Citation: Chunliu HUANG, Ya′nan WU, Muyao ZHAO, Sisi WANG, Hua LU. Research progress on N₂O₂-dipyrrin metal complexes[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(11): 2290-2310. doi: 10.11862/CJIC.20260187 shu

Research progress on N₂O₂-dipyrrin metal complexes

College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of the Ministry of Education, Zhejiang Key Laboratory of Organosilicon Material Technology, Hangzhou Normal University, Hangzhou 311121, China

Corresponding author: Sisi WANG, sisiwang@hznu.edu.cn Hua LU, hualu@hznu.edu.cn
Received Date: 6 June 2026
Revised Date: 1 September 2026

Figures(22)

N₂O₂-dipyrrin metal complexes are emerging as a unique class of functional metallic platforms, owing to the efficient light-harvesting properties of the parent skeleton and the structural stability induced by multidentate coordination. Compared to traditional N, N-bidentate dipyrrin ligands, the N₂O₂ tetradentate ligand, through two pyrrole nitrogen and two phenolate oxygen donors, constructs a potential trianionic coordination environment. This design enhances the rigidity of the molecular skeleton while retaining axial coordination and tunability at the metal center, thereby significantly expanding the structural and functional diversity of the resulting complexes. In recent years, this field has gradually expanded from early main-group metal coordination systems (e.g., Al, Si, Ge, and Sn) to heavy main-group metals (e.g., Ga, In, Sb, and Bi), as well as redox-active transition metal systems (e.g., Mn, Co, Ni, Cu, Pt, and Au). This review, centered on N₂O₂ tetradentate ligands, systematically surveys related studies by metal center and functional type, and further compares the effects of metal radius, axial ligands, substituent electronic effects, and ligand non-innocence on photophysical, electrochemical, and catalytic behaviors across different systems. By summarizing representative photophysical and electrochemical parameters, this review emphasizes the developmental trend of these complexes from rigid luminescent frameworks toward tunable metal-ligand cooperative platforms. It also discusses current key bottlenecks in near-infrared efficiency, structural stability, comparable electrochemical data, validation of biological applications, and elucidation of catalytic mechanisms, aiming to provide more targeted guidance for future molecular design and functional applications.
- N₂O₂-dipyrrin,
- metal complexes,
- tetradentate ligands,
- structure-property relationships,
- coordination chemistry
1. [1]
  WOOD T E, THOMPSON A. Advances in the chemistry of dipyrrins and their complexes[J]. Chem. Rev., 2007, 107(5): 1831-1861 doi: 10.1021/cr050052c
2. [2]
  BUMAGINA N A, ANTINA E V, BEREZIN M B. Features of 1H NMR spectra of structurally related open-chain oligopyrroles and their coordination compounds[J]. Coord. Chem. Rev., 2025, 541: 216810 doi: 10.1016/j.ccr.2025.216810
3. [3]
  SETSUNE J. 2, 2′-bipyrrole-based porphyrinoids[J]. Chem. Rev., 2017, 117(4): 3044-3101 doi: 10.1021/acs.chemrev.6b00430
4. [4]
  SCHOMBERG-SANCHEZ I S, ROBINSON W C, SANDERSON M E, MOSQUERA M A, LEMON C M. Hangman dipyrrin complexes[J]. Chem. Sci., 2026, 17(1): 602-616 doi: 10.1039/D5SC06893B
5. [5]
  LOUDET A, BURGESS K. Bodipy dyes and their derivatives: Syntheses and spectroscopic properties[J]. Chem. Rev., 2007, 107(11): 4891-4932 doi: 10.1021/cr078381n
6. [6]
  PRASAD NAMBIAR A, NAG P, MARIAM IPE R, REDDY VENNAPUSA S, GOKULNATH S. Conformationally locked cyclo[2]dipyrrins linked with anthracene subunits: Synthesis and chiroptical properties[J]. Angew. Chem. ‒Int. Edit., 2023, 62(30): e202306566 doi: 10.1002/anie.202306566
7. [7]
  ZUO H Q, LIU Y R, WANG L, LI R T, GUO X, GUO L Y, LI H, LI M U, ZHANG X F, JIAO L J, XIAO Y, HAO E. A general strategy to develop intramolecular spirocyclic boron dipyrromethene fluorophores for self-blinking super-resolution imaging[J]. Angew. Chem. ‒Int. Edit., 2025, 64(51): e202518973 doi: 10.1002/anie.202518973
8. [8]
  LIU H, ZHANG W N, WANG S S, ZHOU Q L, XU N, ZHANG W Z, REN H J, YANG M, LU H, ZHENG X C, TIAN J W. Selenocysteine-activatable near-infrared fluorescent probe for screening of anti-inflammatory components in herbs[J]. Anal. Chem., 2025, 97(1): 75-85 doi: 10.1021/acs.analchem.4c02157
9. [9]
  SUN Y J, TIAN L, TAUYAKHALE K G, MACK J, NYOKONG T, LU H, GAI L Z. Julolidinyl-engineered BODIPY and Aza-BODIPY dyes: Versatile photofunctional dyes for advanced applications[J]. Coord. Chem. Rev., 2026, 558: 217776 doi: 10.1016/j.ccr.2026.217776
10. [10]
  WANG S S, BI X, ZHU H, JI X B, LU H, SHEN Z. Rational design of aggregation-induced emission-active bisboron complexes (BOQHYS) for high-fidelity lipid droplet imaging[J]. Aggregate, 2025, 6(2): e670 doi: 10.1002/agt2.670
11. [11]
  WU S M, ZHANG W Z, LI C R, NI Z G, CHEN W F, GAI L Z, TIAN J W, GUO Z J, LU H. Rational design of CT-coupled J-aggregation platform based on Aza-BODIPY for highly efficient phototherapy[J]. Chem. Sci., 2024, 15(16): 5973-5979 doi: 10.1039/D3SC06976A
12. [12]
  WANG S S, GAI L Z, CHEN Y C, JI X B, LU H, GUO Z J. Mitochondria-targeted BODIPY dyes for small molecule recognition, bio-imaging and photodynamic therapy[J]. Chem. Soc. Rev., 2024, 53(8): 3976-4019 doi: 10.1039/D3CS00456B
13. [13]
  ALBERS A, MASTHOFF M, FERNÁNDEZ G. Self-assembled (aza)BODIPY dyes for biomedical in vivo imaging[J]. Angew. Chem. ‒Int. Edit., 2026, 65(8): e25491 doi: 10.1002/anie.202525491
14. [14]
  IQBAL M S, AHMAD H, YU C, HUANG H, GUO B. Near-infrared BODIPY-based theranostic agents for photothermal and combinatory therapy of cancers, where do we stand in year 2025[J]. Coord. Chem. Rev., 2025, 541: 216781 doi: 10.1016/j.ccr.2025.216781
15. [15]
  CHEN L X, LEI S X, ZHANG J S, LEI Y F, QI Q Y, LI Z T, TIAN J. Hierarchical assembly of fluorinated BODIPY-based nanoribbons for highly efficient metal-free photocatalytic hydrogen production[J]. J. Am. Chem. Soc., 2026, 148(10): 11127-11137 doi: 10.1021/jacs.5c22856
16. [16]
  BUMAGINA N A, ANTINA E V, KSENOFONTOV A A, ANTINA L A, KALYAGIN A A, BEREZIN M B. Basic structural modifications for improving the practical properties of BODIPY[J]. Coord. Chem. Rev., 2022, 469: 214684 doi: 10.1016/j.ccr.2022.214684
17. [17]
  LIU X, CHI W J, QIAO Q L, KOKATE S V, CABRERA E P, XU Z C, LIU X G, CHANG Y T. Molecular mechanism of viscosity sensitivity in BODIPY rotors and application to motion-based fluorescent sensors[J]. ACS Sens., 2020, 5(3): 731-739 doi: 10.1021/acssensors.9b01951
18. [18]
  ZHANG D X, LIU G R, JIANG X D. Non-aryl substituted Aza-BODIPYs at 1, 7-or 3, 5-sites: Synthesis, structures, optical properties, and applications[J]. J. Mater. Chem. C, 2023, 11(5): 1668-1677 doi: 10.1039/D2TC05048J
19. [19]
  SINGH R S, PAITANDI R P, GUPTA R K, PANDEY D S. Recent developments in metal dipyrrin complexes: Design, synthesis, and applications[J]. Coord. Chem. Rev., 2020, 414: 213269 doi: 10.1016/j.ccr.2020.213269
20. [20]
  SCHOMBERG-SANCHEZ I S, JANUSZ W A, LEMON C M. Beyond bodipy: Dipyrrin complexes of p-block elements[J]. J. Coord. Chem., 2025, 78(22): 2449-2502 doi: 10.1080/00958972.2025.2539945
21. [21]
  KIM H, BURGHART A, WELCH M B, REIBENSPIES J, BURGESS K. Synthesis and spectroscopic properties of a new 4-bora-3a, 4a-diaza-s-indacene (BODIPY®) dye[J]. Chem. Commun., 1999, 18: 1889-1890
22. [22]
  CHEN J, BURGHART A, DERECSKEI-KOVACS A, BURGESS K. 4, 4-difluoro-4-bora-3a, 4a-diaza-s-indacene (BODIPY) dyes modified for extended conjugation and restricted bond rotations[J]. J. Org. Chem., 2000, 65(10): 2900-2906 doi: 10.1021/jo991927o
23. [23]
  SHI Z X, HAN X, HU W B, BAI H, PENG B, JI L, FAN Q L, LI L, HUANG W. Bioapplications of small molecule Aza-BODIPY: From rational structural design to in vivo investigations[J]. Chem. Soc. Rev., 2020, 49(21): 7533-7567 doi: 10.1039/D0CS00234H
24. [24]
  KAUR M, JANAAGAL A, BALSUKURI N, GUPTA I. Evolution of Aza-BODIPY dyes-a hot topic[J]. Coord. Chem. Rev., 2024, 498: 215428 doi: 10.1016/j.ccr.2023.215428
25. [25]
  LOUDET A, BANDICHHOR R, BURGESS K, PALMA A, MCDONNELL S O, HALL M J, O′SHEA D F. B, O-chelated azadipyrromethenes as near-IR probes[J]. Org. Lett., 2008, 10(21): 4771-4774 doi: 10.1021/ol8018506
26. [26]
  THAKUR M S, SINGH N, SHARMA A, RANA R, ABDUL SYUKOR A R, NAUSHAD M, KUMAR S, KUMAR M, SINGH L. Metal coordinated macrocyclic complexes in different chemical transformations[J]. Coord. Chem. Rev., 2022, 471: 214739 doi: 10.1016/j.ccr.2022.214739
27. [27]
  BASUMATARY B, TSURUDA H, SZCZEPANIK D W, LEE J, RYU J, MORI S, YAMAGATA K, TANAKA T, MURANAKA A, UCHIYAMA M, KIM J, ISHIDA M, FURUTA H. Metalla-carbaporphyrinoids consisting of an acyclic N-confused tetrapyrrole analogue served as stable near-infrared-Ⅱ dyes[J]. Angew. Chem. ‒Int. Edit., 2024, 63(23): e202405059 doi: 10.1002/anie.202405059
28. [28]
  TANAKA Y, MURAYAMA T, MURANAKA A, IMAI E, UCHIYAMA M. Ring-opened hemiporphyrazines: Helical molecules exhibiting circularly polarized luminescence[J]. Chem. ‒Eur. J., 2020, 26(8): 1768-1771 doi: 10.1002/chem.201905246
29. [29]
  SCHRAGE B R, GAIRE S, MAMATTAH K, NEVONEN D E, NEMYKIN V N, ZIEGLER C J. Heliphyrin: A ring open porphyrinoid with helical chirality[J]. Inorg. Chem. Front., 2024, 11(13): 3937-3940 doi: 10.1039/D4QI00743C
30. [30]
  IKEDA C, UEDA S, NABESHIMA T. Aluminium complexes of N₂O₂-type dipyrrins: The first hetero-multinuclear complexes of metallo-dipyrrins with high fluorescence quantum yields[J]. Chem. Commun., 2009, 18: 2544-2546
31. [31]
  SAIKAWA M, DAICHO M, NAKAMURA T, UCHIDA J, YAMAMURA M, NABESHIMA T. Synthesis of a new family of ionophores based on aluminum-dipyrrin complexes (aldipys) and their strong recognition of alkaline earth ions[J]. Chem. Commun., 2016, 52(21): 4014-4017 doi: 10.1039/C6CC00250A
32. [32]
  SUMIYOSHI A, CHIBA Y, MATSUOKA R, NODA T, NABESHIMA T. Efficient luminescent properties and cation recognition ability of heavy group 13 element complexes of N₂O₂- and N₂O₄-type dipyrrins[J]. Dalton Trans., 2019, 48(35): 13169-13175 doi: 10.1039/C9DT02403D
33. [33]
  LYSTROM L, SHUKLA M, SUN W, KILINA S. Extending fluorescence of meso-aryldipyrrin indium(Ⅲ) complexes to near-infrared regions via electron withdrawing or π-expansive aryl substituents[J]. J. Phys. Chem. Lett., 2021, 12(33): 8009-8015 doi: 10.1021/acs.jpclett.1c02150
34. [34]
  FORDE A, LYSTROM L, SUN W, KILIN D, KILINA S. Improving near-infrared emission of meso-aryldipyrrin indium(Ⅲ) complexes via annulation bridging: Excited-state dynamics[J]. J. Phys. Chem. Lett., 2022, 13(39): 9210-9220 doi: 10.1021/acs.jpclett.2c02115
35. [35]
  GODARD A, GALÁN L A, ROUILLON J, AL SHEHIMY S, TAJANI W, CAVE C, MALACEA-KABBARA R, ROUSSELIN Y, LE GENDRE P, FIHEY A, BENDELLAA M, BUSSER B, SANCEY L, LE GUENNIC B, BUCHER C, MAURY O, GOZE C, BODIO E. Al(Ⅲ) and Ga(Ⅲ) bisphenolate azadipyrromethene-based "N₂O₂" complexes as efficient nir-fluorophores[J]. Inorg. Chem., 2023, 62(13): 5067-5080 doi: 10.1021/acs.inorgchem.2c03918
36. [36]
  BENDELLAA M, CAVE C, GODARD A, DALONNEAU F, SICKINGER A, GOZE C, MAURY O, LE GENDRE P, BODIO E, BUSSER B, SANCEY L. Wazagay: An innovative Aza-BODIPY-derived near-infrared fluorescent probe for enhanced tumor imaging[J]. J. Med. Chem., 2024, 67(18): 16635-16648 doi: 10.1021/acs.jmedchem.4c01435
37. [37]
  OYELOWO M, JEAYDI T I, ZIEGLER C J, NEMYKIN V N. Design of stable diradicals based on group 13 dyes of N₂O₂-bis(phenolate) aza-dipyrromethene and Aza-BODIPY[J]. Inorg. Chem., 2025, 64(35): 17946-17959 doi: 10.1021/acs.inorgchem.5c03026
38. [38]
  YUAN Y C, MELLAH M, SCHULZ E, DAVID O R P. Making chiral salen complexes work with organocatalysts[J]. Chem. Rev., 2022, 122(9): 8841-8883 doi: 10.1021/acs.chemrev.1c00912
39. [39]
  ONNEKEN C, MORACK T, SOIKA J, SOKOLOVA O, NIEMEYER N, MÜCK-LICHTENFELD C, DANILIUC C G, NEUGEBAUER J, GILMOUR R. Light-enabled deracemization of cyclopropanes by al-salen photocatalysis[J]. Nature, 2023, 621(7980): 753-759 doi: 10.1038/s41586-023-06407-8
40. [40]
  SAKAMOTO N, IKEDA C, YAMAMURA M, NABESHIMA T. Structural interconversion and regulation of optical properties of stable hypercoordinate dipyrrin-silicon complexes[J]. J. Am. Chem. Soc., 2011, 133(13): 4726-4729 doi: 10.1021/ja2001924
41. [41]
  NAKANO K, KOBAYASHI K, NOZAKI K. Tetravalent metal complexes as a new family of catalysts for copolymerization of epoxides with carbon dioxide[J]. J. Am. Chem. Soc., 2011, 133(28): 10720-10723 doi: 10.1021/ja203382q
42. [42]
  OHKAWARA T, SUZUKI K, NAKANO K, MORI S, NOZAKI K. Facile estimation of catalytic activity and selectivities in copolymerization of propylene oxide with carbon dioxide mediated by metal complexes with planar tetradentate ligand[J]. J. Am. Chem. Soc., 2014, 136(30): 10728-10735 doi: 10.1021/ja5046814
43. [43]
  YAMAMURA M, TAKIZAWA H, SAKAMOTO N, NABESHIMA T. Monomeric and dimeric red/nir-fluorescent dipyrrin-germanium complexes: Facile monomer-dimer interconversion driven by acid/base additions[J]. Tetrahedron Lett., 2013, 54(51): 7049-7052 doi: 10.1016/j.tetlet.2013.10.073
44. [44]
  YAMAMURA M, ALBRECHT M, ALBRECHT M, NISHIMURA Y, ARAI T, NABESHIMA T. Red/near-infrared luminescence tuning of group-14 element complexes of dipyrrins based on a central atom[J]. Inorg. Chem., 2014, 53(3): 1355-1360 doi: 10.1021/ic402116j
45. [45]
  KORZUN A, CRESPI S, GOLZ C, BISMUTO A. Replacing the BO in BODIPY: Unlocking the path to sbdipy and bidipy chromophores[J]. Chem. Sci., 2023, 14(24): 6579-6584 doi: 10.1039/D3SC01493B
46. [46]
  LIU C, DAI Y Y, HAN Q, LIU C M, SU Y T. Crystalline heaviest pnictogen-dipyrromethenes: Isolation, characterization, and reactivity[J]. Chem. Commun., 2023, 59(15): 2161-2164 doi: 10.1039/D2CC05736K
47. [47]
  AGOU T, KUROIWA S, FUKUMOTO H, NABESHIMA T. Synthesis and optical properties of antimony(Ⅴ) complexes of a trianionic N₂O₂-type tetradentate dipyrrin ligand[J]. Chem. Commun., 2024, 60(34): 4557-4560 doi: 10.1039/D4CC00630E
48. [48]
  AGOU T, KUROIWA S, MORIYAMA R, KURODA T, KUBO K, FUKUMOTO H, MORITA M, INOUE R, NABESHIMA T. Synthesis and structural characterization of Sb(Ⅲ) and Bi(Ⅲ) complexes with an N₂O₂-type tetradentate dipyrrin ligand[J]. Chem. Commun., 2025, 61(39): 7141-7144 doi: 10.1039/D5CC01037C
49. [49]
  RAUSARIA S, KAMADULSKI A, RATH N P, BRYANT L, CHEN Z, SALVEMINI D, NEUMANN W L. Manganese(Ⅲ) complexes of bis(hydroxyphenyl)dipyrromethenes are potent orally active peroxynitrite scavengers[J]. J. Am. Chem. Soc., 2011, 133(12): 4200-4203 doi: 10.1021/ja110427e
50. [50]
  EL GHACHTOULI S, WÓJCIK K, COPEY L, SZYDLO F, FRAMERY E, GOUX-HENRY C, BILLON L, CHARLOT M F, GUILLOT R, ANDRIOLETTI B, AUKAULOO A. Dipyrrinphenol-Mn(Ⅲ) complex: Synthesis, electrochemistry, spectroscopic characterisation and reactivity[J]. Dalton Trans., 2011, 40(36): 9090-9093 doi: 10.1039/c1dt10868a
51. [51]
  LECARME L, CHIANG L, MOUTET J, LECONTE N, PHILOUZE C, JARJAYES O, STORR T, THOMAS F. The structure of a one-electron oxidized Mn(Ⅲ)-bis(phenolate)dipyrrin radical complex and oxidation catalysis control via ligand-centered redox activity[J]. Dalton Trans., 2016, 45(41): 16325-16334 doi: 10.1039/C6DT02163H
52. [52]
  FANG Y, OSTERLOH W R, DESBOIS N, PACQUELET S, FLEURAT-LESSARD P, GROS C P, KADISH K M. Solvent and anion effects on the electrochemistry of manganese dipyrrin-bisphenols[J]. Inorg. Chem., 2020, 59(21): 15913-15927 doi: 10.1021/acs.inorgchem.0c02416
53. [53]
  KOCHEM A, CHIANG L, BAPTISTE B, PHILOUZE C, LECONTE N, JARJAYES O, STORR T, THOMAS F. Ligand-centered redox activity in cobalt(Ⅱ) and nickel(Ⅱ) bis(phenolate)-dipyrrin complexes[J]. Chem. ‒Eur. J., 2012, 18(46): 14590-14593 doi: 10.1002/chem.201202882
54. [54]
  SHAN W Q, DESBOIS N, PACQUELET S, STÉPHANE B, ROUSSELIN Y, CONRADIE J, GHOSH A, GROS C P, KADISH K M. Ligand noninnocence in cobalt dipyrrin-bisphenols: Spectroscopic, electrochemical, and theoretical insights indicating an emerging analogy with corroles[J]. Inorg. Chem., 2019, 58(12): 7677-7689 doi: 10.1021/acs.inorgchem.8b03006
55. [55]
  VAN LEEST N P, STROEK W, SIEGLER M A, VAN DER VLUGT J I, DE BRUIN B. Ligand-mediated spin-state changes in a cobalt-dipyrrin-bisphenol complex[J]. Inorg. Chem., 2020, 59(17): 12903-12912 doi: 10.1021/acs.inorgchem.0c01979
56. [56]
  LECARME L, KOCHEM A, CHIANG L, MOUTET J, BERTHIOL F, PHILOUZE C, LECONTE N, STORR T, THOMAS F. Electronic structure and reactivity of one-electron-oxidized copper(Ⅱ) bis(phenolate)-dipyrrin complexes[J]. Inorg. Chem., 2018, 57(16): 9708-9719 doi: 10.1021/acs.inorgchem.8b00044
57. [57]
  YAMAMURA M, TAKIZAWA H, GOBO Y, NABESHIMA T. Stable neutral radicals of planar N₂O₂-type dipyrrin platinum complexes: Hybrid radicals of the delocalized organic π-orbital and platinum d-orbital[J]. Dalton Trans., 2016, 45(16): 6834-6838 doi: 10.1039/C5DT05039A
58. [58]
  THOMAS K E, DESBOIS N, CONRADIE J, TEAT S J, GROS C P, GHOSH A. Gold dipyrrin-bisphenolates: A combined experimental and DFT study of metal-ligand interactions[J]. RSC Adv., 2020, 10(1): 533-540 doi: 10.1039/C9RA09228E
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17. [17]
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18. [18]
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19. [19]
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20. [20]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103

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沈阳化工大学材料科学与工程学院沈阳 110142

Research progress on N2O2-dipyrrin metal complexes

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Research progress on N₂O₂-dipyrrin metal complexes