Citation: LI Nana, JIANG Guowei, ZHOU Guangyuan, JIANG Zhenhua, WANG Huawei. Synthesis and Application Progress of Organic Phosphorus-Containing Flame Retardants[J]. Chinese Journal of Applied Chemistry, ;2016, 33(6): 611-623. doi: 10.11944/j.issn.1000-0518.2016.06.150299 shu

Synthesis and Application Progress of Organic Phosphorus-Containing Flame Retardants

1.
a Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2.
b University of Chinese Academy of Sciences, Beijing 100049, China;
3.
c College of Chemistry, Jilin University, Changchun 130012, China;
4.
d Tianjin Dagu Chemical Co., LTD, Tianjin 300450, China

Corresponding author: ZHOU Guangyuan,
Received Date: 17 August 2015
Available Online: 28 October 2015

Organic phosphorus-containing flame retardants have good characteristics, such as high efficiency, low toxicity, no pollution and smokeless. To date, research of synthesis and application in this field attracts a lot of attention. This paper reviewed recent developments, current status and potential future trends of organic phosphorus-containing flame retardants. The classification and mechanism of organic phosphorus-containing flame retardants were also introduced. The development and problems in the application were outlined considering the aspects of organic phosphorus-containing fire retardants.
- phosphorus-containing,
- flame-retardant mechanism,
- classification,
- development
1. [1]
  [1] Cho C S,Fu S C,Chen L W,et al.Aryl Phosphinate Anhydride Curing for Flame Retardant Epoxy Networks[J].Polym Int,1998,47(2):203-209.
2. [2]
  [2] Ravey M,Weil E D,Keidar I,et al.Flexible Polyurethane Foam.Ⅱ.Fire Retardation by Tris (1,3-Dichloro-2-Propyl) Phosphate.Part B.Examination of the Condensed Phase (the Pyrolysis Zone)[J].J Appl Polym Sci,1998,68(2):231-254.
3. [3]
  [3] Nisshihara H,Taun S,Kanatani R.Interactions Between Phosphorus and Nitrogen-Containing Flame Retardants[J].Polym J,1998,30(3):163-167.
4. [4]
  [4] Antony R,Pillai C K S.Synthesis and Thermal Characterization of Chemically Modified Cardanol Polymers[J].J Appl Polym Sci,1993,49(12):2129-2135.
5. [5]
  [5] Davies D,Horrocks A R.Nitrogen Phosphorous Antagonism in Flame-retardant Cotton[J].J Appl Polym Sci,1986,31(6):1655-1662.
6. [6]
  [6] Mandal H,Hay A S.Polycyclic Phosphonate Resins:Thermally Cross-linkable Intermediates for Flame-retardant Materials[J].J Polym Sci,Part A:Polym Chem,1998,36(11):1911-1918.
7. [7]
  [7] Horold S.Phosphorus Flame Retardants in Thermoset Resins[J].Polym Degrad Stab,1999,64(3):427-431.
8. [8]
  [8] Stackman R W.Phosphorus based Additives for Flame Retardant Polyester.1.Low Molecular Weight Wdditives[J].Ind Eng Chem Prod Res Dev,1982,21(2):328-331.
9. [9]
  [9] Stackman R W.Phosphorus Based Additives for Flame Retardant Polyester.2.Polymeric Phosphorus Esters[J].Ind Eng Chem Prod Res Dev,1982,21(2):332-336.
10. [10]
  [10] Liu Y L,Hsiue G H,Lan C W,et al.Flame-retardant Polyurethanes From Phosphorus-containing Isocyanates[J].J Polym Sci,Part A:Polym Chem,1996,35(9):1769-1780.
11. [11]
  [11] Banerjee S,Palit S K,Malti S.Phosphorus Containing Polymers.3.Polyimidophosphonates[J].J Polym Sci,Part A:Polym Chem,1994,32(2):219-227.
12. [12]
  [12] Green J.Phosphorus-bromine Flame Retardant Synergy in Polycarbonate/ABS Blends[J].Polym Degrad Stab,1996,54(2/3):189-193.
13. [13]
  [13] Liu Y L,Hsiue C H,Chiu Y S,et al.Synthesis and Flame-retardant Properties of Phosphorus-containing Polymers Based on Poly (4-hydroxystyrene)[J].J Appl Polym Sci,1996,59(10):1619-1625.
14. [14]
  [14] Ma Z L,Zhao W G,Liu Y F,et al.Synthesis and Properties of Intumescent,Phosphorus-containing,Flame-retardant Polyesters[J].J Appl Polym Sci,1997,63(12):1511-1515.
15. [15]
  [15] Antony R,Pillai C K S.Synthesis and Thermal Characterization of Chemically Modified Phenolic Resins[J].J Appl Polym Sci,1994,54(4):429-438.
16. [16]
  [16] Liu Y L,Hsiue G H,Lan C W,et al.Synthesis,Thermal Properties,and Flame Retardancy of Phosphorus Containing Polyimides[J].J Appl Polym Sci,1997,63(7):875-882.
17. [17]
  [17] Tang H I,Lin R K,Way T F,et al.A Study of Thermal Stability of Polyester Containing Phenyl Phosphonate Unit for Flame Retardant Fiber[J].Polym Degrad Stab,1996,54(2/3):313-377.
18. [18]
  [18] Annakutty K S,Kishore K.Pyrolysis Gas Chromatographic Studies on Polyphosphate Esters of Bisphenol A[J].Macromol Chem Phys,1991,192(1):11-20.
19. [19]
  [19] Duquesne S,Lefebvre J,Seeley G,et al.Vinyl Acetate/butyl Acrylate Copolymers Part 2:Fire Retardancy Using Phosphorus-containing Additives and Monomers[J].Polym Degrad Stab,2004,85(2):883-892.
20. [20]
  [20] Laoutid F,Ferry L,Lopez J M,et al.Red Phosphorus/aluminium Oxide Compositions as Flame Retardants in Recycled Poly (ethylene terephthalate)[J].Polym Degrad Stab,2003,82(2):357-363.
21. [21]
  [21] ZHANG Jun.Polymer Combustion and Flame Retardant Technology[M].Beijing:Chemical Industry Press,2005,268-275(in Chinese).张军.聚合物燃烧与阻燃技术[M].北京:化学工业出版社,2005,268-275.
22. [22]
  [22] Sponton M,Ronda J C,Galia M,et al.Cone Calorimetry Studies of Benzoxazine-epoxy Systems Flame Retarded by Chemically Bonded Phosphorus or Silicon[J].Polym Degrad Stab,2009,94(1):102-106.
23. [23]
  [23] Sun D C,Yao Y W.Synthesis of Three Novel Phosphorus-containing Flame Retardants and Their Application in Epoxy Resins[J].Polym Degrad Stab,2011,96(10):1720-1724.
24. [24]
  [24] Guo Y N,Qiu J J,Tang H Q,et al.High Transmittance and Environment-friendly Flame-resistant Opticalr Resins Based on Poly (methyl methacrylate) and Cyclotriphosphazene Derivatives[J].J Appl Polym Sci,2011,121(2):727-734.
25. [25]
  [25] Wu C S,Liu Y L,Chiu Y S,et al.Thermal Stability of Epoxy Resins Containing Flame Retardant Components:An Evaluation with Thermogravimetric Analysis[J].Polym Degrad Stab,2002,78(1):41-48.
26. [26]
  [26] Wu C S,Liu Y L,Chiu Y S.Epoxy Resins Possessing Flame Retardant Elements from Silicon Incorporated Epoxy Compounds Cured with Phosphorus or Nitrogen Containing Curing Agents[J].Polymer,2002,43(15):4277-4284.
27. [27]
  [27] Liu Y,Wang Q.Reactive Extrusion to Synthesize Intumescent Flame Retardant with a Solid Acid as Catalyst and the Flame Retardancy of the Products in Polypropylene[J].J Appl Polym Sci,2008,107(1):14-20.
28. [28]
  [28] Shankwalkar S G,Placck D G.Oxidation and Weight loss Characteristics of Commercial Phosphate Esters[J].Ind Eng Chem Res,1992,31(7):1810-1813.
29. [29]
  [29] Matuschek G.Thermal-degradation of Different Fire Retardant Polyurethane Foams[J].Thermochim Acta,1995,263:59-71.
30. [30]
  [30] Reshetnikov I,Anonov A,Rudakova T,et al.Some Aspects of Intumescent Fire Rctardant Systems[J].Polym Degrad Stab,1996,54(2/3):137-141.
31. [31]
  [31] Kpura A A.Chemistry of Flame Retardants:3.Aging of n-Methylol-3-dimethoxyphosphoryl Propionamide and Commercial Flame Retardant for Fabrics Containing This Substance[J].J Fire Sci,1996,14(3):169-183.
32. [32]
  [32] XIN Fei.Preparation and Characterization of Resorcinol Bis (diphenyl phosphate) Oligomer[J].New Chem Mater,2011,39(7):123-125(in Chinese).辛菲.无卤阻燃剂间苯二酚双(二苯基)磷酸酯的合成及表征[J].化工新型材料,2011,39(7):123-125.
33. [33]
  [33] FU Quanjun,WANG Xinlong,ZHANG Zhiye,et al.Synehesis and Application of Phosphorus Flame Retardant HDP/ABS Composites[J].Acta Polym Sin,2013,2(2):166-173(in Chinese).付全军,王辛龙,张志业,等.磷酸酯阻燃剂HDP的合成工艺及其在ABS中的阻燃作用[J].高分子学报,2013,2(2):166-173.
34. [34]
  [34] FANG Keyi,LI Juan,KE Chenhao,et al.Promotion Effect of a Hyperbranched Polyphosphnate Ester Flame Retardant on Char Formation of Polyamide 6[J].Acta Polym Sin,2011,1(1):55-62(in Chinese).方科益,李娟,柯晨皓,等.超支化聚磷酸酯阻燃剂对尼龙6的成炭促进作用[J].高分子学报,2011,1(1):55-62.
35. [35]
  [35] WU Denghui,ZHAO Peihua,ZHANG Mei,et al.Synthesis and Flame Retardant Properties of a Novel Monomolecular P-N Intumescent Flame Retardant[J].Chinese J Synth Chem,2013,21(5):530-533(in Chinese).毋登辉,赵培华,张美,等.新型单组分磷-氮膨胀型阻燃剂的合成及其阻燃性能[J].合成化学,2013,21(5):530-533.
36. [36]
  [36] Enescu D,Frache A,Lavaselli M,et al.Novel Phosphorous-nitrogen Intumescent Flame Retardant System.Its Effects on Flame Retardancy and Thermal Properties of Polypropylene[J].Polym Degrad Stab,2013,98(1):297-305.
37. [37]
  [37] Shariatinia Z,Javeri N,Shekarriz S,et al.Flame Retardant Cotton Fibers Produced Using Novel Synthesized Halogen-free Phosphoramide Nanoparticles[J].Carbohydr Polym,2015,118:183-198.
38. [38]
  [38] Yuan H X,Xing W Y,Zhang P,et al.Functionalization of Cotton with UV-cured Flame Retardant Coatings[J].Ind Eng Chem Res,2012,51(15):5394-5401.
39. [39]
  [39] ZHONG Liu,LIU Zhiguo,OU Yuxiang.Synthesis and Identification of Novel Halogen-contained Phosphate Ester and Its Application in PU Foam[J].Plastics,2008,37(5):27-30(in Chinese).钟柳,刘治国,欧育湘.新型含卤磷酸酯阻燃剂的合成、表征和应用[J].塑料,2008,37(5):27-30.
40. [40]
  [40] LU Lingang,ZHOU Xia,ZHAO Min,et al.Synthesis of Flame Retardant Bis (5,5-dibromomethyl-1,3,2-dioxanephosphoryl) Bisphenol A[J].Chem Res Appl,2009,21(12):1667-1670(in Chinese).卢林刚,周霞,赵敏,等.阻燃剂二(5,5-二溴甲基-1,3,2-二氧六环磷酰)双酚A的合成[J].化学研究与应用,2009,21(12):1667-1670.
41. [41]
  [41] WANG Huiya,ZHOU Xia,WANG Yongming,et al.Synthesis of Novel Mono-component P-Br Synergistic Flame Retardant 1,3-Bis (5,5-dibromomethyl-1,3-dioxaphosphori-nanyl-2-oxy) Benzene[J].Chem Reag,2010,32(1):52-54(in Chinese).王会娅,周霞,王永明,等.新型单组分磷溴协效阻燃剂1,3-二(5,5-二溴甲基-1,3-二氧杂己内磷酰氧基)苯的合成[J].化学试剂,2010,32(1):52-54.
42. [42]
  [42] MA Zhiling,CUI Haixiang,ZHANG Jiaojiao,et al.Synthesis and Applications of Intumescent Flame Retardant Dibromoneopentyl Glycol-phosphate Ester-melamine Salt[J].J Hebei Univ(Nat Sci Ed),2008,28(3):258-262(in Chinese).马志领,崔海香,张娇娇,等.膨胀型阻燃剂二溴新戊二醇磷酸酯三聚氰胺盐的合成及应用[J].河北大学学报(自然科学版),2008,28(3):258-262.
43. [43]
  [43] Nguyen C,Kim A.Synthesis of a Novel Nitrogen-phosphorus Flame Retardant Based on Phosphoramidate and Its Application to PC,PBT,EVA,and ABS[J].Macromol Res,2008,16(7):620-625.
44. [44]
  [44] WANG Dan,ZHOU Hao,ZHI Huizhen,et al.Synthesis of Halogen-free Flame Retardant 1,2-Ethylene Bis (dimethyl phosphonate)[J].Fine Chem,2011,4(28):389-392(in Chinese).王丹,周浩,职慧珍,等.无卤阻燃剂1,2-亚乙基双麟酸四甲酯的合成[J].精细化工,2011,4(28):389-392.
45. [45]
  [45] Peng H Q,Zhou Q,Wang D Y.A Novel Charring Agent Containing Caged Bicyclic Phosphate and Its Application in Intumescent Flame Retardant Polypropylene Systems[J].J Ind Eng Chem,2008,14(5):589-595.
46. [46]
  [46] Dumitrascu A,Howell B A.Flame-retarding Vinyl Polymers Using Phosphorus Functionalized Styrene Monomers[J].Polym Degrad Stab,2011,96(3):342-349.
47. [47]
  [47] Jiang D W,Sun C Y,Zhou Y N,et al.Enhanced Flame Retardancy of Cotton Fabrics with a Novel Intumescent Flame-retardant Finishing System[J].Fire Mater,2015,16(2):388-396.
48. [48]
  [48] Wyman P,Crook V,Ebdon J,et al.Flame-retarding Effects of Dialkyl-p-vinylbenzyl Phosphonates in Copolymers with Acrylonitrile[J].Polym Int,2006,55(7):764-771.
49. [49]
  [49] Fan R L,Guo L,Wang P Z,et al.Synthesis and Solubilities of 3,9-Dipyrolidino-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5] undecane-3,9-dioxide in Selected Solvents[J].Chem Eng Sci,2015,202(1):96-101.
50. [50]
  [50] Lin H T,Lin C H,Hu Y M,et al.An Approach to Develop High-T_g Epoxy Resins for Halogen-free Copper Clad Laminates[J].Polymer,2009,50(24):5685-5692.
51. [51]
  [51] Hoang D,Kim J,Jang B N.Synthesis and Performance of Cyclic Phosphorus-containing Flame Retardants[J].Polym Degrad Stab,2008,93(11):2042-2047.
52. [52]
  [52] Karatas S,Hosgor Z,Kayaman-Apohan N,et al.Preparation and Characterization of Phosphine Oxide Containing Organosilica Hybrid Coatings by Photopolymerization and Sol-gel Process[J].Prog Org Coat,2009,65(1):49-55.
53. [53]
  [53] Meenakshi K S,Sudhan E P J,Kumar S A.Development and Characterization of New Phosphorus Based Flame Retardant Tetraglycidyl Epoxy Nanocomposites for Aerospace Application[J].Bull Mater Sci,2012,35(2):129-136.
54. [54]
  [54] Yang X F,Li Q L,Chen Z P,et al.Study on Crystallization Behaviour of Co-polyamide 66 Containing Triaryl Phosphine Oxide[J].Bull Mater Sci,2012,35(2):233-242.
55. [55]
  [55] Rajasekaran R,Karikalchozhan C,Alagar M.Preparation and Characterization of 3,3'-Bis (maleimidophenyl) phenylphosphine Oxide (BMI)/polysulfone Modified Epoxy Intercrosslinked Matrices[J].Polym Compos,2008,29(7):773-781.
56. [56]
  [56] Sponton M,Ronda J C,Galia M,et al.Studies on Thermal and Flame Retardant Behaviour of Mixtures of Bis (m-aminophenyl) methylphosphine Oxide based Benzoxazine and Flycidylether or Benzoxazine of Bisphenol A[J].Polym Degrad Stab,2008,93(12):2158-2165.
57. [57]
  [57] Hua R,Sun J Z,Wu B J,et al.Synthesis and Properties of a Phosphorus-containing Flame Retardant Epoxy Resin Based on Bis-phenoxy (3-hydroxy) phenyl Phosphine Oxide[J].Polym Degrad Stab,2007,92(6):956-961.
58. [58]
  [58] Peng C,Wu Z J,Li J L,et al.Synthesis,Thermal and Mechanical Behavior of a Silicon/phosphorus Containing Epoxy Resin[J].J Appl Polym Sci,2015,132(46):DOI:10.1002/APP.42788.
59. [59]
  [59] Schafer A,Seibold S,Lohstroh W,et al.Synthesis and Properties of Flame-retardant Epoxy Resins Based on DOPO and One of Its Analog DPPO[J].J Appl Polym Sci,2007,105(2):685-696.
60. [60]
  [60] Vasiljevic J,Jerman I,Jaksa G,et al.Functionalization of Cellulose Fibres with DOPO-polysilsesquioxane Flame Retardant Nanocoating[J].Cellulose,2015,22(3):1893-1910.
61. [61]
  [61] Sablong R,Duchateau R,Koning C E,et al.Incorporation of a Flame Retardancy Enhancing Phosphorus-containing Diol into Poly (butylene terephthalate)via Solid State Polycondensation:A Comparative Study[J].Polym Degrad Stab,2011,96(3):334-341.
62. [62]
  [62] Pospiech D,Hauler L,Korwitz A,et al.The Miscibility of Poly (butylene terephthalate)(PBT) with Phosphorus Polyester Flame Retardants[J].High Perform Polym,2012,24(1):64-73.
63. [63]
  [63] Fischer O,Pospiech D,Korwitz A,et al.Synthesis and Properties of Phosphorus Polyesters with Systematically Altered Phosphorus Environment[J].Polym Degrad Stab,2011,96(12):2198-2208.
64. [64]
  [64] Lu L G,Wang X,Yang S S,et al.Synthesis and Application of Novel Arborescent Monomolecular P-N Intumescent Flameretardant[J].Acta Chim Sin,2012,70(2):190-194.
65. [65]
  [65] Lu L G,Wang X,Yang S S,et al.Synthesis and Charring of Arborescent Monomolecular P-N Intumescent Flameretardant[J].Polym Mater Sci Eng,2012,28(7):10-13.
66. [66]
  [66] Qian L,Feng F,Tang S.Bi-phase Flame-retardant Effect of Hexa-phenoxy-cyclotriphosphazeneon Rigid Polyurethane Foams Containing Expandable Graphite[J].Polymer,2014,55(1):95-101.
67. [67]
  [67] Qian L J,Ye L J,Xu G Z,et al.The Non-halogen Flame Retardant Epoxy Resin Based on a Novel Compound with Phosphaphenanthrene and Cyclotriphosphazene Double Functional Groups[J].Polym Degrad Stab,2011,96(6):1118-1124.
68. [68]
  [68] Balabanovich A I,Pospiech D.Pyrolysis Behavior of Phosphorus Polyesters[J].J Anal Appl Pyrolysis,2009,86(1):99-107.
69. [69]
  [69] Perret B,Schartel B.Novel DOPO-based Flame Retardants in High-performance Carbon Fibre Epoxy Composites for Aviation[J].Eur Polym J,2011,47(5):1081-1089.
70. [70]
  [70] Zhao C S,Huang F L,Xiong W C,et al.A Novel Halogen-free Flame Retardant for Glass-fiber-reinforced Poly (ethylene terephthalate)[J].Polym Degrad Stab,2008,93(6):1188-1193.
71. [71]
  [71] Ciesielski M,Schafer A,Doring M.Novel Efficient DOPO-based Flame-retardants for PWB Relevant Epoxy Resins with High Glass Transition Temperatures[J].Polym Adv Technol,2008,19(6):507-515.
72. [72]
  [72] Zhang X,Zhong Y,Mao Z P.The Flame Retardancy and Thermal Stability Properties of Poly (ethylene terephthalate)/hexakis (4-nitrophenoxy) cyclotriphosphazene Systems[J].Polym Degrad Stab,2012,97(8):1504-1510.
73. [73]
  [73] Despinasse M,Schartel B.Influence of the Structure of Aryl Phosphates on the Flame Retardancy of Polycarbonate/acrylonitrile-butadiene-styrene[J].Polym Degrad Stab,2012,97(12):2571-2580.
74. [74]
  [74] BAN Daming,LIU Jiping.Synthesis,Characterization and Thermal Stability of Poly (resorcine phenyl phosphate)[J].Chem J Chinese Univ,2013,24(5):1284-1287(in Chinese).班大明,刘吉平.聚苯基磷酸间苯二酚酯的合成、表征及热性能[J].高等学校化学学报,2013,24(5):1284-1287.
75. [75]
  [75] Li N N,Jiang G W,Zhou G Y.Synthesis and Characterization of a Cyclic 9,9-Bis (4-hydroxyphenyl) fluorine (phenylene phosphonate) oligomer and Its Flame Retardancy Application[J].RSC Adv,2015,5(96):78815-78822.
76. [76]
  [76] Wang X,Song L,Xing W Y,et al.A Effective Flame Retardant for Epoxy Resins Based on Poly (DOPO Substituted Dihydroxyl Phenyl Pentaerythritol Diphosphonate)[J].Mater Chem Phys,2011,125(3):536-541.
77. [77]
  [77] Wang X,Hu Y,Song L,et al.Synthesis and Characterization of a DOPO-substitued Organophosphorus Oligomer and Its Application in Flame Retardant Epoxy Resins[J].Prog Org Coat,2011,71(1):72-82.
78. [78]
  [78] Wang X,Hu Y,Song L,et al.Thermal Degradation Mechanism of Flame Retarded Epoxy Resins with a DOPO-substitued Organophosphorus Oligomer by TG-FTIR and DP-MS[J].J Anal Appl Pyrolysis,2011,92(1):1641-1670.
79. [79]
  [79] Ma H Y,Tong L F,Xu Z B,et al.A Novel Intumescent Flame Retardant:Synthesis and Application in ABS Copolymer[J].Polym Degrad Stab,2007,92(4):720-726.
80. [80]
  [80] Zhou C,Wei Z Y,Yu Y,et al.Synthesis and Crystallization Behavior of Novel Poly (butylene succinate) copolyesters Containing Phosphorus Pendent Groups[J].J Therm Anal Calorim,2015,120(3):1799-1810.
81. [81]
  [81] Zhang J B,Wang X L,He Q X,et al.A Novel Phosphorus-containing Poly (1,4-cyclohexylenedimethylene terephthalate) copolyester:Synthesis,Thermal Stability,Flammability and Pyrolysis Behavior[J].Polym Degrad Stab,2014,108(SI):12-22.
82. [82]
  [82] Chen L,Ruan C,Yang R,et al.Phosphorus-containing Thermotropic Liquid Crystalline Polymers:A Class of Efficient Polymeric Flame Retardants[J].Polym Chem,2014,5(12):3737-3749.
83. [83]
  [83] Lin C H,Huang C M,Wang M W,et al.Synthesis of a Phosphinated Acetoxybenzoic Acid and Its Application in Enhancing Tg and Flame Retardancy of Poly (ethylene terephthalate)[J].J Polym Sci,Part A:Polym Chem,2014,52(3):424-434.
84. [84]
  [84] Lai,X J,Tang,S,Li,H Q,et al.Flame-retardant Mechanism of a Novel Polymeric Intumescent Flame Retardant Containing Caged Bicyclic Phosphate for Polypropylene[J].Polym Degrad Stab,2015,113:22-31.
85. [85]
  [85] DU Dajiang,CAO Fangli,CHEN Jia,et al.Synthesis of P-N Synergistic Alkyl Phosphinate Flame Retardants and Its Application on PBT[J].J Jianghan Univ(Nat Sci Ed),2015,43(1):19-23(in Chinese).杜大江,曹芳利,陈佳,等.磷-氮协效型烷基次膦酸盐阻燃剂的合成及其在PBT中的应用[J].江汉大学学报(自然科学版),2015,43(1):19-23.
86. [86]
  [86] XU Jianzhong,LIU Xin,QU Hongqiang,et al.Application of Hypophosphite Flame Retardant in PBT and Its Synthesis[J].Plast Sci Technol,2013,41(11):90-95(in Chinese).徐建中,刘欣,屈红强,等.次磷酸盐阻燃剂的合成及其在PBT中的应用[J].塑料科技,2013,41(11):90-95.
87. [87]
  [87] Chen L,Luo Y,Hu Z,et al.An Efficient Halogen-free Flame Retardant for Glass-fibre-reinforced Poly (butylene terephthalate)[J].Polym Degrad Stab,2012,97(2):158-165.
88. [88]
  [88] Yan,H W,Wei,J L,Yin B,et al.Effect of the Surface Modification of Ammonium Polyphosphate on the Structure and Property of Melamine-formaldehyde Resin Microencapsulated Ammonium Polyphosphate and Polypropylene Flame Retardant Composites[J].Polym Bull,2015,72(11):2725-2737.
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沈阳化工大学材料科学与工程学院沈阳 110142