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Citation: ZHANG Pei, YUAN Hua, WU Jiaxiong, ZHANG Hualiang. Selective Oxidation of Primary Hydroxyl of Methyl Glucoside by Sodium Tungstate/Hydroperoxide[J]. Chinese Journal of Applied Chemistry, ;2015, 32(10): 1159-1163. doi: 10.11944/j.issn.1000-0518.2015.10.150107 shu

Selective Oxidation of Primary Hydroxyl of Methyl Glucoside by Sodium Tungstate/Hydroperoxide

1.
Key Laboratory for Green Chemical Process of Ministry of Education;School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430073, China

Corresponding author: YUAN Hua,
Received Date: 20 March 2015
Available Online: 17 June 2015
Fund Project: 国家自然科学基金(21276201) (21276201)武汉工程大学研究生教育创新基金项目(CX2014113)资助 (CX2014113)

Sodium tungstate/hydroperoxide was used for the preparation of glucuronic acid and its lactone by selective oxidation of primary hydroxyl group of methyl glucoside.The effects of different catalytic oxidative conditions on the yield were studied.The products were determined by HPLC.A reaction mechanism was proposed.The catalytic system exhibits high activity and good selectivity on the oxidation of primary hydroxyl of methyl glycoside.Combined yield of glucuronic acid and its lactone is up to 74.07%.Compared with the traditional HNO₃ oxidation of starch,this process is more environmental-friendly and economical.
- sodium tungstate/hydroperoxide system,
- methyl glucoside,
- glucuronic acid,
- selective oxidation
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