Citation: CHANG Yu, XIE Wenbing, ZHOU Shihong, LI Junling, LIU Baofeng, PAN Lihua. Synthesis and Spectroscopic Properties of a Cryptate Rare Earth Fluorescence Complex[J]. Chinese Journal of Applied Chemistry, ;2017, 34(3): 361-366. doi: 10.11944/j.issn.1000-0518.2016.03.160232 shu

Synthesis and Spectroscopic Properties of a Cryptate Rare Earth Fluorescence Complex

Laboratory of Polymer Composites Engineering, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: PAN Lihua, lihuap@ciac.ac.cn
Received Date: 2 June 2016
Revised Date: 14 July 2016
Accepted Date: 25 August 2016

Fund Project: Supported by the Science and Technology Development Project of Jilin Province of China No.20150204010YY

Figures(8)

A bifuntional cryptate chelate 2, 6-{N, N', N, N'-[bis (2, 2'-bipyridine-6, 6'-dimethyl)]bis (aminomethyl)}-pyridine-3, 5-diethyl diester for homogeneous time-resolved fluorimmunoassay product was synthesized from the raw material diethyl 2, 6-dimethylpyridine-3, 5-dicarboxylate through N-bromobutanimide (NBS) bromination, electrophilic substitution. The structure and property were confirmed by differential thermal analysis (DTA) Fourier transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance spectroscopy (¹H NMR) and mass spectrometry (MS). Also, the spectral properties of the Eu (Ⅲ)-cryptate chelate, such as absorption spectra, emission spectra, and fluorescence lifetime, were discussed. The fluorescence spectroscopic properties of Eu (Ⅲ)-cryptate are as follows:the excitation peak is at 322 nm, the narrow emission spectrum peaks are at 597 nm (⁵D₀-⁷F₁) and 618 nm (⁵D₀-⁷F₂), respectively, the Stokes shift is 290 nm, the fluorescence lifetime is 918 μs, and the fluorescence quantum yield is Φ=0.249.
- homogeneous time-resolved fluorescence immunoassay,
- chelate,
- synthesis,
- cryptate bipyridine derivative
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