Citation: YANG Jiandong, MA Rong, YAN Xiang, WANG douliu, LU Xiaoquan. Synthesis of Morphology-controllable Porphyrin Materials and Their Photoelectric Properties[J]. Chinese Journal of Applied Chemistry, ;2016, 33(3): 307-312. doi: 10.11944/j.issn.1000-0518.2016.03.150217 shu

Synthesis of Morphology-controllable Porphyrin Materials and Their Photoelectric Properties

YANG Jiandong ^a,b ,
MA Rong ^a ,
YAN Xiang ^a ,
WANG douliu ^a ,
LU Xiaoquan ^b,,

a.
a. Department of Biology & Chemistry, Longnan Normal College, Chengxian, Gansu 742500, China;
b.
b. Key Lab of Bioelectrochemisty & Environmental analysis of Gansu Province;Northwest Normal of University, Lanzhou 730070, China

Corresponding author: LU Xiaoquan,
Received Date: 29 June 2015
Available Online: 30 October 2015
Fund Project:

Various porphyrin-containing nanostructures were facilely synthesized by self-assembly technology via modulations of the pH of mixture solution. At low pH, one-dimensional bar is formed, and at high pH, two-dimensional lamellar structure appears. These nanostructures were analyzed by UV-Vis, IR and XRD. One dimensional J-aggregates is formed at low pH through the packing of porphyrin molecules by π-π, and electrostatic interactions. As the pH increases, hydrogen bond plays a key role to switch the porphyrin aggregates into two-dimensional sheets. Photoelectric property test shows a good response of the porphyrin nano-rods to the visible light. This kind of porphyrin nano materials with photoelectric response is expected to be a photoelectric element in electronic devices.
- preparing method,
- porphyrin nanomaterials,
- photoelectric properties
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