Citation: ZHANG Haoran, WANG Jin, LEI Bingfu, LIU Yingliang. Influence of Tm³⁺ Codopant on Luminescence Properties of CaAlSiN₃: Eu²⁺ Phosphor[J]. Chinese Journal of Applied Chemistry, ;2016, 33(11): 1310-1315. doi: 10.11944/j.issn.1000-0518.2016.11.160326 shu

Influence of Tm³⁺ Codopant on Luminescence Properties of CaAlSiN₃: Eu²⁺ Phosphor

1.
Guangdong Provincial Engineering Technology Research Center for Optical Agriculture, College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China

Corresponding author: LEI Bingfu,
Received Date: 16 August 2016
Available Online: 21 September 2016
Fund Project:

A series of Eu²⁺ single doped and Tm³⁺ co-doped CaAlSiN₃ phosphors were synthesized by high temperature solid-reaction method. Photoluminescence, afterglow emission and thermoluminescence glow curve investigations indicate that CaAlSiN₃:0.1%Eu²⁺ sample possesses excellent photoluminescence properties with broad emission band located at about 630 nm. The introduction of Tm³⁺ codopant creates new emission bands located 654 nm and 800 nm, respectively, which are originated from Tm³⁺ in CaAlSiN₃ matrix. However, the Tm³⁺ codopant causes the disappearance of 89.0℃ thermoluminescence glow peak, which indicates that the introduction of Tm³⁺ has changed the defect distribution and their concentrations, thus deceasing the visible 630 nm red light afterglow of CaAlSiN₃:Eu²⁺.
- CaAlSiN₃:Eu²⁺,
- rare earth co-doped,
- persistent luminescence,
- traps
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Tm3+ Codopant on Luminescence Properties of CaAlSiN3: Eu2+ Phosphor

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通讯作者: 陈斌, bchen63@163.com

Influence of Tm³⁺ Codopant on Luminescence Properties of CaAlSiN₃: Eu²⁺ Phosphor