Citation: JIN Tingjia, ZHANG Xianglin, XU Jian. Preparation of Manganese Ferrite/Humic Acid Composite and Its Adsorption Properties for Methylene Blue[J]. Chinese Journal of Applied Chemistry, ;2016, 33(3): 336-342. doi: 10.11944/j.issn.1000-0518.2016.03.150257 shu

Preparation of Manganese Ferrite/Humic Acid Composite and Its Adsorption Properties for Methylene Blue

a.
a. Anhui Jianzhu University School of Materials and Chemical Engineering Hefei 230601, China;
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b. Anhui Province Key Laboratory of Advanced Building Materials, Hefei 230622, China

Corresponding author: ZHANG Xianglin,
Received Date: 21 July 2015
Available Online: 21 August 2015
Fund Project:

Humic acid(HA)-coated manganese ferrite(MnFe₂O₄/HA) magnetic composite materials were prepared with chemical coprecipitation method and its nanoparticles were characterzied by X-ray diffraction(XRD), scanning electron microscopy(SEM) and Fourier transform infrared(FT-IR) analysis. The results show that the size of the product is about 200 nm. MnFe₂O₄/HA has a typical spinel structure and is successfully coated with humic acid on its surface. The saturation magnetization of MnFe₂O₄/HA is 34.01 A·m²/kg. MnFe₂O₄/HA can be separated from water with low magnetic field within 30 seconds. The adsorption of methylene blue is a pseudo second-rate kinetic process and reaches equilibrium in about 2 h, in good agreement with the Langmuir adsorption model. MnFe₂O₄/HA has higher adsorption ability than that of pure MnFe₂O₄. The max adsorbing capacity can reach 29.94 mg/g at room temperature and pH=9. MnFe₂O₄/HA can be used as adsorption material for effective removal of methylene blue from waste water.
- manganese ferrite,
- humic acid,
- methylene blue,
- selective adsorption,
- regeneration
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