Citation: SUN Bin, LIU Yanlong, BIAN Xinchao, ZHANG Bao, ZHOU Linyao, FENG Lidong, LI Gao, CHEN Zhiming. Preparation of High Heat Resistance Polylactide by Stereocomplexation[J]. Chinese Journal of Applied Chemistry, ;2016, 33(9): 1033-1039. doi: 10.11944/j.issn.1000-0518.2016.09.150456 shu

Preparation of High Heat Resistance Polylactide by Stereocomplexation

SUN Bin ^a,b,c ,
LIU Yanlong ^a,b ,
BIAN Xinchao ^a,b,, ,
ZHANG Bao ^a ,
ZHOU Linyao ^a ,
FENG Lidong ^a,b ,
LI Gao ^a,, ,
CHEN Zhiming ^b

1.
a Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2.
b Zhejiang Hisun Biomaterials Co., Ltd, Taizhou, Zhejiang 318000, China;
3.
c University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: BIAN Xinchao, LI Gao,
Received Date: 22 December 2015
Available Online: 29 March 2016
Fund Project:

The stereocomplex powder was prepared by mixing the same amount of poly(L-lactide)(PLLA) and poly(D-lactide)(PDLA) resins at a relative low temperature and then was mixed with the nucleation agent and glass fiber. The mixture was molded in the injection machine, followed by annealing at different temperatures to form the blends with high heat resistance. The vicat softening temperature reached to 165℃ and the DSC results revealed that the blends were rich in stereocomplex and the enthalpy was as high as 27.6 J/g. Moreover, the tensile strength was increased greatly to 129 MPa.
- polylactide,
- heat resistance,
- stereocomplexation,
- crystallization,
- vicat softening temperature
1. [1]
  [1] Auras R,Harte B,Selke S.An Overview of Polylactides as Packaging Materials[J].Macromol Biosci,2004,4(9):835-864.
2. [2]
  [2] Raquez J M,Habibi Y,Murariu M,et al.Polylactide (PLA)-Based Nanocomposites[J].Prog Polym Sci,2013,38(10/11):1504-1542.
3. [3]
  [3] Rasal R M,Hirt D E.Toughness Decrease of PLA PHBHHx Blend Films upon Surface-Confined Photopolymerization[J].J Biomed Mater Res Part A,2008,88A (4):1079-1086.
4. [4]
  [4] Hiljanen V M,Varpomaa P,Seppälä J,et al.Modification of Poly (L-lactides) by Blending:Mechanical and Hydrolytic Behavior[J].Macromol Chem Phys,1996,197(4):1503-1523.
5. [5]
  [5] Ljungberg N,Wesslén B.The Effects of Plasticizers on the Dynamic Mechanical and Thermal Properties of Poly (Lactic Acid)[J].J Appl Polym Sci,2002,86(5):1227-1234.
6. [6]
  [6] Tsuji H,Takai H,Saha S K.Isothermal and Non-Isothermal Crystallization Behavior of Poly (L-Lactic Acid):Effects of Stereocomplex as Nucleating Agent[J].Polymer,2006,47(11):3826-3837.
7. [7]
  [7] Kawamoto N,Sakai A,Horikoshi T,et al.Nucleating Agent for Poly (L-lactic Acid)-An Optimization of Chemical Structure of Hydrazide Compound for Advanced Nucleation Ability[J].J Appl Polym Sci,2007,103(1):198-203.
8. [8]
  [8] Harris A M,Lee E C.Improving Mechanical Performance of Injection Molded PLA by Controlling Crystallinity[J].J Appl Polym Sci,2008,107(4):2246-2255.
9. [9]
  [9] Lim L T,Aurasb R,Rubinob M.Processing Technologies for Poly (Lactic Acid)[J].Prog Polym Sci,2008,33(8):820-852.
10. [10]
  [10] Ray S S,Okamoto M.Polymer/Layered Silicate Nanocomposites:A Review from Preparation to Processing[J].Prog Polym Sci,2003,28(11):1539-1641.
11. [11]
  [11] Tsuji H,Hyon S H,Ikada Y.Stereocomplex Formation Between Enantiomeric Poly (Lactic Acid) S.3.Calorimetric Studies on Blend Films Cast from Dilute Solution[J].Macromolecules,1991,24(20):5651-5656.
12. [12]
  [12] Tsuji H,Ikada Y.Stereocomplex Formation between Enantiomeric Poly (Lactic Acids).9.Stereocomplexation from the Melt[J].Macromolecules,1993,26(25):6918-6926.
13. [13]
  [13] Narita J,Katagiri M,Tsuji H.Highly Enhanced Nucleating Effect of Melt-recrystallized Stereocomplex Crystallites on Poly (L-lactic acid) Crystallization[J].Macromol Mater Eng,2011,296(10):887-893.
14. [14]
  [14] Sun J,Yu H,Zhuang X,et al.Crystallization Behavior of Asymmetric PLLA/PDLA Blends[J].J Phys Chem B,2011,115(12):2864-2869.
15. [15]
  [15] Shao J,Sun J,Bian X,et al,Investigation of Poly (lactide) Stereocomplexes:3 Armed Poly (L-lactide) Blended with Linear and 3 Armed Enantiomers[J].J Phys Chem B,2012,116(33):9983-9991.
16. [16]
  [16] Haubruge H G,Daussin R,Jonas A M,et al.Epitaxial Nucleation of Poly (Ethylene Terephthalate) by Talc:Structure at the Lattice and Lamellar Scales[J].Macromolecules,2003,36(12):4452-4456.
17. [17]
  [17] Nam J Y,Okamoto M,Okamoto H,et al.Morphology and Crystallization Kinetics in a Mixture of Low-molecular Weight Aliphatic Amide and Polylactide[J].Polymer,2006,47(4):1340-1347.
18. [18]
  [18] Li H,Huneault M A.Effect of Nucleation and Plasticization on the Crystallization of Poly (Lactic Acid)[J].Polymer,2007,48(23):6855-6866.
19. [19]
  [19] HAN Bing,ZHANG Shengchun,ZHANG Chunxiang,et al.Toughening Modification of Glass Fiber-Reinforced PLA Composites[J].Mod Plast Process Appl,2013,25(1):27-30(in Chinese).韩冰,张声春,张春祥,等.璃纤维增强聚乳酸复合材料的增韧改性研究[J].现代塑料加工,2013,25(1):27-30.
1. [1]
  Yan Xiao , Shuling Li , Yifan Li , Jianing Fan , Linlin Shi . Discovering the Beauty of Life: Adding Some “Ingredients” to Crystals. University Chemistry, 2024, 39(6): 366-372. doi: 10.3866/PKU.DXHX202312025
2. [2]
  Lanjun Cheng , Xinyuan Wang , Jie An , Xiang Wu , Chengfeng Zhu , Yanming Fu , Yougui Li . Improvement of the Resolution Experiment of Racemic Tartaric Acid. University Chemistry, 2025, 40(7): 277-285. doi: 10.12461/PKU.DXHX202408010
3. [3]
  Xuewei Qian , Xingwen Sun , Houjin Li , Zhanxiang Liu , Yuan Zheng , Lin Wu , Shuanglian Cai , Ying Xiong , Guangao Yu , Qingwen Liu , Jie Han , Xin Du , Chengshan Yuan , Qihan Zhang , Shuyong Zhang , Jianrong Zhang . Basic Operations and Specification Suggestions for Organic Chemical Recrystallization Experiments. University Chemistry, 2025, 40(5): 66-75. doi: 10.12461/PKU.DXHX202503126
4. [4]
  Chengshan Yuan , Xiaolong Li , Xiuping Yang , Xiangfeng Shao , Zitong Liu , Xiaolei Wang , Yongwen Shen . Standardized Operational Guidelines for Mixed-Solvent Recrystallization in Organic Chemistry Experiment. University Chemistry, 2025, 40(5): 122-127. doi: 10.12461/PKU.DXHX202504073
5. [5]
  Zhi Chai , Huashan Huang , Xukai Shi , Yujing Lan , Zhentao Yuan , Hong Yan . Wittig反应的立体选择性. University Chemistry, 2025, 40(8): 192-201. doi: 10.12461/PKU.DXHX202410046
6. [6]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
7. [7]
  Shi-Yu Lu , Wenzhao Dou , Jun Zhang , Ling Wang , Chunjie Wu , Huan Yi , Rong Wang , Meng Jin . Amorphous-Crystalline Interfaces Coupling of CrS/CoS₂ Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(8): 2308024-0. doi: 10.3866/PKU.WHXB202308024
8. [8]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . Simultaneously Improving Inter-Plane Crystallization and Incorporating K Atoms in g-C₃N₄ Photocatalyst for Highly-Efficient H₂O₂ Photosynthesis. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-0. doi: 10.3866/PKU.WHXB202406005
9. [9]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . Remarkable Photocatalytic H₂O₂ Production Efficiency over Ultrathin g-C₃N₄ Nanosheet with Large Surface Area and Enhanced Crystallinity by Two-Step Calcination. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-0. doi: 10.3866/PKU.WHXB202406019
10. [10]
  Chengxia Tong , Yajie Li , Jin Yan , Xuejian Qu , Shigang Wei , Yong Fan , Zhiguang Song , Yupeng Guo . The Construction and Practice of a Comprehensive and Three-Dimensional Practical Education Model. University Chemistry, 2024, 39(7): 49-55. doi: 10.12461/PKU.DXHX202404155
11. [11]
  Zhiming Feng , Lili Wu , Chengming Wang . Doubly Oxidized Carbene. University Chemistry, 2025, 40(9): 326-331. doi: 10.12461/PKU.DXHX202411008
12. [12]
  Conghao Shi , Ranran Wang , Juli Jiang , Leyong Wang . The Illustration on Stereoisomers of Macrocycles Containing Multiple Chiral Centers via Tröger Base-based Macrocycles. University Chemistry, 2024, 39(7): 394-397. doi: 10.3866/PKU.DXHX202311034
13. [13]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
14. [14]
  Siwen Yuan , Qilin Wu , TianpengYin . NMR Spectroscopy Teaching Design Using the Mosher Method for Stereochemistry of Organic Compounds Based on BOPPPS Teaching Model. University Chemistry, 2025, 40(7): 161-168. doi: 10.12461/PKU.DXHX202502073
15. [15]
  Wanchun Zhu , Yongmei Liu , Li Wang , Yunshan Bai , Shu'e Song , Xiaokui Wang , Zhongyun Wu , Hong Yuan , Yunchao Li , Fuping Tian , Yuan Chun , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement and Control of Temperature. University Chemistry, 2025, 40(5): 128-136. doi: 10.12461/PKU.DXHX202503028
16. [16]
  Ziliang KANG , Jiamin ZHANG , Hong AN , Xiaohua LIU , Yang CHEN , Jinping LI , Libo LI . Preparation and water adsorption properties of CaCl₂@MOF-808 in-situ composite moulded particles. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2133-2140. doi: 10.11862/CJIC.20240282
17. [17]
  Yihan Xue , Xue Han , Jie Zhang , Xiaoru Wen . NCQDs修饰FeOOH基复合材料的制备及其电容脱盐性能. Acta Physico-Chimica Sinica, 2025, 41(7): 100072-0. doi: 10.1016/j.actphy.2025.100072
18. [18]
  Zeyu Liu , Wenze Huang , Yang Xiao , Jundong Zhang , Weijin Kong , Peng Wu , Chenzi Zhao , Aibing Chen , Qiang Zhang . Nanocomposite Current Collectors for Anode-Free All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2305040-0. doi: 10.3866/PKU.WHXB202305040
19. [19]
  Qiaoqiao BAI , Anqi ZHOU , Xiaowei LI , Tang LIU , Song LIU . Construction of pressure-temperature dual-functional flexible sensors and applications in biomedicine. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2259-2274. doi: 10.11862/CJIC.20240128
20. [20]
  Mingxin LU , Liyang ZHOU , Xiaoyu XU , Xiaoying FENG , Hui WANG , Bin YAN , Jie XU , Chao CHEN , Hui MEI , Feng GAO . Preparation of La-doped lead-based piezoelectric ceramics with both high electrical strain and Curie temperature. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 329-338. doi: 10.11862/CJIC.20240206

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(550)
HTML views(55)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142