Citation: WU Liqiong, HAO Lihua, KONG Fanhua, LI Xinheng. Confined In-Situ Synthesis of Ferroferric Oxide Nanoparticles on Mesoporous Carbon[J]. Chinese Journal of Applied Chemistry, ;2016, 33(11): 1340-1342. doi: 10.11944/j.issn.1000-0518.2016.11.160148 shu

Confined In-Situ Synthesis of Ferroferric Oxide Nanoparticles on Mesoporous Carbon

1.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics(LICP), Chinese Academy of Sciences, Suzhou, Jiangsu 215123, China

Corresponding author: KONG Fanhua, LI Xinheng,
Received Date: 11 April 2016
Available Online: 8 June 2016
Fund Project:

Mesoporous carbon with monolithic structures were prepared using abandoned crab shells as a template. And then Fe₃O₄ nanoparticles inside those monolithic mesopores were synthesized by the confined in-situ synthetic strategy. The properties and structure of Fe₃O₄ nanoparticles on nesoporous narbon were characterized by scanning electronic microscopy(SEM), transmission electron microscope(TEM) and X-ray diffraction(XRD). The results show that the pores have a monolithic structure. The diameters of the pores are ca. 40~50 nm and their lengths are ca. 50 μm to 200 μm. The nanoparticles are proven to be Fe₃O₄ with 10 nm in diameter, which have good size monodispersity and are evenly distributed inside the pores. This method features simple and environmental benignity.
- Fischer-Tropsch synthesis,
- nanocatalysis,
- iron oxide,
- porous carbon,
- monolithic structures
1. [1]
  [1] YU Huarong,CHENG Rongming,XU Xuecheng,et al. Carbon Nanotube-supported Fe₂O₃[J]. Chinese Inorg Chem,2005,21(11):1649-1654(in Chinese). 于华荣,成荣明,徐学诚,等. 碳纳米管负载纳Fe₂O₃的研究[J]. 无机化学学报,2005,21(11):1649-1654.
2. [2]
  [2] Li Y B,Yi R,Liu X H. Synthesis and Properties of Ni/ZnS Magnetic Luminescent Bifunctional Nanocomposites[J]. J Alloys Compd,2009,486(1/2):1-4.
3. [3]
  [3] Peng F F,Zhang Y,Gu N. Size-dependent Peroxidase-like Catalytic Activity of Fe₃O₄ Nanoparticles[J]. Chinese Chem Lett,2008,19(6):730-733.
4. [4]
  [4] Cano L A,Cabanillas E D,Marchetti S G. Synthesis and Characterization of Superparamagnetic Iron Oxide Nanoparticles for Biomedical Applications[J]. Hyperfine Interact,2010,195(1):275-280.
5. [5]
  [5] Wu C L,He H,Gao H J,et al. Synthesis of Fe₃O₄@SiO₂@polymer Nanoparticles for Controlled Drug Release[J]. Sci China Chem,2010,53(3):514-518.
6. [6]
  [6] Sriharsha T,Dhirendra B,Satish V,et al. Sonochemical Stabilization of Ultrafine Colloidal Biocompatible Magnetite Nanoparticles Using Amino Acid, L-Arginine for Possible Bioapplications[J]. Ultrason Sonochem,2010,17(4):730-737.
7. [7]
  [7] Wang L Y, Bao J,Wang L,et al. One-pot Synthesis and Bioapplication of Amine-functionalized Magnetite Nanoparticles and Hollow Nanospheres[J]. Chem Eur J,2006,12(24):6341-6347.
8. [8]
  [8] HU Dawei,WANG Yanmin. Control Mechanism and Method of Synthesized Fe₃O₄ Magnetite Nanoparticles[J]. Chinese J Silica,2008,36(10):1488-1493(in Chinese). 胡大为,王燕民. 合成四氧化三铁纳米粒子形貌的调控机理和方法[J]. 硅酸盐学报,2008,36(10):1488-1493.
9. [9]
  [9] FU Jia,XU Qiming,LI Ning,et al. Preparation and Application of Fe₃O₄ Magnetite Nanoparticles[J]. Chinese J Inorg Salt Ind,2007,39(10):5-7(in Chinese).付佳,许启明,李宁,等. 纳米四氧化三铁化学法制备及其应用[J]. 无机盐工业,2007,39(10):5-7.
10. [10]
  [10] MA Chuanguo,LU Wei,ZHENG Haijun,et al. Synthesis of Fe₃O₄/C Composites[J]. Chinese J Inorg Salt Ind,2009,41(4):24-27(in Chinese).马传国,逯伟,郑海军,等. 碳/四氧化三铁纳米复合材料合成研究[J]. 无机盐工业,2009,41(4):24-27.
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沈阳化工大学材料科学与工程学院沈阳 110142