Citation:
SU Bitao, SHAO Kerang, LI Jianjiao, XIN Junlian, LEI Ziqiang. Preparation and Photocatalytic Property of Titanium (Ⅳ) Dopped Zinc Oxide Nanofiber Materials with Multi-wall Structure[J]. Chinese Journal of Applied Chemistry,
;2015, 32(10): 1170-1176.
doi:
10.11944/j.issn.1000-0518.2015.10.150021
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Ti4+/ZnO nanofiber materials with multi-wall structures were prepared by the template-assisted two-step method and characterized by thermogravimetric analysis (TG),X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques.The effect of Ti4+ doping amount (0.000~0.200 at.%) on the photocatalytic property of ZnO nanofiber materials was studied by the model degradation reaction of methylene blue (MB).The results show that Ti4+/ZnO nanofiber materials with multi-wall structures are successfully prepared via the templated-assisted two-step method,doping Ti4+ can greatly change the nano-structure of the Ti4+/ZnO fiber materials,and the photocatalytic activity of Ti4+/ZnO nanofiber materials are higher than that of ZnO.The improved photocatalytic activity of Ti4+/ZnO multi-wall nanofibers can be mainly ascribed to the formation of the active site-O2--Ti4+-O2--Zn2+-and the efficient migration of the photogenerated charges e--h+ from particle to particle in Ti4+/ZnO.
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