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Citation: WU Juan, HU Peng, HUANG Chao, CHEN Dongmei, ZHU Bixue. Synthesis and Properies of Macrocycles Containing Pyridine-2, 6-Dicarboxamide Unit[J]. Chinese Journal of Applied Chemistry, ;2015, 32(3): 284-291. doi: 10.11944/j.issn.1000-0518.2015.03.140247 shu

Synthesis and Properies of Macrocycles Containing Pyridine-2, 6-Dicarboxamide Unit

WU Juan ^a ,
HU Peng ^b ,
HUANG Chao ^a ,
CHEN Dongmei ^a ,
ZHU Bixue ^a,,

1.
a Key Laboratory of Macrocyclic and Supra molecular Chemistry, Guizhou University, Guiyang 550025, China;
2.
b Department of Chemistry, Guiyang Medical College, Guiyang 550004, China

Corresponding author: ZHU Bixue,
Received Date: 16 July 2014
Available Online: 7 October 2014
Fund Project: 国家自然科学基金资助项目(21061003) (21061003)教育部"春晖计划"项目(132008) (132008)

The [1+1] Schiff base macrocyclic compound 3 was synthesized via the condensation of precursor 1[1,3-bis(2'-formylphenoxy) propane] and precursor 2[N,N'-(2-aminophenyl) pyridine-2,6-dicarboxamide] in the presence of sulfuric acid. Macrocycle 3 was reduced to the corresponding saturated macrocycle 4. Their structures were characterized by ¹H NMR,IR,MS spectra and elemental analysis. The crystal structures of the two macrocycles were determined by the X-ray diffraction analysis. The study of the reaction of the macrocyclic compound 3 or 4 with a series of anions was performed by UV-Vis absorption spectra technique. The results show that the saturated macrocycle 4 displayed a selective recognition for Fion,and the stoichiometric ratio and the stability constant of the complex were determined. Furthermore the adsorption abilities of the two macrocycles for methanol were investigated.
- pyridine-dicarboxamide,
- macrocycle,
- crystal structure,
- anion recognition,
- adsorption property
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