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Citation: JIN Guangri, ZHU Jikai, ZHONG Keli, CHEN Tie, JIN Longyi. Synthesis,Self-Assembly and Spectroscopic Analysis of 9, 10-Bis((4-(2-(2-(2-methoxyethoxy) ethoxy) ethoxy) phenyl) ethynyl) anthracene[J]. Chinese Journal of Applied Chemistry, ;2015, 32(2): 177-182. doi: 10.11944/j.issn.1000-0518.2015.02.140164 shu

Synthesis,Self-Assembly and Spectroscopic Analysis of 9, 10-Bis((4-(2-(2-(2-methoxyethoxy) ethoxy) ethoxy) phenyl) ethynyl) anthracene

JIN Guangri ^a ,
ZHU Jikai ^a ,
ZHONG Keli ^b ,
CHEN Tie ^a ,
JIN Longyi ^a,,

1.
a Department of Chemistry, College of Science, Yanbian University, and Key Laboratory for Organism Resources of the Changbai Mountain and Functional Molecules, Ministry of Education, Yanbian University, Yanji, Jilin 133002, China;
2.
b Food Safety Key Lab of Liaoning Province, Engineering and Technology Research Center of Food Preservation, Processing and Safety Control of Liaoning Province, College of Chemistry, Chemical Engineering and Food Safety, Bohai University, Jinzhou, Liaoning 121013, China

Corresponding author: JIN Longyi,
Received Date: 6 May 2014
Available Online: 9 July 2014
Fund Project: 国家自然基金资助项目(21164013,21304009) (21164013,21304009)超分子结构与材料国家重点实验室开放基金资助(sklssm201430) (sklssm201430)

9,10-Bis ((4-(2-(2-(2-methoxyethoxy) ethoxy) ethoxy) phenyl) ethynyl) anthracene (1) was synthesized by Sonogashira coupling. Its structure was characterized by ¹H NMR and MALDI-TOF mass spectroscopy. The self-assembling behavior of compound 1 was investigated by means of differential scanning calorimetry(DSC),thermal polarized optical microscopy(POM),and small-angle X-ray scattering(SAXS) at the bulk state. Compound 1 self-assembled into smectic A phase (SmA) in the solid state. Spectroscopic analysis suggested that compound 1 inherited the characteristic of high fluorescence quantum yield (Φ_f) of disubstituted anthracenes. The title compound 1 is a kind of photoluminescence materials with good performance.
- self-assembly,
- anthracene,
- fluorescence quantum yield,
- smectic A phase,
- Sonogashira coupling reaction
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