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Citation: ZHANG Dechun, WANG Wen'ge, SUN Aiming, LIU Kaijian, OU Lijuan, LI Aiyang. Synthesis and UV Spectra of Aromatic Oligosulfonate-bridged Macrocycles[J]. Chinese Journal of Applied Chemistry, ;2015, 32(3): 292-298. doi: 10.11944/j.issn.1000-0518.2015.03.140231 shu

Synthesis and UV Spectra of Aromatic Oligosulfonate-bridged Macrocycles

1.
Department of Materials & Chemical Engineering, Hu'nan Institute of Technology, Hengyang, Hu'nan 421002, China

Corresponding author: WANG Wen'ge,
Received Date: 1 July 2014
Available Online: 6 November 2014
Fund Project: 广西师范大学药用资源与药物分子工程教育部重点实验室开放基金(CMEMR2011-03)资助 (CMEMR2011-03)

A series of aromatic oligosulfonate-bridged macrocyclic compounds was synthesized using aromatic disulfonyl chlorides and aromatic diphenol as the starting materials. The products were characterized by IR,¹H NMR,¹³C NMR and MALDI-TOF-MS. The synthetic methods,UV spectra and variable-temperature ¹H NMR experiments were also discussed herein. UV spectra maximum absorption peaks of compounds 3~5 and compound 6 in DMF solutions are at 266 nm and 267 nm,respectively. The molar absorption coefficients are 4.65×10⁴,5.61×10⁴,5.09×10⁴ and 9.98×10⁴ L/( mol·cm),respectively. The detection limits are2.15×10^-7,1.78×10^-7,1.96×10^-7and 1.00×10^-7 mol/L,respectively. Variable-temperature ¹H NMR experiments show that branched benzene rings can lock the conformation and facilitate the synthesis of desired macrocylces.
- macrocyclic compound,
- sulfonate,
- synthesis,
- variable-temperature ¹H NMR,
- UV spectra
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