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Citation: ZHANG Fuxing, KUANG Daizhi, FENG Yonglan, WANG Jianqiu, YU Jiangxi, JIANG Wujiu, ZHU Xiaoming. Synthesis,Structure and Properties of Tricyclohexyltin L-Mandeliate[J]. Chinese Journal of Applied Chemistry, ;2015, 32(10): 1120-1126. doi: 10.11944/j.issn.1000-0518.2015.10.150055 shu

Synthesis,Structure and Properties of Tricyclohexyltin L-Mandeliate

1.
Department of Chemistry and Material Science, Hengyang Normal University, Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hu'nan Province, Hengyang, Hu'nan 421008, China

Corresponding author: ZHANG Fuxing,
Received Date: 5 February 2015
Available Online: 23 June 2015
Fund Project: 湖南省高校创新平台开放基金项目(15K107) (15K107)湖南省自然科学基金项目(11JJ3021) (11JJ3021)

Tricyclohexyltin L-mandeliate was synthesized by the reaction of tricyclohexyltin hydroxide with L-mandelic acid.Its structure has been determined by X-ray single crystal diffraction.The crystal is orthorhombic with space group P2₁2₁2₁,a=0.80825(4) nm,b=1.77151(8) nm,c=1.8385(2) nm,α=β=γ=90°,V=2.6324(2) nm³,Z=4,D_c=1.310 g/nm³,μ(MoKα)=9.92 cm^-1,F(000)=1080,R₁=0.0472,wR₂=0.1341.The tin atom has a distorted tetrahedral geometry.The stability of tricyclohexyltin L-mandeliate,its orbital energies and composition characteristics of some frontier molecular orbitals have been investigated by quantum chemistry calculation by means of G03 W package and taking Lanl2 dz basis set.Further more,thermal stability,electrochemical property,CD spectrum and anticancer activity of tricyclohexyltin L-mandeliate were also tested.
- tricyclohexyltin L-mandeliate,
- synthesis,
- structure,
- antitumor activity
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