Citation: TAN Yuhui, GU Zhifeng, LIU Yi, YANG Changshan, WANG Bin, TANG Yunzhi. Synthesis, Structure and Fluorescence Properties of Manganese(Ⅱ) Complex Based on 3-Carboxyl-1,2,4-triazole[J]. Chinese Journal of Applied Chemistry, ;2017, 34(3): 354-360. doi: 10.11944/j.issn.1000-0518.2017.03.160210 shu

Synthesis, Structure and Fluorescence Properties of Manganese(Ⅱ) Complex Based on 3-Carboxyl-1,2,4-triazole

School of Materials and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China

Corresponding author: TANG Yunzhi, tyxcn@163.com
Received Date: 20 May 2016
Revised Date: 25 August 2016
Accepted Date: 28 September 2016

Figures(9)

In order to investigate the properties of 3-carboxyl-1,2,4-triazole complexes, a novel complex,[Mn(C₃H₂N₃O₂)₂(H₂O)₂], was synthesized by the hydrothermal method. The properties of the complex were characterized by Fourier transform infrared spectroscopy(IR), element analysis, thermal gravimetric anlysis(TGA) and powder X-ray diffraction(PXRD). The single crystal X-ray analysis reveals that the complex is a unique single-core structure and belongs to the monoclinic crystal system in space group P21/c. The coordination number of Mn^Ⅱ is six. The Mn^Ⅱ atom is located on an inversion centre. Each Mn^Ⅱ atom is coordinated by two O atoms and two N atoms from two 3-carboxyl-1,2,4-triazole anions and two coordinated water molecules to form a slightly distorted octahedral geometry. The discrete molecules of the complex are furthermore linked, resulting in a three-dimensional network structure through extensive intermolecular hydrogen bonds and π-π interactions. Solid fluorescence of the complex shows an emission peak at 517 nm. Compared with the ligand, there is a 7 nm blue shift. The research provides a reference for exploiting new metal-organic complex fluorescent materials.
- hydrothermal method,
- carboxyl-triazole,
- fluorescence properties
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