Citation: Qiuxiang FANG, Xinyue CHEN, Yuyang GUO, Penghui XIE, Pengbiao GENG. Application of metal-organic framework derived materials in lithium-sulfur battery separators[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(9): 1910-1932. doi: 10.11862/CJIC.20260188 shu

Application of metal-organic framework derived materials in lithium-sulfur battery separators

  • Corresponding author: Pengbiao GENG, pengbiaogeng@outlook.com
  • Received Date: 11 June 2026
    Revised Date: 7 August 2026

Figures(15)

  • Lithium-sulfur batteries are considered a candidate for the next generation of energy storage systems due to their high theoretical energy density (2 600 Wh·kg-1) and environmental friendliness. However, the shuttle effect of lithium polysulfides, the growth of lithium dendrites, and the volume expansion of sulfur cathodes severely limit the commercialization process of lithium-sulfur batteries. Metal-organic frameworks (MOFs)-derived materials with high specific surface area, abundant active sites, and structural stability can efficiently block lithium polysulfide shuttling and accelerate redox kinetics. They are ideal modified materials for lithium-sulfur battery separators. This review mainly introduces the application of MOF-derived materials in lithium-sulfur battery separators. Based on the types of metal-based materials (such as metal nanoparticles, oxides, sulfides, and other metal compounds), the synthesis strategies of MOF-derived materials are first elaborated. Secondly, the mechanism and effect of MOF-derived materials in separators are analyzed in depth. Finally, the development direction of their application in lithium-sulfur battery separators is discussed, aiming to provide a theoretical basis for future research.
  • 加载中
    1. [1]

      DU M, GENG P B, PEI C X, JIANG X Y, SHAN Y Y, HU W H, NI L B, PANG H. High-entropy prussian blue analogues and their oxide family as sulfur hosts for lithium-sulfur batteries[J]. Angew. Chem.‒Int. Edit., 2022, 61(41): e202209350  doi: 10.1002/anie.202209350

    2. [2]

      ZHU M Q, CAI C Y, QUAN K C, WEI Y X, CHEN H D, ZHANG S S, YI H P, GUO Z H, TENG X Y, ZHANG J D. Two-dimensional metal-organic frameworks with highly exposed active centers as a synergetic protective interlayer for shuttle-free lithium-sulfur batteries[J]. Chem. Eng. Sci., 2025, 306: 121325  doi: 10.1016/j.ces.2025.121325

    3. [3]

      LI W W, YANG B, PANG R X, ZHONG L X, ZHANG M Y. Polysulfide and Li Dendrite-blocking aramid nanofiber/metal-organic framework composite separators for advanced lithium-sulfur batteries[J]. ACS Appl. Nano Mater., 2023, 6: 1059-1071  doi: 10.1021/acsanm.2c04500

    4. [4]

      ZHAO R, REN H M, SI Y B, LI G, FU Y Z. MOF 801(Ce)-modified polypropylene separator as efficient barrier for lithium-organosulfide batteries[J]. Electrochim. Acta, 2023, 447: 142116  doi: 10.1016/j.electacta.2023.142116

    5. [5]

      LEE Y W, JUNG Y J, KIM S. Enhanced polysulfide redox reaction of Co/Fe dual-atom catalysts embedded in metal-organic framework-derived microporous carbon electrode for lithium-sulfur cells[J]. Small, 2026, 22: e11122  doi: 10.1002/smll.202511122

    6. [6]

      DANG B Y, GAO D Y, LUO Y H, ZHANG Z S, LI J D, WU F C. Bifunctional design of cerium-based metal-organic framework-808 membrane modified separator for polysulfide shuttling and dendrite growth inhibition in lithium-sulfur batteries[J]. J. Energy Storage, 2022, 52: 104981  doi: 10.1016/j.est.2022.104981

    7. [7]

      LI Q Q, ZHAO X Z, CAO S Y, LI L, LI J D, WU F C. A two-in-one design realized by metal-organic framework nanosheets for dendrite-free and durable lithium-sulfur batteries[J]. J. Alloy. Compd., 2023, 960: 170783  doi: 10.1016/j.jallcom.2023.170783

    8. [8]

      LIU X F, GAO X T, ZOU J X, WU Q, WANG W J, MENG S L, LI Y Q, TAN X Z. Sulfide-based MOF material modification of separators: Enhancing performance of lithium-sulfur batteries by suppressing shuttle effect[J]. Energy Sources Part A-Recovery Util. Environ. Eff., 2024, 46(1): 2828-2841

    9. [9]

      DU M, SHI J K, SHI Y X, ZHANG G X, YAN Y, GENG P B, TIAN Z Q, PANG H. Effects of O, S, and P in transition-metal compounds on the adsorption and catalytic ability of sulfur cathodes in lithium-sulfur batteries[J]. Chem. Sci., 2024, 15(25): 9775-9783  doi: 10.1039/D4SC01628A

    10. [10]

      LIU B R, TORRES J F, TAHERI M, XIONG P, LU T, ZHU J W, LIU Y, YU G H, TRICOLI A. Dual-ion flux management for stable high areal capacity lithium-sulfur batteries[J]. Adv. Energy Mater., 2022, 12: 2103444  doi: 10.1002/aenm.202103444

    11. [11]

      DU M, GENG P B, SHI J K, XU H Y, FENG W C, PANG H. Triple Effect of "Conductivity-adsorption-catalysis" enables MXene@ FeCoNiP to be sulfur hosts for lithium-sulfur batteries[J]. Inorg. Chem., 2024, 63(23): 10823-10831  doi: 10.1021/acs.inorgchem.4c01553

    12. [12]

      MAJID A, SHAH Y, ZAMAN F, YAHYA R, ABBAS S, ZHAO D F, HAMEED M U, LIU W, ZHANG T, WU Z P. Ti-MOF anchored polyaniline network on separator: A dual-function strategy for polysulfide immobilization and redox enhancement in Li-S batteries[J]. Fuel, 2026, 417: 138585  doi: 10.1016/j.fuel.2026.138585

    13. [13]

      XU H X, JIN L N, QIAN X Y, LI B. Nickel-carbon nanorods as multifunctional separators for highly efficient and long-lived lithium sulfur batteries[J]. Chem. Eng. Sci., 2026, 319: 122324  doi: 10.1016/j.ces.2025.122324

    14. [14]

      HUANG T N, WANG J Y, CHEN J W, JIN M L, YANG L, WANG X, CHEN Z W. Electronegativity-driven electronic structure tuning of Zr-O clusters for boosted polysulfide immobilization and conversion in lithium-sulfur batteries[J]. Chem. Eng. J., 2026, 528: 171983  doi: 10.1016/j.cej.2025.171983

    15. [15]

      DIAO W Y, XIE D, LI D L, TAO F Y, LIU C, SUN H Z, ZHANG X Y, LI W L, WU X L, ZHANG J P. Ion sieve membrane: Homogenizing Li+ flux and restricting polysulfides migration enables long life and highly stable Li-S battery[J]. J. Colloid Interface Sci., 2022, 627: 730-738  doi: 10.1016/j.jcis.2022.07.079

    16. [16]

      DENG T, MEN X L, JIAO X C, WANG J. CNTs decorated Cu-BTC with catalytic effect for high-stability lithium-sulfur batteries[J]. Ceram. Int., 2022, 48(3): 4352-4360  doi: 10.1016/j.ceramint.2021.10.230

    17. [17]

      SUN L, XU H G, WANG T Q, YUAN Y, QIAO Y J, LU X T, SU T H, XIA Z Y. Rational design of dual-functional Mo-doped Co9S8 superstructures for synergistic sulfur electrochemistry and lithium stabilization in advanced Li-S batteries[J]. ACS Appl. Mater. Interfaces, 2026, 18(1): 1533-1543

    18. [18]

      XIE W T, XIAO Y X, WANG Z C, XIA X Z, YU Y N, REN Y X, CHEN J J. 2D trimetallic metal-organic framework-based separator for lithium-sulfur batteries with high performance[J]. Small, 2025, 21(35): 2503425  doi: 10.1002/smll.202503425

    19. [19]

      PONNADA S, MANSOOR M, ASLFATTAHI N, BAYDOGAN N, NASKAR S, SHARMA R K, KIAI M S. Sustainable metal-organic framework co-engineered glass fiber separators for safer and longer cycle life of Li-S batteries[J]. J. Alloy. Compd., 2023, 941: 168962  doi: 10.1016/j.jallcom.2023.168962

    20. [20]

      ZHANG Y L, GUO C, ZHOU J, YAO X M, LI J, ZHUANG H F, CHEN Y T, CHEN Y F, LI S L, LAN Y Q. Anisotropically hybridized porous crystalline Li-S battery separators[J]. Small, 2023, 19(5): 2206616  doi: 10.1002/smll.202206616

    21. [21]

      ZHANG M C, ZHANG X J, XIA Q B, JIANG L, LIU L F, LI W, MA G Q, WANG D, LIU C Y, JIA J B, ZHOU J H, CHEN H H, XING C. Lewis acid-base interactions enable sustained catalytic activity for polysulfide conversion in lithium-sulfur batteries[J]. Rare Met., 2026, 45(1): e70176  doi: 10.1002/rar2.70176

    22. [22]

      XIE J, CHENG F, CHEN R Y, JIN Z, SUN L. Promoting overall sulfur redox kinetics for Li-S batteries via interfacial synergy in a NiS-NiTe2 heterostructure-modified separator[J]. J. Mater. Chem. A, 2024, 12(18): 10737-10744  doi: 10.1039/D4TA00036F

    23. [23]

      SUN L, WANG T Q, XIE J, QIAO Y J, LU X, LIU M H, LIU C, JIN Z. Constructing MoO2/Mo2C heterointerfaces on N-doped carbon microspheres for synergistic adsorption-catalysis of polysulfides in lithium-sulfur batteries[J]. J. Colloid Interface Sci., 2026, 717: 140391  doi: 10.1016/j.jcis.2026.140391

    24. [24]

      SUN L, XU H N, XIE J, YUAN Y, WANG H Z, WANG M, CHEN X, JIN Z. D-band center modulation of metallic co-incorporated Co7Fe3 alloy heterostructure for regulating polysulfides in highly efficient lithium-sulfur batteries[J]. Adv. Funct. Mater., 2025, 35(10): 1-10

    25. [25]

      ZHOU L Y, PAN H W, YIN G J, XIANG Y, TAN P P, LI X, JIANG Y Z. Tailoring the function of battery separators via the design of MOF coatings[J]. Adv. Funct. Mater., 2024, 34(23): 2314246  doi: 10.1002/adfm.202314246

    26. [26]

      WANG Y S, YANG Y Y, LIU Z X, YI J J, ZHAO Z L, WU C L. Synchronously modulating the universal diffusion of cations and anions by separator integration: A versatile approach toward safe and high-performance lithium-metal batteries[J]. J. Power Sources, 2025, 650: 237501  doi: 10.1016/j.jpowsour.2025.237501

    27. [27]

      YAN K J, SHEN C L, WANG H X, TAO F, ZHOU C, DONG C X, ZHANG G, CHEN X H, ZHANG L, LUO Y Z, XU X. Monodispersed MOF-modified nanofibers as versatile building blocks for the ion regulations in safe lithium-sulfur batteries[J]. ACS Appl. Mater. Interfaces, 2023, 15(24): 29094  doi: 10.1021/acsami.3c03055

    28. [28]

      XU Y H, JIANG Y X, YU X, GU Y, SHAKOURI M, ZHU R M. Synergistic Ni-Co metal nodes in a conjugated MOF-modified separator for high-performance lithium-sulfur batteries[J]. Adv. Funct. Mater., 2025, 12(45): e13282

    29. [29]

      ANBUNATHAN A, KARUPPIAH C, CHANG J K, JOSE R, YANG C C. In situ grown ZIF-67 particles on a glass fiber separator: The performance booster and anode defender for lithium-sulfurized polyacrylonitrile (SPAN) batteries[J]. ACS Appl. Energy Mater., 2023, 6: 3549-3565  doi: 10.1021/acsaem.3c00163

    30. [30]

      WANG X F, ZHANG G F, WANG Q, LI Y, GUO S W. Regulating the phase and catalytic activity of cobalt phosphide based on the morphological engineering of ZIF-67 to enhance the redox kinetics of polysulfides for high-performance lithium-sulfur batteries[J]. J. Alloy. Compd., 2023, 967: 171730  doi: 10.1016/j.jallcom.2023.171730

    31. [31]

      YE Z D, HE L F, YANG R X, WU W B, CHEN T, JIANG Q. Heterostructures for inhibiting polysulfide shuttling in lithium-sulfur batteries[J]. J. Energy Storage, 2026, 149: 120441  doi: 10.1016/j.est.2026.120441

    32. [32]

      HU X H, LI J T, ZHOU H J, HE Z J, LIANG H Y, OU W H, CHUNG L H, HE J. Ligand engineering of metal-organic frameworks as efficient electrocatalysts for wide-temperature lithium-sulfur batteries[J]. J. Power Sources, 2025, 629: 236053  doi: 10.1016/j.jpowsour.2024.236053

    33. [33]

      JIN L N, CHEN J Y, FU Z H, QIAN X Y, CHENG J, HAO Q Y, ZHANG K. ZIF-8/ZIF-67 derived ZnS@Co-N-C hollow core-shell composite and its application in lithium-sulfur battery[J]. Sustain. Mater. Technol., 2023, 35: e00571

    34. [34]

      ZHANG Y, HE R H, LIU H, LIU H H. A Co-MOF decorated gel separator with high safety and stable electrochemical performance for lithium-sulfurized poly(acrylonitrile) batteries[J]. Electrochim. Acta, 2025, 517: 145757  doi: 10.1016/j.electacta.2025.145757

    35. [35]

      LI D X, OUYANG Y, XIAO Y B, XIE Y F, ZENG Q H, YU S T. Core-shell structured flame-retardant separator mediated with metal-organic framework armor enables self-acceleration mechanism for dendrite-free and safer lithium metal batteries[J]. Adv. Funct. Mater., 2024, 34: 2314296  doi: 10.1002/adfm.202314296

    36. [36]

      YANG P, QIANG J, CHEN J Q, ZHANG Z Y, XU M, FEI L F. A versatile metal-organic-framework pillared interlayer design for high-capacity and long-life lithium-sulfur batteries[J]. Angew. Chem.‒Int. Edit, 2024, 64(2): e202414770

    37. [37]

      MINH N, HAI M, SONG S W, PARK S. Bimetallic metal organic framework-modified glass fiber as composite separator for lithium sulfur batteries[J]. Mater. Lett., 2025, 382: 137835  doi: 10.1016/j.matlet.2024.137835

    38. [38]

      FU C C, HE D, LIU X, GU W, QIN Y T, LU J, WANG C Y, WANG T Y. MXene/ZIF-67-based Janus separator for high-performance lithium-sulphur batteries[J]. J. Alloy. Compd., 2025, 1037: 182305  doi: 10.1016/j.jallcom.2025.182305

    39. [39]

      RAZA W, MEHMOOD A, HUSSAIN A, ALBALAWI K M, AHMAD M, AHMED M, EBAID M S, ASIM M, RAZA N, HUANG H Y, AO L H, LIU D Q, CAI X K. Synergizing ZIF-67 activity with polyetherimide to achieve dendrite and shuttle-free lithium sulfur batteries[J]. Chem. Eng. J., 2025, 519: 164940  doi: 10.1016/j.cej.2025.164940

    40. [40]

      QI D, YANG W, LIU Y, LUAN J, WEI Y J. Co-MOF-derived cobalt nanoparticles on carbon nanotube for high-performance lithium-sulfur battery separators[J]. J. Power Sources, 2025, 647: 237377  doi: 10.1016/j.jpowsour.2025.237377

    41. [41]

      LIN P R, QI Y H, GUO D Y, WANG X Y, FANG G Y. Bivalent cobalt as efficient catalyst intercalation layer improves polysulfide conversion in lithium-sulfur batteries[J]. ChemSusChem, 2023, 16: e202202379  doi: 10.1002/cssc.202202379

    42. [42]

      LIU H X, WANG X F, WANG Q, PEI C C, WANG H, GUO S W. Dual-functional cobalt phosphide nanoparticles for performance enhancement of lithium-sulfur battery[J]. J. Nanostructure Chem., 2024, 14(4): 281-292  doi: 10.1007/s40097-022-00517-x

    43. [43]

      GUPTA N, MURTHY Z V P. Synthesis and application of ZIF-67 on the performance of polysulfone blend membranes[J]. Mater. Today Chem., 2022, 23: 100685  doi: 10.1016/j.mtchem.2021.100685

    44. [44]

      SUN L S, ZHENG B, LIU W Q. Constructing high-throughput and highly adsorptive lithium-sulfur battery separator coatings based on three-dimensional hexagonal star-shaped MOF derivatives[J]. J. Colloid Interface Sci., 2025, 679: 197-205  doi: 10.1016/j.jcis.2024.09.208

    45. [45]

      FENG Y, WANG G, WANG L Y, JU J G, KANG W M, DENG N P, CHENG B W. Taming polysulfides and facilitating redox: Novel interlayer based on chestnut-like and multi-level structural materials for ultra-stable lithium-sulfur batteries[J]. J. Alloy. Compd., 2021, 851: 156859  doi: 10.1016/j.jallcom.2020.156859

    46. [46]

      WU S Y, LI X, GUAN Q H, ZHANG X, ZHANG Y Z, WANG J. Ultra-fine Co nanoparticles in-situ anchored on porous conductive nanosheets as efficient electrocatalysts for promoting sulfur redox reaction kinetics[J]. Mater. Lett., 2023, 337: 133938  doi: 10.1016/j.matlet.2023.133938

    47. [47]

      ZHANG H, CHEN J W, LI Z, PENG Y, XU J, WANG Y G. Operating lithium-sulfur batteries in an ultrawide temperature range from -50 ℃ to 70 ℃[J]. Adv. Funct. Mater., 2023, 33(48): 2304433  doi: 10.1002/adfm.202304433

    48. [48]

      GUO T, DING Y C, XU C, BAI W X, PAN S C, LIU M L, BI M, SUN J W, OUYANG X P, WANG X, FU Y S, ZHU J W. High crystallinity 2d π-d conjugated conductive metal-organic framework for boosting polysulfide conversion in lithium-sulfur batteries[J]. Adv. Sci., 2023, 10: 202302518

    49. [49]

      ZHANG B, QIE J X, WANG W J, LI YQ, CAO Y G, MAO Y Y, YOU J, Y LI C Y, XU Z M. Construction of flower-like Ni-Cu@C/HC nanoparticles capable of inhibiting polysulfide shuttling for high-performance lithium-sulfur batteries[J]. Chem. Eng. J., 2024, 480: 148022  doi: 10.1016/j.cej.2023.148022

    50. [50]

      KIM D, PARK Y, NAM K W. Inhibiting polysulfide shuttle and enhancing polysulfide redox: Conductive 2D metal-organic framework coated separators for lithium-sulfur batteries[J]. J. Alloy. Compd., 2024, 1009: 176812  doi: 10.1016/j.jallcom.2024.176812

    51. [51]

      ZHOU H J, ZHANG X L, ZOU M Y, GU S T, CAI Y P, HONG X J. MOF-derived bimetal ZnPd alloy as a separator coating with fast catalysis of lithium polysulfides for Li-S batteries[J]. ACS Appl. Energy Mater., 2021, 4(11): 13183-13190  doi: 10.1021/acsaem.1c02797

    52. [52]

      FENG J A, SHI C, DONG H H, ZHANG C Y, LIU W D, LIU Y, WANG T Y, ZHAO X X, CHEN S Q, SONG J J. Design of ZnSe-CoSe heterostructure decorated in hollow N-doped carbon nanocage with generous adsorption and catalysis sites for the reversibly fast kinetics of polysulfide conversion[J]. J. Energy Chem., 2023, 86: 135-145  doi: 10.1016/j.jechem.2023.07.007

    53. [53]

      ZHANG Q, ZHANG X, LEI D, QIAO S M, WANG Q, SHI X S, HUANG C H, HE G H, ZHANG F X. MOF-derived hollow carbon supported nickel-cobalt alloy catalysts driving fast polysulfide conversion for lithium-sulfur batteries[J]. ACS Appl. Mater. Interfaces, 2023, 15(12): 15377-15386  doi: 10.1021/acsami.2c21903

    54. [54]

      FENG P L, HOU W S, BAI Z, BAI Y, SUN K N, WANG Z H. Ultrathin two-dimensional bimetal NiCo-based MOF nanosheets as ultralight interlayer in lithium-sulfur batteries[J]. Chin. Chem. Lett., 2023, 34(4): 107427  doi: 10.1016/j.cclet.2022.04.025

    55. [55]

      LENG X L, ZENG J, YANG M D, LI C P, VATTIKUTI S V P, CHEN J L, LI S, SHIM J, GUO T, JO T K. Bimetallic Ni-Co MOF@PAN modified electrospun separator enhances high-performance lithium-sulfur batteries[J]. J. Energy Chem., 2023, 82: 484-496  doi: 10.1016/j.jechem.2023.03.017

    56. [56]

      ZHAN Y, CHEN A, PANG Y T, WANG S P. Electrocatalysis of NiCo quasi-MOFs for the solid-liquid conversion of Li2S/S8 in Li-S batteries[J]. Mater. Today Chem., 2025, 46: 102745  doi: 10.1016/j.mtchem.2025.102745

    57. [57]

      YANG Y Q, MA S L, XIA M Q, GUO Y, ZHANG Y, LIU L, ZHOU C, CHEN G H, WANG X Z, WU Q, YANG L J, HU Z. Elaborately converting hierarchical NiCo-LDH to rod-like LDH-decorated MOF as interlayer for high-performance lithium-sulfur battery[J]. Mater. Today Phys., 2023, 35: 101112  doi: 10.1016/j.mtphys.2023.101112

    58. [58]

      YANG X, AN Z F, ZHANG P, KIM S, YOO P J. Catalytic metal-organic framework-functionalized inverse-opal architectured polymeric separator for high-performance Li-S batteries[J]. Adv. Funct. Mater., 2025, 35(29): 2419983  doi: 10.1002/adfm.202419983

    59. [59]

      HE K Q, YANG H Q, WU X W, FENG J L, HU P, SHANG C Q. A multifunctional secondary based on heterogeneous Co-MnO@NC for depth-induced deposition and conversion of polysulfides in Li-S batteries[J]. Small, 2024, 20(44): 2403419  doi: 10.1002/smll.202403419

    60. [60]

      WANG X B, ZHAO C R, LIU B X, ZHAO S Q, ZHANG Y G, QIAN L T, CHEN Z J, WANG J T, WANG X, CHEN Z W. Creating edge sites within the 2D metal-organic framework boosts redox kinetics in lithium-sulfur batteries[J]. Adv. Energy Mater., 2022, 12: 2201960  doi: 10.1002/aenm.202201960

    61. [61]

      JIANG Y X, DU M, GENG P B, SUN B X, ZHU R M, PANG H. CoO/MoO3@nitrogen-doped carbon hollow heterostructures for efficient polysulfide immobilization and enhanced ion transport in lithium-sulfur batteries[J]. J. Colloid Interface Sci., 2024, 664: 617-625  doi: 10.1016/j.jcis.2024.03.015

    62. [62]

      LI H X, ZHENG W, WU H Z, FANG Y B, LI L, YUAN W H. Ultra-dispersed α-MoC1-x embedded in a plum-like N-doped carbon framework as a synergistic adsorption-electrocatalysis interlayer for high-performance Li-S batteries[J]. Small, 2024, 20: 2306140  doi: 10.1002/smll.202306140

    63. [63]

      HAO Q Y, QIAN X Y, JIN L N, CHENG J, ZHAO S L, CHEN J Y, ZHANG K, LI B Z, PANG S L, SHEN X Q. Application of ZIF-67/ZIF-8 derived Co3O4/ZnO heterojunction in lithium-sulfur battery separators[J]. J. Alloy. Compd., 2023, 967: 171605  doi: 10.1016/j.jallcom.2023.171605

    64. [64]

      ZHOU C, CHEN M J, DONG C X, WANG H, SHEN C L, WU X X, AN Q Y, CHANG G G, XU X, MAI L Q. The continuous efficient conversion and directional deposition of lithium (poly) sulfides enabled by bimetallic site regulation[J]. Nano Energy, 2022, 98: 107332  doi: 10.1016/j.nanoen.2022.107332

    65. [65]

      GUO L H, SHANG H, PENG J, LI H P, PAN H H. In situ growth of graphdiyne on ZnCo-ZIF for enhanced lithium-sulfur battery performance[J]. J. Mater. Chem. A, 2025, 13: 36436-36443  doi: 10.1039/D5TA04981D

    66. [66]

      CHU R R, NGUYEN T T, SONG H W, P M A, BAI Y Q, KIM H D, LEE H J, KIM H N. Crystal transformation engineering for effective polysulfides blocking layer for excellent energy density lithium-sulfur batteries[J]. Energy Storage Mater., 2023, 61: 102877  doi: 10.1016/j.ensm.2023.102877

    67. [67]

      LIU Z H, MAO X, LIU X, LUO Y, SHEN P K. N-doped Fe2(MoO4)3-decorated MoO3 nanorods via metal-organic framework-involved synthesis as a bifunctional nanoreactor for capturing and catalyzing polysulfides in lithium-sulfur batteries[J]. New J. Chem., 2022, 46(41): 19638-19642  doi: 10.1039/D2NJ03894C

    68. [68]

      LI F, QIAN X Y, JIN L N. MOF-derived MnS/N-C@CNT composites as separator coating materials for long-cycling Li-S batteries[J]. ACS Sustain. Chem. Eng., 2021, 9(46): 15469-15477  doi: 10.1021/acssuschemeng.1c04636

    69. [69]

      HUANG J Z, JIANG X W, LIU P F, WANG X. Sulfonic acid groups functionalized titanium-based metal-organic framework composite separators for lithium-sulfur battery applications[J]. ChemistrySelect, 2025, 10(23): e01108  doi: 10.1002/slct.202501108

    70. [70]

      LI Q C, LIU H, JIN B, LI L, SHENG Q D, CUI M Y, LI Y Y, LANG X Y, ZHU Y F, ZHAO L J, JIANG Q. Anchoring polysulfides via a CoS2/NC@1T MoS2 modified separator for high-performance lithium-sulfur batteries[J]. Inorg. Chem. Front., 2022, 10(3): 959-971

    71. [71]

      LI Z, SUN Y J, WU X J, YUAN H, YU Y, TAN Y Q. Boosting adsorption and catalysis of polysulfides by multifunctional separator for lithium-sulfur batteries[J]. ACS Energy Lett., 2022, 7: 4190-4197  doi: 10.1021/acsenergylett.2c02232

    72. [72]

      CUI H G, SUN Y J, YAN X Y, ZHANG X H, ZHAO X X, LIU B S. Spherical NiS2/Ni17S18-C accelerates ion transport and enhances kinetics for lithium-sulfur battery host material[J]. J. Phys. Chem. Solids, 2025, 197: 112419  doi: 10.1016/j.jpcs.2024.112419

    73. [73]

      HU S Y, YI M J, SIYAL S H, WU D, WANG H, ZHU Z Y, ZHANG J H. Metal-organic framework derived NiS2 hollow spheres as multifunctional reactors for synergistic regulation of polysulfide confinement and redox conversion[J]. J. Mater. Chem. A, 2021, 9(27): 15269-15281  doi: 10.1039/D1TA03621A

    74. [74]

      CAI X F, PAN H N, ZHANG J, QIU X Y, ZHAO X Y, ZHAO W M, YANG W, CHEN S Z. Carbon nanotube modified Zn-Co bimetallic selenide composites for lithium-sulfur batteries[J]. Energy Fuels, 2024, 38: 6478-6488  doi: 10.1021/acs.energyfuels.4c00180

    75. [75]

      HU Y J, JIN B, LIU H. High-efficiency metal selenide as an electrocatalyst in a separator for lithium-sulfur batteries[J]. Inorg. Chem. Front., 2025, 12(18): 5406-5418  doi: 10.1039/D5QI00452G

    76. [76]

      SHI X S, LEI D, QIAO S M, ZHANG Q, WANG Q, DENG X Y, LIU J H, HE G H, ZHANG F X. Metal-organic framework-derived NiSe2 nanoparticles on graphene for polysulfide conversion in lithium-sulfur batteries[J]. ACS Appl. Nano Mater., 2022, 5(5): 7402-7409  doi: 10.1021/acsanm.2c01370

    77. [77]

      WANG B, SUN D Y, REN Y L, ZHOU X Y, MA Y J, TANG S C, MENG X K. MOFs derived ZnSe/N-doped carbon nanosheets as multifunctional interlayers for ultralong-life lithium-sulfur batteries[J]. J. Mater. Sci. Technol., 2022, 125: 97-104  doi: 10.1016/j.jmst.2022.02.030

    78. [78]

      ZHANG X X, ZHANG F, SU Q M, HOU X H, CHEN R, CHEN Z, DU G H, SHI W H, SHI Y, LV Y J, HUANG W H, XU B S. MOF-derived MoC/WC heterostructure as bidirectional catalyst for lithium polysulfide enables high-performance lithium-sulfur batteries[J]. Small, 2025, 21(4): 2407283  doi: 10.1002/smll.202407283

    79. [79]

      LI S L, JING S D, PENG X L, YUAN L, LU S J, ZHANG Y F, FAN H S. Three-dimensional decussated superstructure consisting of carbon nanotubes wrapped with Co3Fe7/Co5.47N nanocrystals for super lithium sulfur batteries[J]. Mater. Today Chem., 2025, 43: 102488  doi: 10.1016/j.mtchem.2024.102488

    80. [80]

      RAZAQ R, MEHRAJ M, DIN U, SMÅBRÅTEN D R, EYUPOGLU V, JANAKIRAM S, SUNDE T O, ALLAHGOLI N, RETTENWANDER D, DENG L Y. Synergistic effect of bimetallic MOF modified separator for long cycle life lithium-sulfur batteries[J]. Adv. Energy Mater., 2024, 14(3): 2302897  doi: 10.1002/aenm.202302897

    81. [81]

      YIN J, ZHANG Y S, LIANG H F, ZHANG W L, ZHU Y P. Synthesis strategies of hard carbon anodes for sodium-ion batteries[J]. Mater. Rep.‒Energy, 2024, 4(2): 100268

    82. [82]

      WANG H, JAMIL S, FASEHULLAH M, BAO S J, LI Y, XU M W. Novel N-doped carbon nanotubes impregnated Mn spheres with polydopamine coating as an efficient polysulfide immobilizer for Li-S batteries[J]. Mater. Rep.‒Energy, 2024, 4(4): 100298

    83. [83]

      ZHAO X F, ZHU M Q, TANG C G, QUAN K C, TONG Q S, CAO H W, JIANG J C, YANG H T, ZHANG J D. ZIF-8@MXene-reinforced flame-retardant and highly conductive polymer composite electrolyte for dendrite-free lithium metal batteries[J]. J. Colloid Interface Sci., 2022, 620: 478-485  doi: 10.1016/j.jcis.2022.04.018

    84. [84]

      QU J F, LI S Q, SHU Y Y, QIU J Z, WANG J W, CAI Y H, YANG X G, WU Z Y, LI C M, HU J D. Metal-organic framework-derived hollow NiCo2O4 spinel arrays coupled with Pd-Ni bimetallic sites for efficient CO2 hydrogenation to formate[J]. Mater. Rep.‒Energy, 2025, 5(4): 100375

    85. [85]

      ZHANG Z P, WANG S. Microenvironment modulation of Ni center in Pt@Ni-hexahydroxytriphenylene composites for bifunctional lithium-sulfur separators[J]. J. Power Sources, 2025, 629: 235950  doi: 10.1016/j.jpowsour.2024.235950

    86. [86]

      XIA X Z, XIAO Y X, XIE W T, LIU J L, YU Y N, REN Y X, CHEN J J, YANG B, ZHANG J Y, YANG Z, HU W, YANG H. A sulfonate ligand hybrid ZIF-8 modified separator achieved high-performance Li-S batteries[J]. J. Mater. Chem. A, 2025, 13: 30632-30641  doi: 10.1039/D5TA05169J

    87. [87]

      YOU A Q, OUYANG Z Y, CHEN Q, XU W J, ZHANG H H. Controllable construction of selenide composite derived from hollow pencil-shaped MIL-88V and their application for high-performance lithium-sulfur batteries[J]. J. Energy Storage, 2026, 149: 120067  doi: 10.1016/j.est.2025.120067

    88. [88]

      ZHANG G, ZHOU C, LONG J C, LI Y, LV L, YAN K, CHEN X H, DONG C X, XU X, MAI L Q. Bottom-up synthesis of 2D heterostructures enables effective polysulfides inhibition and conversion[J]. Nano Res., 2023, 16(6): 8488-8496  doi: 10.1007/s12274-023-5535-z

    89. [89]

      QIAN X Y, XU H X, JIN L N, LI B. Low-carbon ZrO2/ZnO@C heterojunction coating: A polysulfide-immobilizing catalyst for high-retention Li-S batteries[J]. J. Energy Storage, 2026, 152: 120613  doi: 10.1016/j.est.2026.120613

    90. [90]

      SONG X H, REN Y R, QIN W, WANG H, ZENG Y P, LI M. Double MOF derived Co2Mo3O8-MoO2 nanorod cluster heterostructure as separator-mediator for high performance lithium-sulfur batteries[J]. J. Alloy. Compd., 2026, 1062: 187561  doi: 10.1016/j.jallcom.2026.187561

  • 加载中
    1. [1]

      Yingtong Shi , Guotong Xu , Guizeng Liang , Di Lan , Siyuan Zhang , Yanru Wang , Daohao Li , Guanglei Wu . PEG-VN改性PP隔膜用于高稳定性高效率锂硫电池. Acta Physico-Chimica Sinica, 2025, 41(7): 100082-0. doi: 10.1016/j.actphy.2025.100082

    2. [2]

      Meng-Yin Wang , Ruo-Bei Huang , Jian-Feng Xiong , Jing-Hua Tian , Jian-Feng Li , Zhong-Qun Tian . Critical Role and Recent Development of Separator in Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2307017-0. doi: 10.3866/PKU.WHXB202307017

    3. [3]

      Han WANG , Baihui CHEN , Chunlai WANG , Zhitao SHAO . Preparation and performance of lithium-sulfur battery of Ni2P/carbon nanotube modified separator. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 933-943. doi: 10.11862/CJIC.20250334

    4. [4]

      Yan'e LIU , Shengli JIA , Yifan JIANG , Qinghua ZHAO , Yi LI , Xinshu CHANG . MoO3/cellulose derived carbon aerogel: Fabrication and performance as cathode for lithium-sulfur battery. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1565-1573. doi: 10.11862/CJIC.20250054

    5. [5]

      Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382

    6. [6]

      Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO2 Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026

    7. [7]

      Mengyang LI , Zhonghao NIU , Hao XU , Jingli XIE . One-pot synthesis of 4H-pyran derivatives catalyzed by viologen-modified metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1513-1522. doi: 10.11862/CJIC.20250205

    8. [8]

      Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393

    9. [9]

      Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO2 Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046

    10. [10]

      Xiaoqi LAN , Wei LI , Deyi YANG , Hao WANG , Zheng LIU , Rongting GUO , Qizhi CHEN . Preparation and electrochemical performance of “sandwich structured” MXene Ti3C2Tx/hollow ZIF-67 sulfur host composites. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 760-772. doi: 10.11862/CJIC.20250273

    11. [11]

      Yijing GU , Huan PANG , Rongmei ZHU . Applications of nickel-based metal-organic framework compounds in supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2029-2038. doi: 10.11862/CJIC.20250186

    12. [12]

      Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270

    13. [13]

      Shuangshuang Mao ,  Juhua Luo ,  Bingjie Han ,  Jiahuan Shi ,  Yujia Gu . Covalent organic framework-derived Fe3C/NC/TiO2 heterostructures for high-performance electromagnetic wave absorption. Acta Physico-Chimica Sinica, 2026, 42(7): 100290-. doi: 10.1016/j.actphy.2026.100290

    14. [14]

      Tao Wang , Qin Dong , Cunpu Li , Zidong Wei . Sulfur Cathode Electrocatalysis in Lithium-Sulfur Batteries: A Comprehensive Understanding. Acta Physico-Chimica Sinica, 2024, 40(2): 2303061-0. doi: 10.3866/PKU.WHXB202303061

    15. [15]

      Zifang ZHAO , Jingteng FENG , Jiaxin LI , Cong YANG , Linhan XING , Weifeng HUANG , Mingming HAN . Research progress and prospects on electrolyte additives for aqueous Zn-I2 battery. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1345-1367. doi: 10.11862/CJIC.20260066

    16. [16]

      Yajie Li , Bin Chen , Yiping Wang , Hui Xing , Wei Zhao , Geng Zhang , Siqi Shi . Inhibiting Dendrite Growth by Customizing Electrolyte or Separator to Achieve Anisotropic Lithium-Ion Transport: A Phase-Field Study. Acta Physico-Chimica Sinica, 2024, 40(3): 2305053-0. doi: 10.3866/PKU.WHXB202305053

    17. [17]

      Ping LI , Geng TAN , Xin HUANG , Fuxing SUN , Jiangtao JIA , Guangshan ZHU , Jia LIU , Jiyang LI . Green synthesis of metal-organic frameworks with open metal sites for efficient ammonia capture. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2063-2068. doi: 10.11862/CJIC.20250020

    18. [18]

      Ri Peng ,  Yuxin Xie ,  Shuai Yuan ,  Ruwei Shen ,  Dunru Zhu . Metal-Organic Frameworks (2014-2024): A decade pursuit for top performance. Acta Physico-Chimica Sinica, 2026, 42(7): 100225-. doi: 10.1016/j.actphy.2025.100225

    19. [19]

      Ting YANG , Jia AN , Jinyu ZHANG , Ruonan FAN , Rong YAN , Xiaoxia JING , Panpan CHANG , Wei YAN . Synergistic enhancement of ion migration and sulfur conversion kinetics in lithium-sulfur batteries by CeO2/g-C3N4. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 519-530. doi: 10.11862/CJIC.20250274

    20. [20]

      Wen WANG , Ying XU , Gang XIONG , Lixin YOU , Yaguang SUN . Pd-NHC-functionalized La-metal-organic framework for efficient Suzuki-Miyaura cross-coupling reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1475-1484. doi: 10.11862/CJIC.20260025

Metrics
  • PDF Downloads(13)
  • Abstract views(326)
  • HTML views(51)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return