Citation: ZHANG Yingying, LI Xinyu, WAN Li, ZHANG Peng, LOU Zhenning, SHAN Weijun, XIONG Ying. Preparation of Thiol/Oxidized Cellulose Adsorbent and Selective Adsorption of Ag (Ⅰ) in Chlorination System[J]. Chinese Journal of Applied Chemistry, ;2017, 34(1): 90-97. doi: 10.11944/j.issn.1000-0518.2017.01.160447 shu

Preparation of Thiol/Oxidized Cellulose Adsorbent and Selective Adsorption of Ag (Ⅰ) in Chlorination System

Key Laboratory of Rare-scattered Elements of Liaoning Province, College of Chemistry, Liaoning University, Shenyang 110036, China

Corresponding author: XIONG Ying, xiongying@lnu.edu.cn
Received Date: 7 November 2016
Revised Date: 9 November 2016
Accepted Date: 9 November 2016

Fund Project: the National Natural Science Foundation of China No.51674131, No.21171080, No.21201094Program for Liaoning Excellent Talents in University LR2015026Liaoning Provincial Department of Education Innovation Team Projects LT2015012Liaoning BaiQianWan Talents Program 2014National Science & Technology Pillar Program 2015BAB02B03

Figures(7)

A series of adsorbents based on waste paper cellulose was prepared by oxidative ring-opening, amination and sulfhydrylation reaction. The adsorption capacity of the cellulose modified by amino thiourea/glutaraldehyde on coordination anion AgCl₄^3- is the best in both the single system and the mixed system containing high levels of Cu (Ⅱ) and Ni (Ⅱ) chlorides. The maximum adsorption capacity of Ag (Ⅰ) can reach 171.16 mg/g. Reasons for different adsorption effects and the electrostatic adsorption mechanism of coordination anion Ag (Ⅰ) on the adsorbent were discussed based on IR, XPS and thermodynamics and so on, which can be ascribed to the electrostatic interaction between AgCl₄^3- and the protonated thiol group of thiolmide group.
- Ag (Ⅰ) chloride anion,
- cellulose,
- chlorination liquid,
- selective adsorption
1. [1]
  Kim C K, Lee G J, Lee M K. A Novel Method to Prepare Cu@Ag Coreshell Nanoparticles for Printed Flexible Electronics[J]. Powder Technol, 2014,263(5):1-6.
2. [2]
  Junejo Y, Güne A, Baykal A. Synthesis and Characterization of Amoxicillin Derived Silver Nanoparticles:Its Catalytic Effect on Degradation of Some Pharmaceutical Antibiotics[J]. Appl Surf Sci, 2014,317(3):914-922.
3. [3]
  HE Faquan, LI Yongjun. Application and Preparation of Silver Powder[J]. China Powder Sci Technol, 2001,7(3):45-47.
4. [4]
  LI Dingxin,WANG Yonglu. Precious Metals Extraction and Refining[M]. Changsha:Central South University Press,2003:375-385(in Chinese).
5. [5]
  Iglesias M, Antico E, Salvado V. The Characterization of Silver Sorption by Chelating Resins Containing Thiol and Amine Groups[J]. Solvent Extr Ion Exch, 2001,19(2):315-327. doi: 10.1081/SEI-100102698
6. [6]
  Atia A A, Donia A M, Yousif A M. Comparative Study of the Recovery of Silver (Ⅰ) from Aqueous Solutions with Different Chelating Resins Derived from Glycidyl Methacrylate[J]. J Appl Polym Sci, 2005,97(3):806-812. doi: 10.1002/(ISSN)1097-4628
7. [7]
  El-Ghaffar M A A, Mohamed M H, Elwakeel K Z. Adsorption of Silver (Ⅰ) on Synthetic Chelating Polymer Derived from 3-Amino-1, 2, 4-triazole-5-thiol and Glutaraldehyde[J]. Chem Eng J, 2009,151(1/2/3):30-38.
8. [8]
  Song X, Gunawan P, Jiang R. Surface Activated Carbon Nanospheres for Fast Adsorption of Silver Ions from Aqueous Solutions[J]. J Hazard Mater, 2011,194(11):162-168.
9. [9]
  Zhang M, Zhang Y, Helleur R. Selective Adsorption of Ag⁺ by Ion-imprinted O-Carboxymethyl Chitosan Beads Grafted with Thiourea-Glutaraldehyde[J]. Chem Eng J, 2015,264:56-65. doi: 10.1016/j.cej.2014.11.062
10. [10]
  Liu P, Borrell P F, Bozic M. Nanocelluloses and Their Phosphorylated Derivatives for Selective Adsorption of Ag⁺, Cu²⁺ and Fe³⁺ from Industrial Effluents[J]. J Hazard Mater, 2015,294:177-185. doi: 10.1016/j.jhazmat.2015.04.001
11. [11]
  Xiong Y, Wan L, Xuan J. Selective Recovery of Ag (Ⅰ) Coordination Anion from Simulate Nickel Electrolyte Using Corn Stalk Based Adsorbent Modified by Ammonia-thiosemicarbazide[J]. J Hazard Mater, 2016,301:277-285. doi: 10.1016/j.jhazmat.2015.09.003
12. [12]
  LOU Zhenning, REN Fuqiang, WANG Jing. Re (Ⅶ) Adsorption by Magnetic Cross-linked Chitosan Microspheres Modified with Diiobutylamine[J]. Chinese J Appl Chem, 2014,31(9):1031-1036.
13. [13]
  Adhikari C R, Parajuli D, Kawakita H. Adsorption Behavior of Iminodiacetic Acid Type of Chelating Gel Prepared from Waste Paper[J]. Sep Sci Technol, 2007,42(3):579-590. doi: 10.1080/01496390601120599
14. [14]
  Monier M, Kenawy I M, Hashem M A. Synthesis and Characterization of Selective Thiourea Modified Hg (Ⅱ) Ion-imprinted Cellulosic Cotton Adsorbent[J]. Carbohydr Polym, 2014,106(106):49-59.
15. [15]
  Atia A A, Donia A M, Heniesh A M. Adsorption of Silver and Gold Ions from Their Aqueous Solutions Using a Magnetic Chelating Resin Derived from a Blend of Bisthiourea/Thiourea/Glutaraldehyde[J]. Sep Sci Technol, 2014,49(13):2039-2048. doi: 10.1080/01496395.2014.906452
1. [1]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
2. [2]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
3. [3]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
4. [4]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
5. [5]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
6. [6]
  Rong Tian , Yadi Yang , Naihao Lu . Comprehensive Experimental Design of Undergraduate Students Based on Interdisciplinarity: Study on the Effect of Quercetin on Chlorination Activity of Myeloperoxidase. University Chemistry, 2024, 39(8): 247-254. doi: 10.3866/PKU.DXHX202312064
7. [7]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
8. [8]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
9. [9]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
10. [10]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
11. [11]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
12. [12]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
13. [13]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
14. [14]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
15. [15]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
16. [16]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
17. [17]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
18. [18]
  Yutong Dong , Huiling Xu , Yucheng Zhao , Zexin Zhang , Ying Wang . The Hidden World of Surface Tension and Droplets. University Chemistry, 2024, 39(6): 357-365. doi: 10.3866/PKU.DXHX202312022
19. [19]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
20. [20]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(340)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142