Citation: FENG Xuejiao, CUI Hongmin, XIAO Zhengqiang, YAN Nanfu, LI Min. Synthesis of Porous Silicon Oxide/Silicon/Carbon Composite Material from Micro-SiO for Lithium Storage[J]. Chinese Journal of Applied Chemistry, ;2017, 34(1): 76-82. doi: 10.11944/j.issn.1000-0518.2017.01.160101 shu

Synthesis of Porous Silicon Oxide/Silicon/Carbon Composite Material from Micro-SiO for Lithium Storage

a.
Institute of Science and Technology Strategy, Jiangxi Academy of Science, Nanchang 330029, China
b.
Institute of Applied Chemistry, Jiangxi Academy of Science, Nanchang 330029, China

Corresponding author: FENG Xuejiao, cuihm1215@163.com
Received Date: 9 March 2016
Revised Date: 7 April 2016
Accepted Date: 7 April 2016

Fund Project: the Doctoral Project of Jiangxi Academy of Science No.2014-YYB-27, No.2014-YYB-20

Figures(7)

Porous silicon oxide/silicon/carbon composite was derived from micro-silicon monoxide with simple calcination, chemical vapor deposition and HF etching. The obtained c-SiO_x/Si/C (c-refers to calcination) composite after etching possesses a high specific surface area of 32.9 m²/g and an average/mean pore distribution of 3 nm. The atomic ratio of Si/O in c-SiO_x/Si/C is increased comparing to that of c-SiO/C without etching. The Si nano-crystallites were embedded in porous Si-suboxide, and the particles are covered by a uniform carbon layer with a thickness of 6 nm on the surface. The c-SiO_x/Si/C with this particular structure exhibits a stable reversible capacity of ca. 645.1 mA·h/g after 50 cycles with the current density at 0.3 mA/g. In contrast, c-SiO/C composite without pores presents a reversible capacity of only ca. 466 mA·h/g under the same carbon coating condition. The different cycling performances of c-SiO_x/Si/C and c-SiO/C may be consequences of their structural differences. It is believed that the rich nanopores of the c-SiO_x/Si/C can endure and buffer the severe volume change of silicon upon lithium insertion and extraction and improve the mechanical integrity of composite.
- silicon monoxide,
- porous structure,
- electrochemical performance,
- lithium ion battery
1. [1]
  LI Zhijie, LIANG Qi, CHEN Dongliang. Cooperation Action of Carbon Nanotubes and Graphite During Lithium Electrochemical Intercalation[J]. Chinese J Appl Chem, 2001,18(4):269-27.
2. [2]
  Liang B, Liu Y, Xu Y. Silicon-Based Materials as High Capacity Anodes for Next Generation Lithium Ion Batteries[J]. J Power Sources, 2014,267:469-490. doi: 10.1016/j.jpowsour.2014.05.096
3. [3]
  Wang W, Datta M K, Kumta P N. Silicon-Based Composite Anodes for Li-ion Rechargeable Batteries[J]. J Mater Chem, 2007,17(30):3229-3237. doi: 10.1039/b705311h
4. [4]
  Bao Q, Huang Y H., Lan C K. Scalable Upcycling Silicon from Waste Slicing Sludge for High-Performance Lithium-Ion Battery Anodes[J]. Electrochim Acta, 2015,173:82-90. doi: 10.1016/j.electacta.2015.04.155
5. [5]
  Park H, Choi S, Lee S. Novel Design of Silicon-Based Lithium-ion Battery Anode for Highly Stable Cycling at Elevated Temperature[J]. J Mater Chem A, 2014,3(3):1325-1332.
6. [6]
  Lin H, Weng W, Ren J. Twisted Aligned Carbon Nanotube/Silicon Composite Fiber Anode for Flexible Wire-shaped Lithium-Ion Battery[J]. Adv Mater, 2014,26(8):1217-1222. doi: 10.1002/adma.v26.8
7. [7]
  Wang J, Wang H, Zhang B. A Stable Flexible Silicon Nanowire Array as Anode for High-Performance Lithium-Ion Batteries[J]. Electrochim Acta, 2015,176:321-326. doi: 10.1016/j.electacta.2015.07.001
8. [8]
  Wang W, Ruiz I, Ahmed K. Silicon Decorated Cone Shaped Carbon Nanotube Clusters for Lithium Ion Battery Anodes[J]. Small, 2014,10(16):3389-3396. doi: 10.1002/smll.v10.16
9. [9]
  FAN Xuge, LI Guocai, CHENG Chaoqun. Progress in Controlled Fabrication Techniques and Applications of Silicon Nanowires Associated with Metal-Assisted Chemical Etching[J]. Chinese J Appl Chem, 2013,30(11):1257-126.
10. [10]
  Si Q, Hanai K, Ichikawa T. Improvement of Cyclic Behavior of a Ball-Milled SiO and Carbon Nanofiber Composite Anode for Lithium-Ion Batteries[J]. J Power Sources, 2011,196(22):9774-9779. doi: 10.1016/j.jpowsour.2011.08.005
11. [11]
  Liu Y H, Okano M, Mukai T. Improvement of Thermal Stability and Safety of Lithium Ion Battery Using SiO Anode material[J]. J Power Sources, 2016,304:9-14. doi: 10.1016/j.jpowsour.2015.10.106
12. [12]
  Doh C H, Park C W, Shin H M. A New SiO/C Anode Composition for Lithium-ion Battery[J]. J Power Sources, 2008,179(1):367-370. doi: 10.1016/j.jpowsour.2007.12.074
13. [13]
  Hou X, Wang J, Zhang M. Facile Spray-Drying/Pyrolysis Synthesis of Intertwined SiO@CNFs&G Composites as Superior Anode Materials for Li-Ion Batteries[J]. RSC Adv, 2014,4(65):34615-34622. doi: 10.1039/C4RA03475A
14. [14]
  Wu W, Liang Y, Ma H. Insights into the Conversion Behavior of SiO-C Hybrid with Pre-treated Graphite as Anodes for Li-ion Batteries[J]. Electrochim Acta, 2016,187:473-479. doi: 10.1016/j.electacta.2015.11.008
15. [15]
  Doh C H, Park C W, Shin H M. A New SiO/C Anode Composition for Lithium-Ion Battery[J]. J Power Sources, 2008,179(1):367-370. doi: 10.1016/j.jpowsour.2007.12.074
16. [16]
  Liu W R, Yen Y C, Wu H C. Nano-Porous SiO/Carbon Composite Anode for Lithium-Ion Batteries[J]. J Appl Electrochem, 2009,39(9):1643-1649. doi: 10.1007/s10800-009-9854-x
17. [17]
  Lee J I, Lee K T, Cho J. Chemical-Assisted Thermal Disproportionation of Porous Silicon Monoxide into Silicon-Based Multicomponent Systems[J]. Angew Chem Int Ed, 2012,51(11):2767-2771. doi: 10.1002/anie.201108915
18. [18]
  Feng X, Yang J, Lu Q. Facile Approach to SiO_x/Si/C Composite Anode Material from Bulk SiO for Lithium Ion Batteries[J]. Phys Chem Chem Phys, 2013,15(34):14420-14426. doi: 10.1039/c3cp51799c
19. [19]
  Etacheri V, Haik O, Goffer Y. Effect of Fluoroethylene Carbonate (FEC) on the Performance and Surface Chemistry of Si-Nanowire Li-Ion Battery Anodes[J]. Langmuir, 2012,28(1):965-976. doi: 10.1021/la203712s
20. [20]
  Doh C H, Veluchamy A, Lee D J. Comparative Study on Performances of Composite Anodes of SiO, Si and Graphite for Lithium Rechargeable Batteries[J]. Bull Korean Chem Soc, 2010,31(5):1257-1261. doi: 10.5012/bkcs.2010.31.5.1257
1. [1]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
2. [2]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
3. [3]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
4. [4]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
5. [5]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
6. [6]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
7. [7]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
8. [8]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
9. [9]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
10. [10]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
11. [11]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
12. [12]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
13. [13]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
14. [14]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
15. [15]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
16. [16]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
17. [17]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
18. [18]
  Ping Ye , Lingshuang Qin , Mengyao He , Fangfang Wu , Zengye Chen , Mingxing Liang , Libo Deng . 荷叶衍生多孔碳的零电荷电位调节实现废水中电化学捕集镉离子. Acta Physico-Chimica Sinica, 2025, 41(3): 2311032-. doi: 10.3866/PKU.WHXB202311032
19. [19]
  Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164
20. [20]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(319)
HTML views(40)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142