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Citation: ZHU Xiaoming, FENG Yonglan, ZHANG Fuxing, YU Jiangxi, JIANG Wujiu, OU Yaping, KUANG Daizhi. Synthesis, Crystal Structure and Properties of Dinuclear Copper(Ⅱ) Complex {[Cu(Phen)(Nap)2]2·(EtOH)2·(H2O)2} (Phen=1,10-Phenanthroline; Nap=1-Naphthoic Acid; EtOH=Ethyl Alcohol)[J]. Chinese Journal of Applied Chemistry, ;2016, 33(8): 932-938. doi: 10.11944/j.issn.1000-0518.2016.08.150402 shu

Synthesis, Crystal Structure and Properties of Dinuclear Copper(Ⅱ) Complex {[Cu(Phen)(Nap)2]2·(EtOH)2·(H2O)2} (Phen=1,10-Phenanthroline; Nap=1-Naphthoic Acid; EtOH=Ethyl Alcohol)

  • 1.

    Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hu'nan Province, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hu'nan 421008, China

  • Corresponding author: KUANG Daizhi, 
  • Received Date: 16 November 2015
    Available Online: 25 January 2016

    Fund Project:

  • A new complex [Cu(Phen)(Nap)2]2·(EtOH)2·(H2O)2(Phen=1,10-phenanthroline; Nap=1-naphthoic acid; EtOH=ethyl alcohol) was synthesized. The compound was characterized by elemental analysis, FTIR, TG-DTG, single crystal X-ray diffraction. The complex is dinuclear copper(Ⅱ) structure. The electrochemical and luminescent properties of the complex was studied by cyclic voltammetry and emission spectrum. The interactions of the complex with calf thymus DNA(ct-DNA) has been studied by UV and fluorescence spectroscopy. The results show that the copper(Ⅱ) complex shows irreversible redox process, and possesses a fluorescent emission band at 416 nm, and this copper(Ⅱ) complex binds to ct-DNA in groove binding and its intrinsic binding constant Kb is 4.68×103 L/mol.
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    1. [1]

      [1] Akitsu T,Komorita S,Urushiyama A. Assignment of d-d Transitions of Square Planar [CuⅡN4] Complexes Containing Imidate and Amine Ligands by Means of Polarized Crystal Spectra[J]. Bull Chem Soc Jpn,2001,74(5):851-860.

    2. [2]

      [2] Akitsu T,Komorita S,Tamura H. Diastereomers of Copper(Ⅱ) Complexes Exhibiting Difference in Coordination Geometry by R- or S-1-Phenylethylamine Ligands in the Solid State and Structural Conversion of Crystals into Solutions[J]. Inorg Chim Acta,2003,348(10):25-32.

    3. [3]

      [3] LI Hong,LE Xueyi,WU Jianzhong,et al. Studies on the Interaction Between Copper(II) Complex with Phenanthroline and L-Methionine Ligands and DNA[J]. Acta Chim Sin,2003,61(2):245-250(in Chinese).李红,乐学义,吴建中,等. 铜(Ⅱ)邻菲咯啉蛋氨酸配合物与DNA相互作用的研究[J]. 化学学报,2003,61(2):245-250.

    4. [4]

      [4] YIN Fuling,SHEN Jia,ZOU Jiajia,et al. Study on the Synthesis, Characterization, Crystal Structure and Anticancer Acitivity of a Bridging Ligand Complex of Cu(Ⅱ) with 2,2'-Bipyridine and Demethylcantharate[J]. Acta Chim Sin,2003,61(4):556-561(in chinese).尹富铃,申佳,邹佳嘉,等. 2,2'-联吡啶和去甲基斑蝥酸根桥联双核铜(Ⅱ)配合物的合成、结构表征及抗癌活性的研究[J]. 化学学报,2003,61(4):556-561.

    5. [5]

      [5] XIA Sifeng,LU Xiaoming. Progress of Anticancer Activities of Copper Complexes with 1,10-Phenanthroline and Its Derivatives[J]. Chemistry,2011,74(12):1096 -1104(in Chinese).夏寺丰,鲁晓明. 1,10-菲咯啉及其衍生物铜配合物的抗癌活性研究进展[J]. 化学通报,2011,74(12):1096-1104.

    6. [6]

      [6] Lu J Y. Crystal Engineering of Cu-containing Metal-organic Coordination Polymers Under Hydrothermal Conditions[J]. Coord Chem Rev,2003,246(1/2):327-347.

    7. [7]

      [7] ZHAO Xiaofei,XU Jingyuan,XIE Chengzhi,et al. Two Polypyridyl Copper(Ⅱ) Complexes Interact with Human Bovine Serum[J]. J Tianjin Med Univ,2013,19(4):279-281(in Chinese).赵晓飞,徐靖源,谢承志,等. 两个多吡啶铜配合物与人血清蛋白的相互作用[J]. 天津医科大学学报,2013,19(4):279-281.

    8. [8]

      [8] Yang E C,Dai P X,Wang X G,et al. Two Discrete Lanthanum(Ⅲ) Complexes with Bulky Aromatic Mixed Ligands:Syntheses, Crystal Structures and Fluorescent Properties[J]. Z Anorg Allg Chem,2009,635(2):346-350.

    9. [9]

      [9] Yang S P,Yang H,Yu X B,et al. Synthesis, Structure and Fluorescence of Eu2(NAP)6(PHEN)2(NAPH=α-Naphthoic Acid; PHEN=1,10-Phenanthroline)[J]. J Mol Struct,2003,659(1/2/3):97-102.

    10. [10]

      [10] Song Y M,Luo F,Luo M B,et al. The Application of Single-crystal-to-single-crystal Transformation Towards Adjustable SMM Properties[J]. Chem Commun,2012,48(7):1006-1008.

    11. [11]

      [11] YANG Hong,WANG Zemin,YU Xibin,et al. Characterization of Ternary Complexes of Rare Earth(La3+,Eu3+,Tb3+) with α-Naphthoic Acid and 1,10-Phenanthroline[J]. Chem Res,2013,14(2):35-38(in Chinese).杨红,王则民,余锡宾,等. 稀土(La3+,Eu3+,Tb3+)萘甲酸邻菲咯啉三元配合物的性质[J]. 化学研究,2013,14(2):35-38.

    12. [12]

      [12] BIAN Lin, LI Lianzhi,WANG Xia,et al. Synthesis, Crystal Structure and DNA-Binding Studies of an Oxovanadium(Ⅳ) Complex [VO(Naph-Phe)(Phen)] with Mixed-Ligands[J]. Chinese J Inorg Chem,2011,27(4):649-654(in Chinese).边琳,李连之,王霞,等. 混配氧钒配合物[VO(Naph-Phe)(Phen)]的合成、晶体结构及与DNA作用研究[J]. 无机化学学报,2011,27(4):649-654.

    13. [13]

      [13] George M S. SHELXTL-97:Program for Crystal Structure Analysis. Göttingen[M]. University of Göttingen,1997.

    14. [14]

      [14] MENG Yue,GAO Yang,ZHAO Mingxing,et al. Synthesis, Characterizations and Crystal Structure of Binuclear Copper(Ⅱ) Complex Cu2(2,2'-bpy)2(2-bba)4[J]. Chemistry,2014,77(8):809-813(in Chinese).孟跃,高杨,赵明星,等. 双核铜配合物Cu2(2,2'-bpy)2(2-bba)4的合成、表征与晶体结构[J]. 化学通报,2014,77(8):809-813.

    15. [15]

      [15] WENG Shifu. Fourier Translation Infrared Spectroscopy Analysis:[M]. The Second Edition.Beijing:Chemical Industry Press,2005:305-306(in Chinese).翁诗甫. 傅里叶变换红外光谱分析[M]. 第2版. 北京:化学工业出版社,2005:305-306.

    16. [16]

      [16] YANG Shuping,HAN Lijun,PAN Yan,et al. Synthesis, Crystal Structure and Antibacterial Activity of a Bismuth(Ⅲ) Complex [Bi2(PPA)6·(Phen)2] with Phenylacetic Acid and 1,10-Phenanthroline[J]. Acta Chim Sin,2012,70(4):519-524(in Chinese).杨树平,韩立军,潘燕,等. 铋(Ⅲ)苯乙酸-1,10-邻菲罗啉三元配合物[Bi2(PPA)6·(Phen)2]的合成、晶体结构及抑菌活性[J]. 化学学报,2012,70(4):519-524.

    17. [17]

      [17] ZHANG Xiaoge,GAO Loujun,CHEN Xiaoli,et al. Syntheses, Crystal Structures and Fluorescent Properties of Zinc/Cadmium Complexes Based on Tetranuclear Metal Unit[J]. Chinese J Inorg Chem,2015,31(4):739-748(in Chinese).张潇戈,高楼军,陈小莉,等. 基于四核金属单元的锌/镉配合物的合成、晶体结构及荧光性质[J]. 无机化学学报,2015,31(4):739-748.

    18. [18]

      [18] MA Feng,ZHAO Lianhua,CHEN Zhaoxiang,et al. Hydrothermal Synthesis, Crystal Structure and Fluorescent Property of a Supramolecular Compound [Cu2(phen)2(H2O)4]·(SO4)2[J]. J Huaiyin Teachers College,2011,10(1):39-44(in Chinese).马凤,赵莲花,陈兆祥,等. 三维超分子化合物[Cu2(phen)2(H2O)4]·(SO4)2的水热合成、晶体结构及荧光性质研究[J]. 淮阴师范学院学报,2011,10(1):39-44.

    19. [19]

      [19] LI Dongping,CHEN Zhimin,KUANG Yunfei,et al. Synthesis, Crystal Structure and Electrochemical Properties of [Cu(NPA)2(Im)2(H2O)]·H2O[J]. Chinese J Inorg Chem,2007,23(5):892-896(in Chinese).李东平,陈志敏,匡云飞,等. 配合物[Cu(NPA)2(Im)2(H2O)]·H2O的合成、晶体结构及电化学性质[J]. 无机化学学报,2007,23(5):892-896.

    20. [20]

      [20] NIU Maofei,CHANG Wenming, NIU Meiju. Synthesis, Crystal Structure and DNA Interaction of Substituted Aromatic Crown Ether and Its Complexes[J]. Chinese J Inorg Chem,2014,30(9):2049-2056(in Chinese).牛茂斐,常文明,牛美菊. 取代芳香族冠醚配合物的合成、晶体结构及其与DNA相互作用的研究[J]. 无机化学学报,2014,30(9):2049-2056.

    21. [21]

      [21] XU Jin'gou,WANG Zunben. Fluorescence Analysis[M]. The Third Edition. Beijing:Science Press,2006:64-70(in Chinese).许金钩,王尊本. 荧光分析法[M]. 第三版. 北京:科学出版社,2006:64-70.

    22. [22]

      [22] ZHANG Bingwei,LI Bo,XIA Wenshui,et al. Selection of Models in the Calculation of Binding Constants in the Study of Interaction Between Molecules by Fluorescence Spectroscopy[J]. Prog Pharm Sci,2011,35(7):296-303(in Chinese).张冰卫,李博,夏文水,等. 用荧光光谱法研究分子间结合常数和结合位点数时的公式选择[J]. 药学进展,2011,35(7):296-303.

    23. [23]

      [23] LI Haiping,WANG Liting,WANG Ting,et al. Study on the Weak Interaction Between Metal Complexes and DNA—A New Undergraduate Comprehensive Experiment[J]. China Mod Educ Equip,2008,68(10):73-76(in Chinese).李海平,王丽婷,王婷,等. 金属配合物与DNA的弱相互作用研究—一个新的本科综合实验[J]. 中国现代教育装备,2008,68(10):73-76.

    24. [24]

      [24] ZHANG Qianling,LIU Jianhong,REN Xiangzhong,et al. Studies on the Formation, DNA-Binding and Luminescent Properties of New Heterobimetallic Complexes[J]. Acta Chim Sin,2006,64(10):968-974(in Chinese).张黔玲,刘剑洪,任祥忠,等. 新型双核配合物的形成、与DNA的作用机制及荧光性质研究[J]. 化学学报,2006,64(10):968-974.

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