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Citation: YIN Yuli, LONG Fang, RAO Wei, ZHANG Zhaohui, YAN Liang. Preparation and Adsorption Properties of Novel Magnetic Nonylphenol Molecularly Imprinted Nanocomposite Material Based on Multiwalled Carbon Nanotubes[J]. Chinese Journal of Applied Chemistry, ;2015, 32(4): 472-480. doi: 10.11944/j.issn.1000-0518.2015.04.140254 shu

Preparation and Adsorption Properties of Novel Magnetic Nonylphenol Molecularly Imprinted Nanocomposite Material Based on Multiwalled Carbon Nanotubes

YIN Yuli ^a ,
LONG Fang ^a ,
RAO Wei ^a ,
ZHANG Zhaohui ^a,b,, ,
YAN Liang ^a

1.
a College of Chemistry and Chemical Engineering, Jishou University, Jishou, Hu'nan 416000, China;
2.
b State Key Laboratory of Chemo/Biosensing and Chemometrics, Hu'nan University, Changsha 410082, China

Corresponding author: ZHANG Zhaohui,
Received Date: 21 July 2014
Available Online: 15 December 2014
Fund Project: 国家自然科学基金(21005030和21267010) (21005030和21267010)吉首大学校级课题(14JDY071)资助 (14JDY071)

A novel magnetic nonylphenol molecularly imprinted composite extraction materials(MWNTs@Fe₃O₄-MIPs) was prepared based on multiwalled carbon nanotubes(MWNTs) using nonylphenol(NP) as the template,methacrylic acid(MAA) as the functional monomer and ethylene glycol dimethacrylate(EGDMA) as the cross-linker. The MWNTs@Fe₃O₄-MIPs were characterized by scanning electron microscopy(SEM),Fourier-transform infrared(FT-IR) analysis and vibrating sample magnetometer(VSM).The results show that a thermally stable magnetic imprinted layer with the thickness of 60~70 nm was coated steadily on the MWNTs surface. Adsorption performance of the MWNTs@Fe₃O₄-MIPs was investigated by magnetic solid phase extraction(M-SPE) and high-performance liquid chromatography(HPLC) technology.The results indicate that the MWNTs@Fe₃O₄-MIPs possessed higher selectivity towards nonylphenol(NP) with the maximum adsorption capacity of 38.46 mg/g. This magnetic molecularly imprinted composite material combining with HPLC technology is successfully applied to the separation and the enrichment of nonylphenol(NP) in environmental water samples.
- molecularly imprinted,
- magnetic multiwalled carbon nanotubes,
- nonylphenol,
- magnetic solid phase extraction
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