Citation: ZHU Danyang, JIN Rui, WU Zuolin, HAN Baochun, YANG Zhenghua, ZHANG Chunhua. Effect of the Degree of Chemical Imidization on the Positive Photosensitive Polyimide[J]. Chinese Journal of Applied Chemistry, ;2017, 34(3): 276-281. doi: 10.11944/j.issn.1000-0518.2017.03.160195 shu

Effect of the Degree of Chemical Imidization on the Positive Photosensitive Polyimide

a.
Polymer Composites Engineering Laboratory, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, China
b.
Global Energy Interconnection Research Institue, Beijing 102211, China

Corresponding author: ZHANG Chunhua, chhzhang@ciac.ac.cn
Received Date: 11 May 2016
Revised Date: 13 June 2016
Accepted Date: 6 July 2016

Fund Project: Supported by the Project of the State Grid Corporation:Technology of High Voltage IGBTchip Surface Passivation No.5455DW150005

Figures(4)

Condensation polymerization of 2,2'-bis(trifluoromethyl)-4,4'-diamino biphenyl(TFDB) and 3,3',4,4'-tetracarboxydiphthalic ether dianhydride(ODPA) gives a soluble polyimide. The effect of the degree of chemical imidization on positive photosensitive polyimide performance was investigated by adjusting the content of α-picoline in the imidization reagent to control the extent of the imide. The results show that the photosensitive polyimide has the best developing performance when the mole ratio of α-picoline to acetic anhydride is 1 to 5 in the process of chemical imidization.
- positive photosensitive polyimide,
- chemical imidization,
- solubility,
- photolithography
1. [1]
  Fukushima T, Hosokawa K, Oyama T. Synthesis and Positive-imaging Photosensitivity of Soluble Polyimides Having Pendant Carboxyl Groups[J]. Polym Sci Polym Chem, 2001,39(6):934-946. doi: 10.1002/(ISSN)1099-0518
2. [2]
  Hsu S L C, Lee P I, King J S. Synthesis and Characerization of a Positive-working Aqueous-base-developable Photosensitive Polyimide Precursor[J]. J Appl Polym Sci, 2002,86(2):352-358. doi: 10.1002/(ISSN)1097-4628
3. [3]
  Hsu S L C, Lee P I, King J S. Novel Positive-working Aqueous-base Developable Photosensitive Polyimide Precursors Based on Diazonaphthoquinone-capped Polyamic Ester[J]. J Appl Polym Sci, 2003,90(8):2293-2300. doi: 10.1002/(ISSN)1097-4628
4. [4]
  Hayase S, Takano K, Mtkogami Y. High-temperature-post-exposure Bake Process(HIT-PEB) for Base-developable Polyimides Consisting of Diazonaphthoquinones and Polyamic Acids[J]. Electrochem Soc, 1991,138(12):3625-3629. doi: 10.1149/1.2085469
5. [5]
  DING Mengxian. Polyimides:Chemistry, Relationship Between Structure and Properties and Materials[M]. Beijing:Science Press,2006(in Chinese).
6. [6]
  Lu Q H, Yin J, Xu H J. Preparation and Properties of Organo-soluble Polyimides Based-on 4,4'-Diamino-3,3'-dimethyldipheylmethane and Conventional Dianhydrides[J]. J Appl Polym Sci, 1999,10(72):1299-1304.
7. [7]
  Ayala D, Lozano A E, Abajo J D. Synthesis and Characterization of Novel Polyimides with Bulky Pendant Groups[J]. J Appl Polym Sci:Part A:Polym Chem, 1999,6(37):805-814.
8. [8]
  Yen C T, Chen W C, Liaw D J. Synthesis and Properties of New Polyimide-silica Hybrid Films Through Both Intrachain and Interchain Bonding[J]. Polym J, 2003,23(44):7079-7087.
9. [9]
  Li F, Fang S W, Ge J J. Diamine Architecture Effects on Glass Transitions, Relaxation Processes and Other Material Properties in Organo-soluble Aromatic Polyimide Film[J]. Polym J, 1999,16(40):4571-4583.
10. [10]
  Kim I C, Kim J H, Lee K H. Preparation of Soluble Polyimides and Ultrafiltration Membrane Performances[J]. J Appl Polym Sci, 2000,1(75):1-9.
11. [11]
  Eichstadt A E, Ward T C, Bagwell M D. Synthesis and Characterization of Amorphous Partially Aliphatic Polyimide Copolymers Based on Bisphenol-adianhydrides[J]. Macromolecules, 2002,20(35):7561-7568.
12. [12]
  Banihashemi A, Abdolmaleki A. Novel Aromatic Polyimides Derived from Benzofuro[2,3-b]benzofuran-2,3,8,9-tetracarboxylic dianhydride(BBTDA)[J]. Eur Polym J, 2004,8(40):1629-1635.
13. [13]
  Chen B K, Tsai Y J, Tsay S Y. 2,6-Diamino-4-phenylphenol(DAPP) Copolymerized Polyimides:Synthesis and Characterization[J]. Polym Int, 2006,1(55):93-100.
14. [14]
  Hayase R, Kihara N, Oyasato N. Positive Photosensitive Polyimides Using Polyamic Acid Esters with Phenol Moieties[J]. Appl Polym Sci, 1994,51(11):1971-1978. doi: 10.1002/app.1994.070511113
1. [1]
  Yonghui Wang , Weilin Chen , Yangguang Li . Knowledge Construction of “Solubility of Inorganic Substances” in Elemental Chemistry Teaching. University Chemistry, 2024, 39(4): 261-267. doi: 10.3866/PKU.DXHX202312102
2. [2]
  Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
3. [3]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
4. [4]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
5. [5]
  Cuicui Yang , Bo Shang , Xiaohua Chen , Weiquan Tian . Understanding the Wave-Particle Duality and Quantization of Confined Particles Starting from Classic Mechanics. University Chemistry, 2025, 40(3): 408-414. doi: 10.12461/PKU.DXHX202407066
6. [6]
  Lei Shi . Nucleophilicity and Electrophilicity of Radicals. University Chemistry, 2024, 39(11): 131-135. doi: 10.3866/PKU.DXHX202402018
7. [7]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
8. [8]
  Kai Yang , Gehua Bi , Yong Zhang , Delin Jin , Ziwei Xu , Qian Wang , Lingbao Xing . Comprehensive Polymer Chemistry Experiment Design: Preparation and Characterization of Rigid Polyurethane Foam Materials. University Chemistry, 2024, 39(4): 206-212. doi: 10.3866/PKU.DXHX202308045
9. [9]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
10. [10]
  Wenkai Chen , Yunjia Shen , Xiangmeng Kong , Yanli Zeng . Quantum Chemistry Calculation of Key Physical Quantity in Circularly Polarized Luminescence: Introducing an Exploratory Computational Chemistry Experiment. University Chemistry, 2025, 40(3): 83-91. doi: 10.12461/PKU.DXHX202405018
11. [11]
  Dongheng WANG , Si LI , Shuangquan ZANG . Construction of chiral alkynyl silver chains and modulation of chiral optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 131-140. doi: 10.11862/CJIC.20240379
12. [12]
  Suqing Shi , Anyang Li , Yuan He , Jianli Li , Xinjun Luan . Exploration and Practice of the “Progressive” Integrated Training Mode for Innovative Chemistry Talents at Comprehensive Universities in Western China. University Chemistry, 2024, 39(6): 42-49. doi: 10.3866/PKU.DXHX202402009
13. [13]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
14. [14]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
15. [15]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
16. [16]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
17. [17]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
18. [18]
  Jiying Liu , Zehua Li , Wenjing Zhang , Donghui Wei . Molecular Orbital and Nucleus-Independent Chemical Shift Calculations for C₆H₆ and B₁₂H₁₂^2-: A Computational Chemistry Experiment. University Chemistry, 2025, 40(3): 186-192. doi: 10.12461/PKU.DXHX202406085
19. [19]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
20. [20]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106

Get Citation

PDF

XML

Metrics

PDF Downloads(26)
Abstract views(1681)
HTML views(328)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142