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Citation: LIU Jianben, CHEN Shang. Ruthenium/Acid Co-catalyzed Synthesis of Quinoline Derivatives from o-Aminoarylmethanols and Terminal Arylalkynes[J]. Chinese Journal of Applied Chemistry, ;2015, 32(3): 267-272. doi: 10.11944/j.issn.1000-0518.2015.03.140250 shu

Ruthenium/Acid Co-catalyzed Synthesis of Quinoline Derivatives from o-Aminoarylmethanols and Terminal Arylalkynes

LIU Jianben ^, ,
CHEN Shang

1.
College of Chemistry and Chemical Engineering, Jishou University, Jishou, Hu'nan 416000, China

Corresponding author: LIU Jianben,
Received Date: 18 July 2014
Available Online: 5 November 2014

By using o-aminophenyl methanol as the starting material and undergoing a dehydrogenation reaction,[RuCl₂(p-cymene)]₂/AgOTf was finally employed as the co-catalyst system upon a systematical screening of catalysts,which enables the dehydrogenation of o-aminophenyl methanol to undergo a crosscoupling reaction with terminal aryl alkynes,affording a series of 2-aryl quinolines in 39% to 47% yields. The study has demonstrated a new method for the synthesis of quinolines from o-aminophenyl methanol and terminal aryl alkynes,which is an important complement to the synthesis of quinoline derivatives.
- ruthenium catalysis,
- o-aminoaryl methanol,
- dehydrogenation,
- quinoline derivatives
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