Citation: XIE Fezhi, LI Haibin, LI Guolian, CHEN Jianli, YANG Wen, WANG Xuechun, HU Tingting, SHENG Dandan, XIE Zhiyong. Phosphate Removal by Using Shield Residues/Carbon Composite Ceramsite[J]. Chinese Journal of Applied Chemistry, ;2017, 34(2): 211-219. doi: 10.11944/j.issn.1000-0518.2017.02.160176 shu

Phosphate Removal by Using Shield Residues/Carbon Composite Ceramsite

XIE Fezhi ^a,b,*,, ,
LI Haibin ^a,c ,
LI Guolian ^b,d ,
CHEN Jianli ^a,c ,
YANG Wen ^a,c ,
WANG Xuechun ^a,c ,
HU Tingting ^a,c ,
SHENG Dandan ^a,c ,
XIE Zhiyong ^a,c

a.
School of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei 230601, China
b.
Anhui Key Laboratory of Water Pollution Control and Wastewater Resource, Anhui Jianzhu University, Hefei 230601, China
c.
Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei 230601, China
d.
School of Environment and Energy Engineering, Anhui Jianzhu University, Hefei 230601, China

Corresponding author: XIE Fezhi, fzxie@ahjzu.edu.cn
Received Date: 26 April 2016
Revised Date: 15 June 2016
Accepted Date: 8 July 2016

Fund Project: the Outstanding Youth Elite Support Program in Universities of Anhui Province 2014-5the Natural Science Foundation of Education Department of Anhui Province KJ2016A154the National Natural Science Foundation of China 21107001Natural Science Foundation of Anhui Province, China 1608085MB43

Figures(9)

Composite ceramsite was prepared by sintering solid waste residue of shield residues, powdered rice straw and magnesium oxide. The effects of pH, sorption time and temperature were investigated. The results show that the optimal sintering temperature of the composite ceramsite is 700℃ with the mass ratio of shield residue to powdered rice straw and to magnesium oxide as 7:2:1. The optimum adsorption pH is 6.3, and phosphate can reach adsorption equilibrium within 12 hours. The Lagergren pseudo second order kinetics and the Temkin isotherm model fit the experimental data well. The adsorption capacity increases with increasing the sorption temperature, and the maximum adsorption of ceramsite is 12.76 mg/g at 40℃. The adsorption is confirmed as a nonspontaneous endothermic process according to the results of ΔH=5.64 kJ/mol > 0, ΔS=8.00 J/(K·mol) > 0, ΔG=3.16 kJ/mol > 0. Meanwhile, the adsorbed phosphate on ceramsite can be recovered by using 2.0 mol/L NaOH.
- shield residue,
- carbon,
- ceramsite,
- phosphate,
- adsorption
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