Citation: Yifang ZHANG, Zifeng SHAO, Hexuan JIN, Lijuan YANG, Runlong HAO, Jianfeng WANG, Ning LIU. Research progress in the application of metal-organic frameworks in electrocatalytic urea synthesis[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(10): 2051-2062. doi: 10.11862/CJIC.20260204 shu

Research progress in the application of metal-organic frameworks in electrocatalytic urea synthesis

Yifang ZHANG ^{1, 2} ,
Zifeng SHAO ^{1, 2} ,
Hexuan JIN ^{1, 2} ,
Lijuan YANG ^{1, 2} ,
Runlong HAO ^{1, 2} ,
Jianfeng WANG ³ ,
Ning LIU ^{1, 2,,}

1.
Yanzhao Electric Power Laboratory of North China Electric Power University, Baoding, Hebei 071000, China
2.
Hebei Key Lab of Power Plant Flue Gas Multi-Pollutants Control, North China Electric Power University, Baoding, Hebei 071003, China
3.
Hebei Jiantou Energy Science and Technology Research Institute Co., Ltd., Shijiazhuang 050051, China

Corresponding author: Ning LIU, liuning@ncepu.edu.cn
Received Date: 26 June 2026
Revised Date: 10 September 2026

Figures(7)

Urea is an important agricultural fertilizer and chemical feedstock; however, its conventional production is plagued by high energy consumption and substantial carbon emissions. Electrocatalytic urea synthesis offers a green alternative that facilitates both carbon reduction and nitrogen resource recycling. Nevertheless, this route is currently hindered by key scientific bottlenecks, including the difficulty of activating reactants and low C-N coupling efficiency. Metal-organic frameworks (MOFs), featuring tunable active sites, porous architectures conducive to mass transfer, and functionalizable ligands, represent an ideal material platform to overcome these limitations. This review systematically summarizes recent advances in single-metal MOFs, multi-metal MOFs, and MOF-based composites for electrocatalytic urea production, with a focus on structural design strategies, catalytic mechanisms, and performance enhancement approaches. Furthermore, we critically analyze the persistent challenges regarding C-N coupling efficiency and reaction selectivity, and discuss the prospects for large-scale applications. This review aims to offer guidance for the rational design and development of high-performance electrocatalysts for urea synthesis.
- metal-organic frameworks,
- electrochemical catalysis,
- urea synthesis,
- C-N coupling,
- carbon dioxide emission reduction
1. [1]
  LV C D, ZHONG L X, LIU H J, FANG Z W, YAN C S, CHEN M X, KONG Y, LEE C, LIU D B, LI S Z, LIU J W, SONG L, CHEN G, YAN Q, YU G. Selective electrocatalytic synthesis of urea with nitrate and carbon dioxide[J]. Nat. Sustain., 2021, 4(10): 868-876 doi: 10.1038/s41893-021-00741-3
2. [2]
  MESQUITA I S, MELO P A, SECCHI A R. Novel pathways for urea synthesis decarbonization: An analytical review from Bosch-Meiser to electroreduction processes[J]. Appl. Energy, 2025, 400: 126527 doi: 10.1016/j.apenergy.2025.126527
3. [3]
  XIA M K, MAO C L, GU A L, TOUNTAS A A, QIU C Y, WOOD T E, LI Y F, ULMER U, XU Y F, VIASUS C J, YE J, QIAN C X, OZIN G. Solar urea: Towards a sustainable fertilizer industry[J]. Angew. Chem. -Int. Edit., 2021, 61(1): 202110158
4. [4]
  CHEN H, LIU L, MA X H, ZHENG S J, DONG X Y, HUANG R W, WANG Z Y, CAI J, ZANG S Q. Atomically precise silver-based bimetallic clusters for electrocatalytic urea synthesis[J]. Natl. Sci. Rev., 2025, 12(2): nwae440 doi: 10.1093/nsr/nwae440
5. [5]
  LIM J, FERNÁNDEZ C A, LEE S W, HATZELL M C. Ammonia and nitric acid demands for fertilizer use in 2050[J]. ACS Energy Lett., 2021, 6(10): 3676-3685 doi: 10.1021/acsenergylett.1c01614
6. [6]
  CUI Z J, WANG H H, LI C L, PENG W C, LIU J P. Three birds with one stone: Electrocatalytic C-N coupling for carbon neutrality, nitrogen resource utilization, and urea synthesis[J]. Renew. Sustain. Energy Rev., 2024, 205: 114822 doi: 10.1016/j.rser.2024.114822
7. [7]
  DAI L J, LI S J, DAI Y, ZHENG Y J, LIU K H, LI H X, JIANG B. Engineering CoO/B heterojunction electrocatalysts for boosting electrocatalytic nitrate reduction to ammonia[J]. Chem. Eng. J., 2024, 498: 155735 doi: 10.1016/j.cej.2024.155735
8. [8]
  PADINJAREVEETIL A K K, PERALES‑RONDON J V, ZAORALOVÁ D, OTYEPKA M, ALDUHAISH O, PUMERA M. Fe-MOF catalytic nanoarchitectonic toward electrochemical ammonia production[J]. ACS Appl. Mater. Interfaces, 2023, 15(40): 47294-47306 doi: 10.1021/acsami.3c12822
9. [9]
  LI J Z, LI H, FAN K, LEE J Y, XIE W F, SHAO M F. Electrocatalytic nitrate reduction to ammonia coupled with organic oxidation[J]. Chem. Catal., 2023, 3(6): 100638
10. [10]
  ZHANG D Y, XUE Y R, ZHENG X C, ZHANG C, LI Y L. Multi-heterointerfaces for selective and efficient urea production[J]. Natl. Sci. Rev., 2023, 10(2): nwac209 doi: 10.1093/nsr/nwac209
11. [11]
  HAO R L, SONG Y C, YANG L L, GUO Y X, WU X H, MA Z, QIAN Z, LIU F, WU Z B, WANG L D. Electrochemical reduction of flue gas denitrification wastewater to ammonia using a dual-defective Cu₂O@Cu heterojunction electrode[J]. Environ. Sci. Technol., 2024, 58(12): 5557-5566 doi: 10.1021/acs.est.3c09811
12. [12]
  JIANG H, WU X, ZHANG H, YAN Q, LI H, MA T, YANG S. Toward effective electrocatalytic C-N coupling for the synthesis of organic nitrogenous compounds using CO₂ and biomass as carbon sources[J]. SusMat, 2023, 3(6): 781-820 doi: 10.1002/sus2.175
13. [13]
  GUO Y X, CHEN H, DU J X, YUAN J Y, FANG S Y, JIN S Y H, LIU F, QI M, WU X H, HAO R L, WU Z B, WANG L D. Electroreduction of carbon dioxide and nitrogenous pollutants to achieve C-N coupling for urea synthesis: Progress, mechanism, and challenges[J]. Coord. Chem. Rev., 2026, 551: 217473 doi: 10.1016/j.ccr.2025.217473
14. [14]
  GE R Y, HUO J J, LU P, DOU Y H, BAI Z C, LI W X, LIU H K, FEI B, DOU S X. Multifunctional strategies of advanced electrocatalysts for efficient urea synthesis[J]. Adv. Mater., 2024, 36(49): 2412031 doi: 10.1002/adma.202412031
15. [15]
  WANG C, GAO W Q, HU W, WEN W, WANG S F, ZHANG X H, YAN D F, XIA B Y. Recent advances in electrochemical synthesis of urea via C-N coupling[J]. J. Energy Chem., 2024, 98: 294-310 doi: 10.1016/j.jechem.2024.06.042
16. [16]
  YUAN M L, CHEN J W, BAI Y L, LIU Z J, ZHANG J X, ZHAO T K, WANG Q, LI S W, HE H Y, ZHANG G J. Unveiling electrochemical urea synthesis by Co-activation of CO₂ and N₂ with Mott-Schottky heterostructure catalysts[J]. Angew. Chem. -Int. Edit., 2021, 60(19): 10910-10918 doi: 10.1002/anie.202101275
17. [17]
  YU Y D, LV Z, LIU Z Y, SUN Y Y, WEI Y Y, JI X, LI Y Y, LI H D, WANG L, LAI J P. Activation of Ga liquid catalyst with continuously exposed active sites for electrocatalytic C-N coupling[J]. Angew. Chem. -Int. Edit., 2024, 63(18): e202402236 doi: 10.1002/anie.202402236
18. [18]
  MA L J, YUAN J L, LIU Z T, LUO Y Q, SU Y N, ZHU K Y, FENG Z F, NIU H H, XIAO S S, WEI J J, XIANG X. Mesoporous electrocatalysts with p-n heterojunctions for efficient electroreduction of CO₂ and N₂ to urea[J]. ACS Appl. Mater. Interfaces, 2024, 16(20): 26015-26024 doi: 10.1021/acsami.4c00257
19. [19]
  WEI X X, WEN X J, LIU Y Y, CHEN C, XIE C, WANG D D, QIU M Y, HE N H, ZHOU P, CHEN W, CHENG J, LIN H Z, JIA J F, FU X Z, WANG S Y. Oxygen vacancy-mediated selective C-N coupling toward electrocatalytic urea synthesis[J]. J. Am. Chem. Soc., 2022, 144(26): 11530-11535 doi: 10.1021/jacs.2c03452
20. [20]
  KOHLHAAS Y, TSCHAUDER Y S, PLISCHKA W, SIMON U, EICHEL R A, WESSLING M, KELLER R. Electrochemical urea synthesis[J]. Joule, 2024, 8(6): 1579-1600 doi: 10.1016/j.joule.2024.04.004
21. [21]
  JIANG M H, ZHU M F, WANG M J, HE Y, LUO X J, WU C J, ZHANG L Y, JIN Z. Review on electrocatalytic coreduction of carbon dioxide and nitrogenous species for urea synthesis[J]. ACS Nano, 2023, 17(4): 3209-3224 doi: 10.1021/acsnano.2c11046
22. [22]
  GUAN Y J, YU Y D, LIU F F, YANG J K, CHAO Y X, LI H D, CHI J Q, LAI J P, WANG L. Enhancing the yield of electrocatalytic C-N coupling for urea synthesis: Challenges, strategies, and prospects[J]. Green Chem., 2026, 28(2): 783-812 doi: 10.1039/D5GC05787F
23. [23]
  SHI H K, ZHAO L, WANG W Z, PANG S Y, LI H D, CHI J Q, LAI J P, WANG L. Cu-based catalysts for electrocatalytic urea synthesis from CO₂ and NO₃^-: Mechanism, design and perspectives[J]. Inorg. Chem. Front., 2026, 13(6): 2302-2326 doi: 10.1039/D5QI02240A
24. [24]
  MENG N N, HUANG Y M, LIU Y, YU Y F, ZHANG B. Electrosynthesis of urea from nitrite and CO₂ over oxygen vacancy-rich ZnO porous nanosheets[J]. Cell Rep. Phys. Sci., 2021, 2(3): 100378 doi: 10.1016/j.xcrp.2021.100378
25. [25]
  ZHENG J G, XU S H, SUN J, ZHANG J X, SUN L Z, PAN X, LI L N, ZHAO G H. Boosting efficient C—N bonding toward photoelectrocatalytic urea synthesis from CO₂ and nitrate via close Cu/Ti bimetallic sites[J]. Appl. Catal. B-Environ., 2023, 338: 123056 doi: 10.1016/j.apcatb.2023.123056
26. [26]
  FU J J, YANG Y, HU J S. Dual-sites tandem catalysts for C—N bond formation via electrocatalytic coupling of CO₂ and nitrogenous small molecules[J]. ACS Mater. Lett., 2021, 3(10): 1468-1476 doi: 10.1021/acsmaterialslett.1c00375
27. [27]
  FAN Y X, FENG Z, CAO X W, PENG Z Y, CHEN J M, WANG L L. Modifying MOF electrocatalysts for enhanced oxygen and hydrogen evolution reactions[J]. Small, 2026, 22(1): e12470 doi: 10.1002/smll.202512470
28. [28]
  LI J T, CHU D. Research on electrocatalytic materials for hydrogen evolution and oxygen evolution[J]. Materials, 2025, 18(18): 4232 doi: 10.3390/ma18184232
29. [29]
  DUAN Y, RUAN W, GUAN J. Optimization strategies for carbon dioxide electroreduction to ethylene[J]. Chem. Eng. J., 2025, 510: 161665 doi: 10.1016/j.cej.2025.161665
30. [30]
  DUAN Y Y, RUAN W D, GUAN J Q. Advances in the carbon dioxide electroreduction to ethanol[J]. Coord. Chem. Rev., 2025, 543: 216908 doi: 10.1016/j.ccr.2025.216908
31. [31]
  ZHANG C, CHEN S J, GUO L W, LI Z Y, YAN C S, LV C D. Recent advances in urea electrocatalysis: Applications, materials and mechanisms[J]. Chin. J. Chem., 2024, 42(24): 3441-3468 doi: 10.1002/cjoc.202400442
32. [32]
  GE W Y, LIN L P, WANG S Q, WANG Y C, MA X W, AN Q, ZHAO L. Electrocatalytic urea oxidation: Advances in mechanistic insights, nanocatalyst design, and applications[J]. J. Mater. Chem. A, 2023, 11(28): 15100-15121 doi: 10.1039/D3TA02007J
33. [33]
  ZHAO R, UTOMO W P, QU S Y, LEI Q, LI Y G, WU H. Toward sustainable urea synthesis: Materials design and mechanistic perspectives in electrocatalytic and photo(electro)catalytic systems[J]. Adv. Energy Mater., 2026, 27: e71106
34. [34]
  GAO W T, WU Q Y, FAN X F, LU N, LIU Y M, QUAN X. Promoting electrocatalytic reduction of CO₂ and nitrate to urea on N-doped porous hollow carbon spheres[J]. ACS Appl. Mater. Interfaces, 2024, 16(38): 50726-50735 doi: 10.1021/acsami.4c09949
35. [35]
  JAMES S L. Metal-organic frameworks[J]. Chem. Soc. Rev., 2003, 32(5): 276-288 doi: 10.1039/b200393g
36. [36]
  ZHANG S Q, LU L L, JIANG J L, LIU N, ZHAO B, XU M M, CHENG P, SHI W. Organizing photosensitive and photothermal single-sites uniformly in a trimetallic metal-organic framework for efficient photocatalytic hydrogen evolution[J]. Adv. Mater., 2024, 36(26): 2403464 doi: 10.1002/adma.202403464
37. [37]
  LIU N, JIANG J L, XU M M, ZHANG S Q, ZHANG R H, CHEN Z H, MAO Y, CHENG P, SHI W. Asymmetric charge distribution in one-dimensional metal-organic assemblies to promote photocatalytic hydrogen evolution[J]. ChemSusChem, 2024, 18(2): e202401338
38. [38]
  LIU N, JIANG J L, CHEN Z H, WU B Y, ZHANG S Q, ZHANG Y Q, CHENG P, SHI W. Promoted photocatalytic hydrogen evolution by tuning the electronic state of copper sites in metal-organic supramolecular assemblies[J]. Angew. Chem. -Int. Edit., 2023, 62(47): e202312306 doi: 10.1002/anie.202312306
39. [39]
  YE S J, YAN M, TAN X F, LIANG J, ZENG G M, WU H P, SONG B, ZHOU C Y, YANG Y, WANG H. Facile assembled biochar-based nanocomposite with improved graphitization for efficient photocatalytic activity driven by visible light[J]. Appl. Catal. B-Environ., 2019, 250: 78-88 doi: 10.1016/j.apcatb.2019.03.004
40. [40]
  KALMUTZKI M J, DIERCKS C S, YAGHI O M. Metal-organic frameworks for water harvesting from air[J]. Adv. Mater., 2018, 30(37): 1704304 doi: 10.1002/adma.201704304
41. [41]
  BHAT M M, SHEIKH U R, BHAT S A, HAMID A, KUCHEY M Y, ZAHOOR S, SOFI F A, BHAT A Y, INGOLE P P, OTTAKAM THOTIYL M, BHAT M A. MOF-driven direct oxidative electrocatalysis of urea[J]. ACS Appl. Mater. Interfaces, 2026, 18(5): 8061-8080 doi: 10.1021/acsami.5c19710
42. [42]
  JIN S. How to effectively utilize MOFs for electrocatalysis[J]. ACS Energy Lett., 2019, 4(6): 1443-1445 doi: 10.1021/acsenergylett.9b01134
43. [43]
  YUAN M L, CHEN J W, ZHANG H H, LI Q G, ZHOU L, YANG C, LIU R J, LIU Z J, ZHANG S J, ZHANG G J. Host-guest molecular interaction promoted urea electrosynthesis over a precisely designed conductive metal-organic framework[J]. Energy Environ. Sci., 2022, 15(5): 2084-2095 doi: 10.1039/D1EE03918K
44. [44]
  GAO Y H, WANG J N, YANG Y J, WANG J, ZHANG C, WANG X, YAO J N. Engineering spin states of isolated copper species in a metal-organic framework improves urea electrosynthesis[J]. Nano-Micro Lett., 2023, 15(1): 158 doi: 10.1007/s40820-023-01127-0
45. [45]
  HUANG D S, QIU X F, HUANG J R, MAO M, LIU L, HAN Y, ZHAO Z H, LIAO P Q, CHEN X M. Electrosynthesis of urea by using Fe₂O₃ nanoparticles encapsulated in a conductive metal-organic framework[J]. Nat. Synth., 2024, 3(11): 1404-1413 doi: 10.1038/s44160-024-00603-8
46. [46]
  GAO Y H, WANG J N, SUN M L, JING Y, CHEN L L, LIANG Z Q, YANG Y J, ZHANG C, YAO J N, WANG X. Tandem catalysts enabling efficient C-N coupling toward the electrosynthesis of urea[J]. Angew. Chem. -Int. Edit., 2024, 63(23): e202402215 doi: 10.1002/anie.202402215
47. [47]
  GERKE C S, XU Y, YANG Y, FOLEY G D, ZHANG B, SHI E, BEDFORD N M, CHE F, THOI V S. Electrochemical C—N bond formation within boron imidazolate cages featuring single copper sites[J]. J. Am. Chem. Soc., 2023, 145(48): 26144-26151 doi: 10.1021/jacs.3c08359
48. [48]
  TAN Y, CHEN X K, YUAN J, SHENG G, DENG W Q, WU H. Concentration-adaptive electrocatalytic urea synthesis from CO₂ and nitrate via porphyrin and metalloporphyrin MOFs[J]. Angew. Chem. -Int. Edit., 2025, 64(35): e202513441 doi: 10.1002/anie.202513441
49. [49]
  ZHANG M D, HUANG J R, LIAO P Q, CHEN X M. Utilisation of carbon dioxide and nitrate for urea electrosynthesis with a Cu-based metal-organic framework[J]. Chem. Commun., 2024, 60(27): 3669-3672 doi: 10.1039/D3CC05821B
50. [50]
  LIU X F, FENG J, CHENG X F, ZHANG J C, HUO J Y, CHEN D Y, MARCOMINI A, LI Y Y, XU Q F, LU J M. High C-selectivity for urea synthesis through O-philic adsorption to form *OCO intermediate on Ti-MOF based electrocatalysts[J]. Adv. Funct. Mater., 2024, 34(34): 2400892 doi: 10.1002/adfm.202400892
51. [51]
  LIU Y C, HUANG J R, ZHU H L, QIU X F, YU C, CHEN X M, LIAO P Q. Electrosynthesis of pure urea from pretreated flue gas in a proton-limited environment established in a porous solid-state electrolyte electrolyser[J]. Nat. Nanotechnol., 2025, 20(7): 907-913 doi: 10.1038/s41565-025-01914-3
52. [52]
  QIU X F, HUANG J R, YU C, CHEN X M, LIAO P Q. Highly efficient electrosynthesis of urea from CO₂ and nitrate by a metal-organic framework with dual active sites[J]. Angew. Chem. -Int. Edit., 2024, 34(34): e202410625
53. [53]
  YAO S, JIANG S Y, WANG B F, YIN H Q, XIANG X Y, TANG Z, AN C H, LU T B, ZHANG Z M. Polyoxometalate confined synthesis of BiVO₄ nanocluster for urea production with remarkable O₂/N₂ tolerance[J]. Angew. Chem. -Int. Edit., 2024, 64(6): e202418637
54. [54]
  ZHANG X, SUN H, WANG Y R, SHI Z, ZHONG R L, SUN C Y, LIU J Y, SU Z M, LAN Y Q. Dynamic control of asymmetric charge distribution for electrocatalytic urea synthesis[J]. Adv. Mater., 2024, 36(41): 2408510 doi: 10.1002/adma.202408510
55. [55]
  QUAN X Y, ZHOU Y L, DU R L, DUAN L, CHEN G, ZHANG N. Ag₂O-loaded Cu based metal-organic framework material as pre-electrocatalyst for efficient urea synthesis[J]. J. Mater. Chem. A, 2025, 13(27): 21535-21544 doi: 10.1039/D5TA02983J
56. [56]
  QI Q L, ZHANG C X, HU J. Triggered factors and structure-activity relationship in the dynamic reconstruction processing of MOF for the alkaline oxygen evolution reaction[J]. Chem. Rev., 2025, 522: 216235
57. [57]
  XIAO L Y, WANG Z L, GUAN J Q. Advances in multinuclear metal-organic frameworks for electrocatalysis[J]. Chin. J. Catal., 2026, 80: 59-91 doi: 10.1016/S1872-2067(25)64859-5
58. [58]
  WANG J J, WANG H J, GONG Y N, LIU J Y, LU C J, YANG H Y, ZHONG D C, LU T B. Encapsulation of perovskite quantum dots in dual-metal sites metal-organic frameworks for efficient artificial photosynthesis[J]. Appl. Catal. B-Environ., 2026, 381: 125878 doi: 10.1016/j.apcatb.2025.125878
59. [59]
  WU Y, XU W Q, JIAO L, TANG Y J, CHEN Y F, GU W L, ZHU C Z. Defect engineering in nanozymes[J]. Mater. Today, 2022, 52: 327-347 doi: 10.1016/j.mattod.2021.10.032
60. [60]
  BAI S, ZHANG N, GAO C, XIONG Y J. Defect engineering in photocatalytic materials[J]. Nano Energy, 2018, 53: 296-336 doi: 10.1016/j.nanoen.2018.08.058
61. [61]
  SEO Y K, KIM Y W, KIM K J, SEO W S. Electrically conductive SiC-BN composites[J]. J. Eur. Ceram. Soc., 2016, 36(16): 3879-3887 doi: 10.1016/j.jeurceramsoc.2016.06.040
62. [62]
  JIANG Z C, WANG S X, LU Y Y, MENG Z Y, PANG H. Conductive metal-organic framework as an emerging platform with electrochemical energy storage[J]. Coord. Chem. Rev., 2025, 544: 216983 doi: 10.1016/j.ccr.2025.216983
63. [63]
  XU Y T, FOLEY G D, ON L, THOI V S, CHE F L. Multi-scale modeling guided electrochemical C-N coupling for urea production in metal-organic frameworks[J]. J. Catal., 2026, 453: 116523 doi: 10.1016/j.jcat.2025.116523
64. [64]
  HU B, CHEN K, SHEN B B, SHANG X H, DUAN F H, GUO C P, ZHANG S, ZHANG Z H. Structural engineering of metal-organic frameworks for enhanced electrocatalytic urea oxidation reaction: Mechanistic insights and electronic modulation strategies[J]. J. Rare Earths, 2026, 44(2): 469-490 doi: 10.1016/j.jre.2025.08.016
65. [65]
  LIANG H, LI A S, YUAN N. Multifunctional metal-organic framework-based electrocatalysts: From CO₂ reduction and ammonia synthesis to urea production[J]. Adv. Powder Mater., 2026, 5(3): 100370 doi: 10.1016/j.apmate.2025.100370
66. [66]
  SHRESTHA N K, PATIL S A, SALUNKE A S, INAMDAR A I, KIM H, IM H. Metal-ion doping in metal-organic-frameworks: Modulating the electronic structure and local coordination for enhanced oxygen evolution reaction activity[J]. Dalton Trans., 2023, 52(39): 13852-13857 doi: 10.1039/D3DT02405A
67. [67]
  GUO Z Y, KOBAYASHI T, WANG L L, GOH T W, XIAO C X, CAPORINI M A, ROSAY M, JOHNSON D D, PRUSKI M, HUANG W Y. Selective host-guest interaction between metal ions and metal-organic frameworks using dynamic nuclear polarization enhanced solid-state NMR spectroscopy[J]. Chem. ‒Eur. J., 2014, 20(49): 16308-16313 doi: 10.1002/chem.201403884
68. [68]
  YANG J M, YU Y X, JIANG H S, LIU Y H, ZHOU H P, ZHANG K, CHEN P X, GAO C, ZHANG B C, LUO P Y, JIANG H, LUO X P, LIU Y. Breaking the stability bottleneck in CO₂ electroreduction with pulse-regenerated SnO₂[J]. Appl. Surf. Sci., 2026, 737: 166901 doi: 10.1016/j.apsusc.2026.166901
69. [69]
  WANG X, WANG Z Y, DE ARQUER F P G, DINH C T, OZDEN A, LI Y G C, NAM D H, LI J, LIU Y S, WICKS J, CHEN Z T, CHI M F, CHEN B, WANG Y, TAM J, HOWE J Y, PROPPE A, TODOROVIC P, LI F W, ZHUANG T T, GABARDO C M, KIRMANI A R, MCCALLUM C, HUNG S F, LUM Y W, LUO M C, MIN Y M, XU A N, O′BRIEN C P, STEPHEN B, SUN B, IP A H, RICHTER L J, KELLEY S O, SINTON D, SARGENT E H. Efficient electrically powered CO₂-to-ethanol via suppression of deoxygenation[J]. Nat. Energy, 2020, 5(6): 478-486 doi: 10.1038/s41560-020-0607-8
70. [70]
  CHEN Z Z, CHANG X H, LIU C, LI G, LI H Y, CAI C, YAO W L, SHI J T, ZHOU Y, ZHANG X X, JIA Q X, YAO Z J. MOF-derived FeNb₂O₆/carbon nanofiber hybrids with enhanced kinetics for high-rate lithium storage[J]. Energy Fuels, 2025, 39(43): 21030-21038 doi: 10.1021/acs.energyfuels.5c04378
71. [71]
  LONG J C, ZHANG X, ZHANG H J, WANG H Y, XIE C K, CHEN X, LIN G H, CHEN Y, CHEN X, LIU H T, LU R Q. Mass transfer analysis of a concentration-regulated metal-assisted chemical etching system and its application in Si nanohole fabrication[J]. Chem. Eng. J., 2025, 513: 162997 doi: 10.1016/j.cej.2025.162997
72. [72]
  SHANG Y, CHEN D W, CHEN C, WANG S Y. Surface-functionalized two-dimensional materials towards electrocatalytic C-N coupling reaction for urea[J]. Catal, 2025, 1(1): 9 doi: 10.1007/s44422-025-00009-3
73. [73]
  YANG J J, LI J, XU C X, WEN B B, SI L J, SHEN W F, FENG Z Q, MAI W X, LIN X M, WU Y B, YANG H C. Recent advancements in metal-organic frameworks-derived metal phosphides as anode for lithium-ion batteries[J]. ChemNanoMat, 2025, 11(2): e202400504 doi: 10.1002/cnma.202400504
74. [74]
  TIAN J F, XU Y J, LI J, CHI J Q, FENG L, PAN Q Q, LI X, SU Z M. Post-decorated synthesis of metal-organic frameworks derived Ni/Ni₃S₂@CN electrocatalyst for efficient hydrogen evolution[J]. J. Solid State Chem., 2022, 313: 123287 doi: 10.1016/j.jssc.2022.123287
75. [75]
  LI Y, HUANG K, LIU W H, WANG K, FU S, GUO H Z, ZHANG J Y, LIAN C, WANG L. Interfacial engineering of carbon quantum dot/metal-organic framework heterostructures for boosted urea electrosynthesis from carbon dioxide and nitrate[J]. J. Colloid Interface Sci., 2026, 703: 139264 doi: 10.1016/j.jcis.2025.139264
76. [76]
  WEI S B, XU L L, ZHAO H, ZHOU J, NI T J, ZHANG C H, LI J Y, CHEN Z K, WANG H L, CHEN J W, HOU X B, HUANG M H. In situ tracking of programmable reconstruction in metal-organic frameworks toward ampere-level urea oxidation[J]. Angew. Chem. -Int. Edit., 2026, 65(28): e6742100 doi: 10.1002/anie.6742100
1. [1]
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13. [13]
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16. [16]
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19. [19]
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20. [20]
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沈阳化工大学材料科学与工程学院沈阳 110142