Citation: Hui LI, Shuang LI, Yanhong WANG, Yun LÜ, Hongcheng LU. Synthesis and magnetic properties of one-dimensional chain rare-earth borates Cd₄LnO(BO₃)₃ (Ln=Yb, Dy)[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(11): 2371-2380. doi: 10.11862/CJIC.20260193 shu

Synthesis and magnetic properties of one-dimensional chain rare-earth borates Cd₄LnO(BO₃)₃ (Ln=Yb, Dy)

Hui LI ¹ ,
Shuang LI ¹ ,
Yanhong WANG ^{1, 2} ,
Yun LÜ ¹ ,
Hongcheng LU ^{1, 2,,}

1.
School of Chemistry and Chemical Engineering, Key Laboratory of Material Chemistry for Energy Conversion and Storage, Hubei Key Laboratory of Materials Chemistry and Service Failure, Huazhong University of Science and Technology, Wuhan 430074, China
2.
Wuhan National High Magnetic Field Center, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding author: Hongcheng LU, hcl@hust.edu.cn
Received Date: 16 June 2026
Revised Date: 30 September 2026

Figures(7)

The magnetic properties of two isostructural rare-earth borate compounds Cd₄LnO(BO₃)₃ [Ln=Yb (1), Dy (2)], whose crystal structures have been previously reported, were investigated. Single crystals of compound 1 were obtained and structurally characterized by single-crystal X-ray diffraction. The phase purity and isostructural relationship of compounds 1 and 2 were confirmed by powder X-ray diffraction, together with infrared spectroscopy. Their band gaps and thermal stabilities were characterized by UV-Vis-NIR spectroscopy and thermogravimetric analysis. Single-crystal X-ray diffraction reveals that [YbO₆] are connected via edge-sharing to form 1D chains of rare-earth magnetic ions in compound 1, and these chains are separated by borate groups and Cd²⁺ ions. Magnetic studies indicate that antiferromagnetic interactions dominate in both compounds 1 and 2, and no long-range magnetic order was observed down to 2 K.
- rare earths,
- one-dimensional chain,
- magnetic properties
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Synthesis and magnetic properties of one-dimensional chain rare-earth borates Cd4LnO(BO3)3 (Ln=Yb, Dy)

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Synthesis and magnetic properties of one-dimensional chain rare-earth borates Cd₄LnO(BO₃)₃ (Ln=Yb, Dy)