Citation: CHEN Dun, MA Yali, Tunsagnl Awut, Ismayil Nurulla. Preparation of 6-(4'-Nicotinamido) phenyl-3-(3'-pyridinyl) pyridazino[3,2-c]1,2,4-triazole and Its Adsorption Performance for Mercury(Ⅱ) Ions[J]. Chinese Journal of Applied Chemistry, ;2016, 33(11): 1322-1328. doi: 10.11944/j.issn.1000-0518.2016.11.160069 shu

Preparation of 6-(4'-Nicotinamido) phenyl-3-(3'-pyridinyl) pyridazino[3,2-c]1,2,4-triazole and Its Adsorption Performance for Mercury(Ⅱ) Ions

CHEN Dun ^a,b ,
MA Yali ^a,b ,
Tunsagnl Awut ^a ,
Ismayil Nurulla ^a,,

1.
a Key Laboratory of Functional Polymer Materials, School of Chemistry and Chemical Engineering, Urumqi 830046, China;
2.
b Xinjiang Education Institute, Urumqi 830043, China

Corresponding author: Ismayil Nurulla,
Received Date: 23 February 2016
Available Online: 13 June 2016
Fund Project:

6-(4'-Nicotinamido)phenyl-3-(3'-pyridinyl)pyridazino[3,2-c]1,2,4-triazole(K₂) was prepared by 3-(4-bromophenyl)-6-chloropyridazine and nicotinic hydrazide, and characterized by infrared spectroscopy, ¹H- and ¹³C-nuclear magnetic resonance spectroscopy. The adsorptive properties and the selectivity of compound K₂ for the separation of Hg²⁺ were investigated. The results indicate that the maximum adsorption capacity is 46.50 mg/g. The adsorption capacity reaches equilibrium within 20 min at pH 6.0~8.0. Using 0.50 mol/L HCl and 1.00 mol/L thiourea as desorption solvent, the desorption rate is more than 97%. The selective factor(α) values of Hg(Ⅱ) for Cd(Ⅱ), Co(Ⅱ), Ni(Ⅱ), Zn(Ⅱ) and Mn(Ⅱ) are 5.67, 6.70, 10.20, 8.90 and 9.21, respectively. These indicate that compound K₂ has excellent adsorption and selective properties. The experimental data follow the Langmuir adsorption model and a pseudo-second-order model.
- mercury(Ⅱ),
- adsorption material,
- adsorption property,
- conjugated structure
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