Citation: CHEN Lidong, LIU Di, NIU Siqi, JIANG Chunjie, LIU Liping, WANG Xiangsheng, ZHU Jiang. Oxidative Desulfurization of Organic Sulfides over Phosphotungstic Acid/Nano-ZSM-5 Composite Catalyst[J]. Chinese Journal of Applied Chemistry, ;2016, 33(3): 364-366. doi: 10.11944/j.issn.1000-0518.2016.03.150339 shu

Oxidative Desulfurization of Organic Sulfides over Phosphotungstic Acid/Nano-ZSM-5 Composite Catalyst

CHEN Lidong ^a,, ,
LIU Di ^a ,
NIU Siqi ^a ,
JIANG Chunjie ^a ,
LIU Liping ^b ,
WANG Xiangsheng ^b ,
ZHU Jiang ^a,,

a.
a. Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 110629, China;
b.
b. School of Chemistry Engineering, Dalian University of Technology, Dalian, Liaoning 110624, China

Corresponding author: CHEN Lidong, ZHU Jiang,
Received Date: 18 September 2015
Available Online: 26 October 2015
Fund Project:

The phosphotungstic acid(HPW)/nano-ZSM-5 catalyst was prepared by the impregnation method. When the nano-ZSM-5 is supported by HPW alone, the Keggin structure HPW changes to a Dawson structure heteropoly compounds, and the Keggin structure remains unchanged after binding with nickel salt. With oxidative desulfurization of organic sulfides as a probe, the oil desulfurization rate in simulation oils with dibenzothiophene components of n-octane reaches 94.5% at 40℃.
- phosphotungstic acid,
- nano-ZSM-5 zeolite,
- oxidative desulfurization,
- n-octane
1. [1]
  [1] Omwoma S,Gore C T,Ji Y C,et al. Environmentally Benign Polyoxometalate Materials[J]. Coord Chem Rev,2015,286(1):17-29.
2. [2]
  [2] Li C,Jiang Z X,Gao J B,et al. Ultra-Deep Desulfurization of Diesel：Oxidation with a Recoverable Catalyst Assembled in Emulsion[J]. Chem Eur J,2004,10(9):2277-2280.
3. [3]
  [3] SONG Pengyue,ZHU Jiang,YU Bohao,et al. Study on the Performance of Phosphotungstic Acid-urea/Fe₃O₄ Magnetic Oxidative Desulfurization Catalyst[J]. Chinese J Appl Chem,2015,32(3):317-321(in Chinese).宋鹏月,朱江,于博浩,等. 磷钨酸-尿素/四氧化三铁磁性氧化脱硫催化剂反应性能[J]. 应用化学,2015,32(3):317-321.
4. [4]
  [4] Chen L D,Wang X S,Guo X W,et al. In Situ Nanocrystalline HZSM-5 Zeolites Encaged Heteropoly Acid H₃PMo₁₂O₄₀ and Ni Catalyst for Hydroconversion of n-Octane[J]. Chem Eng Sci,2007,62(16):4469-4478.
5. [5]
  [5] JIANG Chunjie,SUN Shengnan,WANG Xuyang,et al. Synthesis of Dimethyl Ether from Methanol over Heteropoly Acid/Nanocrystalline HZSM-5 Complex Solid Acidic Catalyst[J]. Acta Chim Sin,2013,71(5):810-814(in Chinese). 姜春杰,孙胜男,王旭阳,等. 甲醇脱水制二甲醚的杂多酸/纳米HZSM-5复合固体酸催化剂[J]. 化学学报,2013,71(5):810-814.
6. [6]
  [6] WANG Xuyang,SONG Pengyue,WANG Xiangsheng,et al. In-situ Characterization and Reactivity of Heteropoly Acid-based Catalysts for Deep Hydrodesulfurization of Fluid Catalytic Cracking Gasoline[J]. Chinese J Appl Chem,2014,31(8):990-992(in Chinese).王旭阳,宋鹏月,王祥生,等. 多酸基深度加氢脱硫催化剂的原位表征和反应性能[J]. 应用化学,2014,31(8):990-992.
7. [7]
  [7] Otsuki S,Nonaka T,Takashima N,et al. Oxidative Desulfurization of Light Gas Oil and Vacuum Gas Oil by Oxidation and Solvent Extraction[J]. Energy Fuels,2000,14(6):1232-1239.
8. [8]
  [8] Muñoz M,Romanelli G,Botto I L,et al. Al₁₃[X-Mo/WOn](X=Al,Co,V,P) Composites as Catalysts in Clean Oxidation of Aromatic Sulfides[J]. Appl Catal B:Environ,2010,73(1/2):311-316.
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