Citation:
HU Sanming, WEI Wei, YANG Tianbo, ZHENG Changmei, ZHENG Chunbai, DENG Pengyang. Properties of a New Type Heat-Resistant System of Epoxy Resin Cured at Room Temperature[J]. Chinese Journal of Applied Chemistry,
;2016, 33(2): 175-180.
doi:
10.11944/j.issn.1000-0518.2016.02.150223
-
Bisphenol-A epoxy resin E-51 was cured by [C6mim]FeCl4 and mixed amines at room temperature(20℃). Compared to other E-51 systems which were cured by aliphatic amine, E-51 systems cured by [C6mim]FeCl4/mixed amine have better mechanical properties, thermal properties, and aging properties. The effect of the amount of [C6mim]FeCl4 on the properties of the cured epoxy resin systems was also investigated. Tensile strength of the [C6mim]FeCl4/mixed amine cured E-51 system reaches 90 MPa, and the system maintains its excellent mechanical properties at high temperature(120℃). The TGA result shows that the decomposition temperature is 310℃ when the mass loss of epoxy system reaches 5%. Even after 7 days aging at 200℃, the tensile strength of the [C6mim]FeCl4/mixed amine cured epoxy resin system is 28 MPa. Therefore, the [C6mim]FeCl4/mixed amine cured epoxy resin system is a new type of epoxy resin cured system which can be applied under high temperature.
-
-
-
[1]
[1] SUN Manling,WU Liangyi. Application of The Principles and Techniques of Epoxy Resin[M]. Beijing:China Machine Press,2002:4-8(in Chinese).孙曼灵,吴良义. 环氧树脂应用原理及技术[M]. 北京:机械工业出版社,2002:4-8.
-
[2]
[2] CHEN Ping,LIU Shengping,WANG Dezhong. Epoxy Resin and Its Application[M]. BeiJing:Chemical Industry Press,2011:1-5(in Chinese).陈平,刘胜平,王德中.环氧树脂及其应用[M]. 北京:化学工业出版社,2011:1-5.
-
[3]
[3] SONG Junjun,ZHANG Jun. The Room Temperature Fast Curing Epoxy Adhesive Development Present Situation[J]. Heilongjiang Sci,2013,4(1):40-42(in Chinese).宋军军,张君. 室温快速固化环氧胶黏剂的发展现状[J]. 黑龙江科学,2013,4(1):40-42.
-
[4]
[4] WU Yanfei,HUANG Ying. Research Progress of Room Temperature Cured Heat-Resistant Adhesive[J]. Mater Develop Appl,2010,6:88-93(in Chinese).吴燕飞,黄英. 室温固化耐温胶黏剂研究进展[J]. 材料开发与应用,2010,6:88-93.
-
[5]
[5] DUAN Huajun,ZHANG Lianmeng,WANG Jun,et al. Study on the Properties of the Low Viscosity, Low Heat Liberation and High Toughening Curing Agent for Epoxy Resin[J]. Insulat Mater,2007,40(6):1-4(in Chinese).段华军,张联盟,王均,等. 低放热、低粘度、高韧性环氧树脂室温固化剂的性能研究[J]. 绝缘材料,2007,40(6):1-4.
-
[6]
[6] GONG Yunjin. Preparing TG301 Epoxy Resin Room Temperature Curing Agent with Modifed Hexanediamine[J]. China Adhes,1999,4(1):35-38(in Chinese).龚云金. 改性己二胺制备TG301环氧树脂室温固化剂[J]. 中国胶黏剂,1999,4(1):35-38.
-
[7]
[7] WANG Zhongyi,ZHANG Lianhong. Synthesis of Epoxy Resin Fast Curing Agent at Room Temperature[J]. Synth Resin Plast,2013,30(3):25-30(in Chinese).王钟熠,张连红. 环氧树脂室温快速固化剂的合成[J]. 合成树脂及塑料,2013,30(3):25-30.
-
[8]
[8] Dodiuk H,Kenig S,Liran I. Room Temperature Curing Epoxy Adhesives for Elevated Temperature Service[J]. J Adhes,1987,22(3):227-251.
-
[9]
[9] ZHANG Xiaobo,LIU Haiping. Study on Synthesis and Performance of Flexible Curing Agent for Room Temperature Curing Epoxy Resin Adhesive[J]. China Adhes,2008,17(5):1-4(in Chinese).张小博,刘海萍. 环氧树脂室温固化用柔性固化剂的制备与性能研究[J]. 中国胶黏剂,2008,17(5):1-4.
-
[10]
[10] XIA Lanjun,LI Fuzhi,XIONG Hejian,et al. Performance of Silicone Modified Epoxy Resin Curable at Room Temperature[J]. Adhesion,2013,4(54):1-5(in Chinese).夏兰君,李福志,熊和建,等. 有机硅改性环氧树脂及其室温固化的性能研究[J]. 粘接,2013,4(54):1-5.
-
[11]
[11] LI Xiaohua,YANG Fuming,ZHOU Qing,et al. Synthesis and Properties of 1-Methyl-3-Alkylimnida-zolium Tetrahalogenoferrate Magnetic Ionic Liquids[J]. Process Eng J,2010,10(4):789-794(in Chinese).李小华,杨富明,周清,等. 磁性离子液体1-甲基-3-烷基咪唑四氯化铁盐的合成及其物性表征[J]. 过程工程学报,2010,10(4):789-794.
-
[12]
[12] MA Yuqin,WEI wei,ZHENG Changmei,et al. Reaction Characteristics of Epoxy Resins E-51 Cured by 1-Hexyl-3-methyl Imidazole Iron Tetrachloride Salt[J]. Chinese J Appl Chem,2015,32(6):636-640(in Chinese).马玉芹,魏巍,郑昌梅,等. 1-己基-3-甲基咪唑四氯化铁盐固化环氧树脂E-51的反应特性[J]. 应用化学,2015,32(6):636-640.
-
[1]
-
-
-
[1]
Hong Zheng , Xin Peng , Chunwang Yi . The Tale of Caprolactam Cyclic Oligomers: The Ever-changing Life of “Princess Cyclo”. University Chemistry, 2024, 39(9): 40-47. doi: 10.12461/PKU.DXHX202403058
-
[2]
Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
-
[3]
Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H2 production activity of BaTiO3 nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
-
[4]
Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
-
[5]
Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO2 methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
-
[6]
Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO2 reduction performance of Z-scheme Ag-Cu2O/BiVO4 photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
-
[7]
Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
-
[8]
Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
-
[9]
Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
-
[10]
Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
-
[11]
Lei Shu , Zhengqing Hao , Kai Yan , Hong Wang , Lihua Zhu , Fang Chen , Nan Wang . Development of a Double-Carbon Related Experiment: Preparation, Characterization and Carbon-Capture Ability of Eggshell-Derived CaO. University Chemistry, 2024, 39(4): 149-156. doi: 10.3866/PKU.DXHX202310134
-
[12]
Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
-
[13]
Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO3 for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
-
[14]
Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
-
[15]
Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu2O/Bi2MoO6 Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
-
[16]
Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
-
[17]
Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
-
[18]
Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
-
[19]
Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co3O4 as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
-
[20]
Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO2 reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(336)
- HTML views(29)