Citation: WANG Bin, WANG Xiaohong, Li Jiuming, WANG Xiaohui, XIE Lijuan, Duan Limei, LIU Zongrui. Electrochromic Properties of Hybrid Mutilayer Film Based on Pressler Type Polyoxometalate P₅W₃₀, Positive Polyelectrolyte and Graphene Oxide[J]. Chinese Journal of Applied Chemistry, ;2017, 34(2): 233-241. doi: 10.11944/j.issn.1000-0518.2017.02.160125 shu

Electrochromic Properties of Hybrid Mutilayer Film Based on Pressler Type Polyoxometalate P₅W₃₀, Positive Polyelectrolyte and Graphene Oxide

College of Chemistry and Chemical Engineering, Inner Mongolia University for the Nationalities, Tongliao, Inner Mongolia 028000, China

Corresponding author: WANG Bin, jluwangbin09@163.com
Received Date: 25 March 2016
Revised Date: 20 May 2016
Accepted Date: 17 June 2016

Fund Project: Natural Science Foundation of Inner Mongolia 2015BS0207Science Foundation of Inner Mongolia University for the Nationalities NMDGP1501Open Projects Founded by Inner Mongolia Key Laboratory for the Natural Products Chemistry and Functional Molecular Synthesis MDK2016010Ph.D Initiative Science Foundation of Inner Mongolia University for the Nation-alities BS338the National Natural Science Foundation of China 21501102

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To improve the electrochromic performance of thin film[PEI/P₅W₃₀]₃₀(PEI:polyethyleneimine), graphene oxide with large two-dimensional size and excellent electrical conductivity was incorporated. We have fabricated an organic/inorganic hybrid thin film[PEI/P₅W₃₀/PEI/GO]₃₀ based on Preyssler-type polyoxometalate K_12.5Na_1.5[NaP₅W₃₀O₁₁₀]·15H₂O (P₅W₃₀) and graphene oxide (GO) by layer-by-layer method (LBL). The composition and growth process of the film were characterized by ultraviolet-visible (UV-Vis) spectrophotometer. We investigated the morphology by atomic force microscopy (AFM) and studied the electrochemical properties by cyclic voltammetry of the multilayers. The film displays reversible electrochromic behavior from colorless to blue when applied a redox potential, and the response time of the coloring and discoloring process are all within 10 seconds. More importantly, the electrochromic property has no obvious change after 150 cycles under double potential step at 0.75 V and -0.75 V, the electrocromic film reflects a good reversibility. The film of[PEI/P₅W₃₀/PEI/GO]₃₀ exhibits fast response, long durability after GO embedding, and has a potential application in electrochromic devices.
- polyoxometalates,
- graphene oxide,
- controllable self-assembly thin films,
- electrochromism
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Electrochromic Properties of Hybrid Mutilayer Film Based on Pressler Type Polyoxometalate P5W30, Positive Polyelectrolyte and Graphene Oxide

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通讯作者: 陈斌, bchen63@163.com

Electrochromic Properties of Hybrid Mutilayer Film Based on Pressler Type Polyoxometalate P₅W₃₀, Positive Polyelectrolyte and Graphene Oxide