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Citation: ZHAO Shengfang, CHEN Nianyou, ZHANG Hanmei, ZHANG Jing, LI Zaoying. Microwave Synthesis and Antibacterial Activity of Novel Asymmetric Porphyrin Matal Complexes from Substituted Piperonal[J]. Chinese Journal of Applied Chemistry, ;2015, 32(5): 542-546. doi: 10.11944/j.issn.1000-0518.2015.05.140302 shu

Microwave Synthesis and Antibacterial Activity of Novel Asymmetric Porphyrin Matal Complexes from Substituted Piperonal

1.
a Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemical Engineering, Huanggang Normal University, Huanggang, Hubei 438000, China;
2.
b College of Chemical and Molecular Sciences, Wuhan University, Wuhan 430072, China

Corresponding author: ZHAO Shengfang,
Received Date: 1 September 2014
Available Online: 20 November 2014
Fund Project: 国家自然科学基金(21307038) (21307038)湖北省自然科学基金(2013CFC056)资助项目 (2013CFC056)

Zn(Ⅱ),Co(Ⅱ) and Mn(Ⅱ) complexes of 5-(2-nitro-4,5-methylenedioxy) phenyl-10,15,20-triphenyl-porphyrin and 5-(2-nitro-4,5-methylenedioxy) phenyl-10,15,20-tri(p-chlorophenyl)-porphyrin were synthesized by microwave irradiation.Their structures were characterized by UV-Vis,IR,fluoresence spectroscopies.The bactericidal activities of these metal compounds on Escherichia coli aureu(Ec) and Staphylococcusaureu(Sa) were studied with the inhibition ring test.These complexes show photosensitive antibacterial activities against these two bacteria.The Co(Ⅱ) complexes have obvious bacteriostatic activities against Ec and Sa at the concentration of 0.32 mmol/L and 0.02 mmol/L,respectively,and some bacteriostatic effects.The Zn(Ⅱ) and Co(Ⅱ) complexes have moderate antibacterial effects at 0.16~0.32 mmol/L.The order of the antibacterial activity of these complexes is Por(Co)>Por(Mn)≈Por(Zn).The bacteriostatic effects of the complexes on Ec are 10%~20% higher than those on Sa.
- asymmetrical porphyrin,
- metal complex,
- microwave synthesis,
- characterization,
- antibacterial activity
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