Citation: ZHAO Liping, CAI Xingnan, WANG Hongyu, QI Li. Molybdenum Trioxide: A New Type Negative Electrode Material for Electric Energy Storage Devices Using Na⁺-based Organic Electrolytes[J]. Chinese Journal of Applied Chemistry, ;2017, 34(3): 262-268. doi: 10.11944/j.issn.1000-0518.2017.03.160239 shu

Molybdenum Trioxide: A New Type Negative Electrode Material for Electric Energy Storage Devices Using Na⁺-based Organic Electrolytes

ZHAO Liping ^a ,
CAI Xingnan ^a ,
WANG Hongyu ^b ,
QI Li ^b,*,,

a.
Liaoning Shihua University, Fushun, Liaoning 113001, China
b.
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China

Corresponding author: QI Li, qil@ciac.ac.cn
Received Date: 7 June 2016
Revised Date: 11 July 2016
Accepted Date: 2 August 2016

Fund Project: Supported by the National Basic Research Program of China No.2011CB935702, No.2012CB932800Talent Scientific Research Fund of LSHU No.2016XJJ-020the National Natural Science Foundation of China No.21173206

Figures(8)

Owing to the shortage of lithium resources, we investigated the sodium-ion storage device using MoO₃ as the negative electrode materials. MoO₃ was prepared through a simple method and characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM) and transmission electron microscopy(TEM). MoO₃ was used as the negative electrode materials for electric energy storage devices using Na⁺-based organic electrolytes. The charge storage mechanism at the MoO₃ negative electrode was investigated by cyclic voltammetry and galvanostatic charge-discharge tests. A new type of electric energy storage devices was constructed with MoO₃ as negative materials and activated carbon(or graphite) as positive materials. The electrochemical properties were studied in 1 mol/L NaPF₆-propylene carbonate(PC). The MoO₃/AC and MoO₃/graphite devices owns the voltage ranges of 0~3.2 V and 0~3.5 V, energy densities of 31.6 Wh/kg and 53 Wh/kg, respectively. The long-cycling stabilities of both devices are superior to the AC/AC symmetric capacitor obviously. This kind of energy storage devices would be a good substitute for lithium-ion batteries.
- molybdenum trioxide,
- activated carbon,
- graphite,
- negative electrode materials,
- electric energy storage devices
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Molybdenum Trioxide: A New Type Negative Electrode Material for Electric Energy Storage Devices Using Na+-based Organic Electrolytes

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通讯作者: 陈斌, bchen63@163.com

Molybdenum Trioxide: A New Type Negative Electrode Material for Electric Energy Storage Devices Using Na⁺-based Organic Electrolytes