Citation: JIN Qifeng, JIANG Dongyue, TONG Lina, JIAN Xigao. Preparation and Properties of Triethoxysilane Functionalized Poly(phthalazinone ether nitrile) Self-Assembled Thin Films[J]. Chinese Journal of Applied Chemistry, ;2016, 33(2): 169-174. doi: 10.11944/j.issn.1000-0518.2016.02.150205 shu

Preparation and Properties of Triethoxysilane Functionalized Poly(phthalazinone ether nitrile) Self-Assembled Thin Films

1.
a School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116021, China;
2.
b Department of Polymer Science & Materials, Dalian University of Technology, Dalian, Liaoning 116012, China

Corresponding author: JIN Qifeng,
Received Date: 17 June 2015
Available Online: 12 November 2015
Fund Project:

A novel triethoxysilyl-functionalized poly(phthalazinone ether nitrile)(PNAS) was synthesized by hydrolysis, acylation and 3-aminopropyltriethoxysilance-functionalization, and characterized by FTIR, ²⁹Si NMR, DSC and TGA. The self-assembled polymer film was designed to serve as wear resistant coating for silicon surface. It has an excellent heat-resistance with a glass transition temperature and the temperature at which 5% mass loss at 329℃ and 492℃, respectively. The surface morphology of self-assembled film was studied by atomic force microscopy, while the friction performance was investigated using reciprocating friction tester. Comparing with the short chain self-assembled film, the friction coefficient of the prepared film is very low(about 0.07 at the loading of 400 nN), and the anti-wear behavior is good, with a lack of failure after sliding over 5 hours.
- poly(aryl ether nitrile),
- self-assembled film,
- tribology,
- lubrication
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