cu²⁺, Co²⁺and Cd²⁺ in real sludge samples with the enrichment factor of 18.6, 13.4 and 10.9, respectively.
- magnetic multi-ion imprinted polymers,
- polydopamine,
- heavy metal ion,
- magnetic solid phase extraction
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Application of Magnetic Multi-ion Imprinted Polymers Based on Multiwalled Carbon Nanotubes

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com