Citation: ZHU Yiming, ZHANG Hao, ZHANG Jun, MI Gang, SONG Bangcai, DU Xigang. Preparation and Catalytic Performance Evaluation of Multi-metal Catalysts for Conversion of Tetrachloromethaneto Trichloromethane by Liquid Phase Hydrogenation[J]. Chinese Journal of Applied Chemistry, ;2017, 34(2): 242-244. doi: 10.11944/j.issn.1000-0518.2017.02.160251 shu

Preparation and Catalytic Performance Evaluation of Multi-metal Catalysts for Conversion of Tetrachloromethaneto Trichloromethane by Liquid Phase Hydrogenation

Chemical Engineering & Pharmaceutics School, He'nan University of Science & Technology, Luoyang, He'nan 471023, China

Corresponding author: ZHANG Jun, j-zhang@126.com
Received Date: 15 June 2016
Revised Date: 20 July 2016
Accepted Date: 9 August 2016

Fund Project: the National Natural Science Foundation of China 21076063the National Natural Science Foundation of China 21576073

Figures(2)

By using Pd/Pt as main active ingredients and Fe/Ni as auxiliary, coconut shell activated carbon (ACcs) loaded mono metal (M/ACcs), binary metal (M-Ni/ACcs, M-Fe/ACcs) and ternary metal (M-Ni-Fe/ACcs) catalysts have been prepared via metal impregnation and H₂ reduction. The catalytic activity and selectivity of the catalysts for conversion of CCl₄ to CHCl₃ by liquid-phase hydrogenation was evaluated. Compared with Pt-based catalysts, the Pd-based counterparts have higher activity, but lower CHCl₃ selectivity. During initial reaction time of 5 h, the catalytic activity order follows:Pd-Ni-Fe/ACcs > Pd-Fe/ACcs > Pd/ACcs > Pd-Ni/ACcs and Pt/ACcs≈Pt-Fe/ACcs > Pt-Ni/ACcs > Pt-Ni-Fe/ACcs. Addition of Fe component improves the activity while single addition of Ni lowers the catalytic performance. The Pd-Ni-Fe/ACcs catalyst can realize more than 97% conversion of CCl₄ and nearly 100% selectivity for CHCl₃ at 393 K for 5 h.
- tetrachloromethane,
- trichloromethane,
- liquid-phase hydrogenation,
- Pd/Pt catalysts,
- catalytic performance,
- conversion rate
1. [1]
  ZHANG Dongbao, ZHU Jianjun, SHAN Yuhua. Advances in Hydrodechlorination of Carbon Tetrachloride[J]. Chem Ind Eng Prog, 2007,26(4):477-480.
2. [2]
  Bae J W, Kim I G, Lee K H. Hydrodechlorination of CCl₄ over Pt/γ-Al₂O₃ Effects of Reaction Pressure and Diluent Gases on Distribution of Products and Catalyst Stability[J]. Appl Catal A, 2001,217(1):79-89.
3. [3]
  Barnes R J, Riba O, Gardner M N. Optimization of Nano-Scale Nickel/Iron Particles for Reduction of High Concentration Chlorinated Aliphatic Hydrocarbon Solutions[J]. Chemosphere, 2010,79(4):448-454. doi: 10.1016/j.chemosphere.2010.01.044
4. [4]
  Gómez-Sainero L M, Grau J M, Arcoyna A. Liquid-Phase Hydrodechlorination of CCl₄ to CHCl₃ on Pd/Carbon Catalysts:Nature and Role of Pd Active Species[J]. J Catal, 2002,209(2):279-288. doi: 10.1006/jcat.2002.3655
5. [5]
  Choi H C, Choi S H, Yang O B. Hydrodechlorination of Carbon Tetrachloride over Pt/MgO[J]. J Catal, 1996,161(2):790-797. doi: 10.1006/jcat.1996.0242
6. [6]
  Choi H C, Choi S H, Lee J S. Effects of Pt Precursors on Hydrodechlorination of Carbon Tetrachloride over Pt/Al₂O₃[J]. J Catal, 1997,166(2):284-293. doi: 10.1006/jcat.1997.1508
7. [7]
  Gómez-Sainero L M, Seoane X L, Arcoya A. Hydrodechlorination of Carbon Tetrachloride in the Liquid Phase on a Pd/Carbon Catalyst:Kinetic and Mechanistic Studies[J]. Appl Catal B, 2004,53(2):101-110. doi: 10.1016/j.apcatb.2004.05.007
8. [8]
  Zinovyev S, Perosa A, Yufit S. Hydrodechlorination and Hydrogenation over Raney-Ni under Multiphase Conditons:Role of Multiphase Environment in Reaction Kinetics and Selectivity[J]. J Catal, 2002,211(2):347-354. doi: 10.1016/S0021-9517(02)93755-3
9. [9]
  HUANG Yuanying, LIU Fei, TANG Mingnie. Dechlorination of Tetrachloroethene with Nanoscale Ni/Fe and Cu/Fe Bimetallic Particles[J]. J Environ Sci-China, 2007,27(1):80-85.
1. [1]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
2. [2]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
3. [3]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
4. [4]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
5. [5]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
6. [6]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
7. [7]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
8. [8]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
9. [9]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
10. [10]
  Xinghai Li , Zhisen Wu , Lijing Zhang , Shengyang Tao . Machine Learning Enables the Prediction of Amide Bond Synthesis Based on Small Datasets. Acta Physico-Chimica Sinica, 2025, 41(2): 100010-. doi: 10.3866/PKU.WHXB202309041
11. [11]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
12. [12]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
13. [13]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
14. [14]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
15. [15]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
16. [16]
  Zhiwen HU , Ping LI , Yulong YANG , Weixia DONG , Qifu BAO . Morphology effects on the piezocatalytic performance of BaTiO₃. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 339-348. doi: 10.11862/CJIC.20240172
17. [17]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
18. [18]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
19. [19]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
20. [20]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(471)
HTML views(135)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142