Citation: XIE Fazhi, SHENG Dandan, HU Tingting, LI Haibin, WANG Xuechun, XIE Zhiyong. Adsorption Behavior and Mechanism of Pyrophosphate on Goethite[J]. Chinese Journal of Applied Chemistry, ;2016, 33(3): 343-349. doi: 10.11944/j.issn.1000-0518.2016.03.150243 shu

Adsorption Behavior and Mechanism of Pyrophosphate on Goethite

a.
a. School of Materials Science and Chemical Engineering;
b.
b. Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei 230022, China

Corresponding author: XIE Fazhi,
Received Date: 10 July 2015
Available Online: 11 September 2015
Fund Project:

In order to study the fate and transport behavior of polyphosphate in water body, the adsorption process of pyrophosphate on synthetic goethite which stablely exists in the supergene environment has been studied systematically. The adsorption behaviors under different conditions(pH, electrolyte, time, temperature) were investigated and the adsorption mechanism was discussed. The results indicate that the adsorption capacity decreases from 3.00 mg/g to 0.75 mg/g with the increase of pH from 6.27 to 10.99. The lower the electrolyte concentration, the more favorable to the adsorption. The adsorption characteristic within 48 h was investigated. The adsorption capacity increases rapidly within 1 h, and then reaches the adsorption equilibrium. Moreover, the adsorption capacity increases with the increase of the adsorption temperature. Kinetic models and thermodynamic models were used to analyze the adsorption process, and the results show that the adsorption is in accord with the pseudo second-order equation and Langmuir model. Furthermore, combined with the characterization of materials, the adsorption may be mainly based on surface complexation and physical adsorption.
- goethite,
- pyrophosphate,
- adsorption,
- kinetic,
- thermodynamic
1. [1]
  [1] Barca C,Gerente C,Meyer D,et al. Phosphate Removal from Synthetic and Real Wastewater Using Steel Slags Produced in Europe[J]. Water Res,2012,46(7):2376-2384
2. [2]
  [2] Yan Y,Sun X,Ma F,et al. Removal of Phosphate from Wastewater Using Alkaline Residue[J]. J Environ Sci,2014,26(5):970-980.
3. [3]
  [3] ZHOU Jishi. Mechanism and Synergistic Effect on Capture of Polyphosphate by Polynary Layered Double Hydroxide(LDH)[D]. Shanghai:Shanghai University,2011(in Chinese).周吉峙. 多元 LDH 层状双氢氧化物捕集多聚磷酸盐的机制和协同效应[D]. 上海：上海大学,2011.
4. [4]
  [4] LIU Zhigang,YU Jingjing,LI Tie,et al. Study on the Form of Phosphorus in Urban Sewage Treatment Plant[J]. Water Wastewater Eng,2011,37(2):50-53(in Chinese).刘志刚,虞静静,李轶,等. 城市污水处理厂磷的形态变化规律研究[J]. 给水排水,2011,37(2):50-53.
5. [5]
  [5] Kulaev I S,Vagabov V,Kulakovskaya T. The Biochemistry of Inorganic Polyphosphates[M]. John Wiley & Sons,2005:90-93.
6. [6]
  [6] ZHENG Yiyun,ZHOU Boqing,LI Qin. Present Status and Development of Corrosion Inhibitors for Water Treatment[J]. Corros Sci Prot Technol,2004,16(2):101-104(in Chinese).郑逸云,周柏青,李芹. 水处理缓蚀剂应用现状与发展[J]. 腐蚀科学与防护技术,2004,16(2):101-104.
7. [7]
  [7] XU Wenwen. The Preliminary Study of Polyphosphates on the Quality of Cultured Lateolabrax Japonicus[D]. Zhejiang:Zhejiang Gongshang University,2010(in Chinese).许雯雯. 多聚磷酸盐对养殖鲈鱼品质影响的初步研究[D]. 浙江：浙江工商大学,2010.
8. [8]
  [8] WANG Yingying,GAO Hua,ZHANG Huizhen,et al. Determination of Polyphosphates in Aquatic Products by Ion Chromatography[J]. Qingdao Univ(E&T),2011,26(2):74-78(in Chinese).王莹莹,高华,张辉珍,等. 离子色谱法测定水产品中的多聚磷酸盐[J]. 青岛大学学报:工程技术版,2011,26(2):74-78.
9. [9]
  [9] EUROPA Food Safety-Rapid Alert System for Food and Feed(RASFF)[OL]. 2015-08-20.EU. http://ec.europa.Eu/food/food/rapidalert/archive_en.htm.
10. [10]
  [10] Yao Y,Gao B,Inyang M,et al. Removal of Phosphate from Aqueous Solution by Biochar Derived from Anaerobically Digested Sugar Beet Tailings[J]. J Hazard Mater,2011,190(1):501-507.
11. [11]
  [11] Xi B,Zhao Y,Zhang L,et al. Return Chemical Sludge Employed in Enhancement of Phosphate Removal from Wastewater[J]. Desalin Water Treat,2014,52(34/35/36):6639-6647.
12. [12]
  [12] Yao Y,Gao B,Chen J,et al. Engineered Carbon(Biochar) Prepared by Direct Pyrolysis of Mg-accumulated Tomato Tissues:Characterization and Phosphate Removal Potential[J]. Bioresour Technol,2013,138:8-13.
13. [13]
  [13] Long F,Gong J L,Zeng G M,et al. Removal of Phosphate from Aqueous Solution by Magnetic Fe Zr Binary Oxide[J]. Chem Eng J,2011,171(2):448-455.
14. [14]
  [14] de-Bashan L E,Bashan Y. Recent Advances in Removing Phosphorus from Wastewater and It's Future Use as Fertilizer(1997-2003)[J]. Water Res,2004,38:4222-4246.
15. [15]
  [15] HONG Hanlie,MIN Xinmin. Study on the Surface Chemistry of Minerals by Quantum Chemical Method[M]. Wuhan:China University of Geosciences Press,2004:126-130(in Chinese).洪汉烈,闵新民. 量子化学方法研究矿物的表面化学[M]. 武汉：中国地质大学出版社,2004:126-130
16. [16]
  [16] LIU Fan,JIE Xiaolei,HE Jizheng,et al. Coordination Forms and Transformations of Phosphate Adsorbed by Goethite Surface on Different pH[J]. Acta Pedol Sin,1997,34(4):367-374(in Chinese).刘凡,介晓磊,贺纪正,等. 不同pH条件下针铁矿表面磷的配位形式及转化特点[J]. 土壤学报,1997,34(4):367-374.
17. [17]
  [17] SONG Kang. Mechanism of Humic Acid Influence the Adsorption of Phosphate on Goethite[D]. Nanjing:Nanjing Normal University,2012(in Chinese).宋康. 腐殖酸对针铁矿吸附磷的影响机理研究[D]. 南京：南京师范大学,2012.
18. [18]
  [18] Liu H,Chen T,Frost R L. An Overview of the Role of Goethite Surfaces in the Environment[J]. Chemosphere,2014,103:1-11.
19. [19]
  [19] MAO Yanpeng. The Mechanism and Mathmatical Model Study on the Interaction Between Iron and Phosphate in Water[D]. Ji'nan:Shandong University,2012(in Chinese).毛岩鹏. 水体中铁盐与磷酸盐的相互作用机理及其数学模型研究[D]. 济南：山东大学,2012.
20. [20]
  [20] Schwertmann U,Cornell R M. Iron Oxides in the Laboratory[M]. New York:Wiley Online Library,1991.
21. [21]
  [21] Guan X. Adsorption of Phosphates and Organic Acids on Aluminum Hydroxide in Aquatic Environment-Mechanisms and Interactions[D]. Hong Kong:The Hong Kong University of Science Technology,2005.
22. [22]
  [22] Rashchi F,Finch J A. Polyphosphates:A Review Their Chemistry and Application with Particular Reference to Mineral Processing[J]. Miner Eng,2000,13(10):1019-1035.
23. [23]
  [23] Gao Y,Mucci A. Acid Base Reactions, Phosphate and Arsenate Complexation, and Their Competitive Adsorption at the Surface of Goethite in 0.7 M NaCl Solution[J]. Geochim Cosmochim Acta,2001,65(14):2361-2378.
24. [24]
  [24] Liu J,Wan L,Zhang L,et al. Effect of pH, Ionic Strength, and Temperature on the Phosphate Adsorption onto Lanthanum-doped Activated Carbon Fiber[J]. J Colloid Interface Sci,2011,364(2):490-496.
25. [25]
  [25] Kajiyoshi K,Sakabe Y. Preparation of a Barium Titanate Thin Film on a Porous Titanium Body by the Hydrothermal-Electrochemical Method[J]. J Am Ceram Soc,1999,82(11):2985-2992.
26. [26]
  [26] LI Ying. Interaction Between Heavy Metals,Humic Acid and Clay Particles in Water[D]. Ji'nan:Shandong University,2010(in Chinese).李颖. 水体中重金属,腐殖酸和粘土颗粒物之间的相互作用研究[D]. 济南：山东大学,2010.
27. [27]
  [27] Kumar K V,Sivanesan S. Comparison of Linear and Non-linear Method in Estimating the Sorption Isotherm Parameters for Safranin onto Activated Carbon[J]. J Hazard Mater,2005,123(1): 288-292.
28. [28]
  [28] Foo K Y,Hameed B H. Insights into the Modeling of Adsorption Isotherm Systems[J]. Chem Eng J,2010,156(1):2-10.
29. [29]
  [29] Soejoko D S,Tjia M O. Infrared Spectroscopy and X Ray Diffraction Study on the Morphological Variations of Carbonate and Phosphate Compounds in Giant Prawn(Macrobrachium Rosenbergii) Skeletons During Its Moulting Period[J]. J Mater Sci,2003,38(9):2087-2093.
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