Citation: Jilei LIANG, Mengmeng WU, Lü QI, Yunqi LIU, Chenguang LIU. In-situ preparation of mesoporous carbon-encapsulated NiMoS hydrodesulfurization catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(10): 2127-2137. doi: 10.11862/CJIC.20260127 shu

In-situ preparation of mesoporous carbon-encapsulated NiMoS hydrodesulfurization catalyst

Jilei LIANG ^{1, #,,} ,
Mengmeng WU ^{1, #} ,
Lü QI ^2,, ,
Yunqi LIU ³ ,
Chenguang LIU ³

1.
School of Chemistry, Chemical and Materials Engineering, Taizhou University, Taizhou, Jiangsu 225300, China
2.
School of Petrochemical Engineering, Changzhou University, Changzhou, Jiangsu 213164, China
3.
State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, Shandong 266580, China

Corresponding author: Jilei LIANG, liangjilei@tzu.edu.cn Lü QI, qilv1983@cczu.edu.cn
Received Date: 14 April 2026
Revised Date: 22 August 2026

Figures(9)

Using Ni-Mo bimetallic-oxygen clusters as precursors, a mesoporous carbon-coated high-activity NiMoS hydrodesulfurization catalyst (NiMoS/C-FD) was constructed through an in-situ synthesis strategy. By combining the introduction of the precursor and the preparation of the support, the spatial encapsulation and uniform dispersion of metal active components in the mesoporous carbon support were achieved. The as-prepared catalyst was analyzed using various techniques such as X-ray diffraction, N₂ adsorption-desorption, scanning electron microscopy, high-resolution transmission electron microscopy, X-ray photoelectron spectroscopy, etc. Compared with the reference catalyst (NiMoS/C-IM) prepared by the traditional impregnation method, the MoS₂ particles of the as-prepared catalyst (NiMoS/C-FD) had a smaller size, higher dispersion, more sulfurization, and formed more highly active NiMoS phases. In the hydrodesulfurization evaluation, the catalyst showed excellent catalytic performance, with a conversion rate of 93.2%. The reaction rate constant and turnover frequency reached 1.6×10^-6 mol·g^-1·s^-1 and 3.3×10^-3 s^-1, respectively, which were significantly higher than NiMoS/C-IM.
- in-situ synthesis,
- hydrodesulfurization,
- encapsulation,
- metal-oxygen cluster
1. [1]
  ZHOU W W, HAN Z Y, CHEN Z P, DUAN Y F, KANG J, FAN F, TIAN C, ZHANG X M. Hierarchical TS-1 zeolite loaded with NiMo catalysts: Preparation and performance in hydrodesulfurization[J]. Chinese J. Inorg. Chem., 2023,39(5):891-905. doi: 10.11862/CJIC.2023.049
2. [2]
  SUN F Y, BAO W J, YUE C L, ZHANG C, JU Y W, DI H P, XU C Z, XU Y Y, LIU N, HAO H Y, LU Y K. Hydrogen activation and migration: Confined sulfidation coupling with in-situ intercalation to construct NiS₂@NiMoS nanoreactor for promoting hydrodesulfurization by hydrogen spillover effect[J]. Appl. Catal. B-Environ., 2025,367125084. doi: 10.1016/j.apcatb.2025.125084
3. [3]
  WANG X P, MA H J, WANG D E, TIAN Z J. Preparation of the slurry bed hydrodesulfurization catalyst MoS₂ promoted by dispersed cobalt by means of hydrothermal synthesis[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2021,37(6):1287-1297.
4. [4]
  WU P Y, LAN L, JI S F, WEI N, LÜ Z W, LIU H. Co-Ni₂P/SBA-15/cordierite monolithic catalysts: Preparation and performance for hydrodesulfurization of dibenzothiophene[J]. Chinese J. Inorg. Chem., 2012,28(3):565-571.
5. [5]
  CABRERA-MUNGUIA D, ROSALES-MARINES L, RUBIO-RIOS A, FARIAS-CEPEDA L, ROMERO-GALARZA A. Silicon Materials[M]. London: IntechOpen, 2019: 1-17
6. [6]
  XU H, JIANG W X, WANG D X, KANG X, SHAO L C, LIU J C, TIAN C G, FU H G. Controlling the growth of ZnNiMoS_x on biomass-derived porous carbon materials for deep hydrodesulfurization[J]. Appl. Catal. A-Gen., 2023,660119188. doi: 10.1016/j.apcata.2023.119188
7. [7]
  RYABOSHAPKA D, PICCOLO L, AOUINE M, BARGIELA P, BRIOIS V, AFANASIEV P. Ultradispersed (Co) Mo catalysts with high hydrodesulfurization activity[J]. Appl. Catal. B-Environ., 2022,302120831. doi: 10.1016/j.apcatb.2021.120831
8. [8]
  XU J S, SHI C X, XIAO Z R, GAO R J, LI Y T, ZHANG X W, PAN L, ZOU J J. Ni-modified MoS₂ nanoflake arrays with stepped sites on carbon nanotubes for efficient hydrodesulfurization of coal-to-liquid fuel[J]. Chem. Commun., 2020,56:5540-5543. doi: 10.1039/D0CC00960A
9. [9]
  LIANG J L, WU W J, WU M M, HUA J W, LIU Y Q, LIU C G. Green synthesis of mesoporous carbon supported (Ni) MoS₂ as efficient hydrodesulfurization catalyst[J]. Journal of Fuel Chemistry and Technology, 2023,51:1761-1771.
10. [10]
  LEE S Y, ARIS R. The distribution of active ingredients in supported catalysts prepared by impregnation[J]. Catal. Rev. Sci. Eng., 1985,27(2):207-340. doi: 10.1080/01614948508064737
11. [11]
  LIN Z H, ZHANG H H, HUANG C C, SUN R Q, WU X Y. Hydrothermal synthesis and crystal structure of H₁₀[NiMo₁₂^ⅤO₄₀{Ni (H₂O)₃}₄][J]. Chin. J. Struct. Chem., 2003,22(2):207-210.
12. [12]
  LIANG J L, WU M M, ZHANG Z H, WANG H, HUANG T T, ZHAO L, LIU Y Q, LIU C G. Constructing a superior Co-Mo HDS catalyst from a crystalline precursor separated from the impregnating solution[J]. Catal. Sci. Technol., 2022,12:2278-2288. doi: 10.1039/D2CY00083K
13. [13]
  LIANG J L, WU M M, WEI P H, ZHAO J C, HUANG H, LI C F, LU Y K, LIU Y Q, LIU C G. Efficient hydrodesulfurization catalysts derived from Strandberg PMoNi polyoxometalates[J]. J. Catal., 2018,358:155-167. doi: 10.1016/j.jcat.2017.11.026
14. [14]
  LIANG J L, WU M M, QI L, QIAN S, RUI H, LIU Y Q, LIU C G. The superior HDS catalyst derived from a new Waugh Co-Mo polyoxometalate via cationic substitution[J]. Fuel, 2024,360130597. doi: 10.1016/j.fuel.2023.130597
15. [15]
  QIU L M, XU G T. The application of X-ray photoelectron spectroscopy on refining catalyst[J]. Spectroscopy and Spectral Analysis, 2015,35(12):3514-3518.
16. [16]
  WANG Y, SUN Z C, WANG A J, RUAN L F, LU M H, REN J, LI X, LI C, HU Y K, YAO P J. Kinetics of hydrodesulfurization of dibenzothiophene catalyzed by sulfided Co-Mo/MCM-41[J]. Ind. Eng. Chem. Res., 2004,43:2326-2328.
17. [17]
  NASCIMENTO I G, LOCATEL W R, MAGALHAES B C, TRAVALLONI L, ZOTIN J L, DA SILVA M A P. Kinetics of dibenzothiophene hydrodesulfurization reactions using CoMoP/Al₂O₃ and NiMoP/Al₂O₃[J]. Catal. Today, 2021,381:200-208. doi: 10.1016/j.cattod.2020.07.013
18. [18]
  LIANG J L, FAN M W, WU M M, HUA J W, CAI W S, HUANG T T, LIU Y Q, LIU C G. In situ synthesis of MoS₂ nanoflakes within a 3D mesoporous carbon framework for hydrodesulfurization of DBT[J]. J. Catal., 2022,415:153-164. doi: 10.1016/j.jcat.2022.10.006
19. [19]
  LI Q Y, XIAO Z T, XIN H C, LI G C, WANG D, FENG C, LI X B, CHEN S, CHUNG K H. Enhancement of hydrotreating activity of oil-soluble CoMo6 heteropolyacid for 4, 6-dimethyldibenzothiophene and vacuum residue by controlling sulfurization degree[J]. Chem. Eng. J., 2023,472145128. doi: 10.1016/j.cej.2023.145128
20. [20]
  WEI J, HUANG H, LUO Q L, LIU N, WANG X Y, WANG X F, ZHONG M, HUANG X L. Synthesis of few layer amorphous 1T/2H MoS₂ by a one-step ethanol/water solvothermal method and its hydrodesulfurization performance[J]. Catal. Lett., 2022,152:263-275. doi: 10.1007/s10562-021-03621-9
21. [21]
  ZHOU W W, WEI Q, ZHOU Y F, LIU M F, DING S J, YANG Q. Hydrodesulfurization of 4, 6-dimethyldibenzothiophene over NiMo sulfide catalysts supported on meso-microporous Y zeolite with different mesopore sizes[J]. Appl. Catal. B-Environ., 2018,238:212-224. doi: 10.1016/j.apcatb.2018.07.042
22. [22]
  AMAYA S L, ALONSO-NUNEZ G, CRUZ-REYES J, FUENTES S, ECHARRIA A. Influence of the sulfidation temperature in a NiMoW catalyst derived from layered structure (NH₄) Ni₂OH (H₂O)(MoO₄)₂[J]. Fuel, 2015,139:575-583. doi: 10.1016/j.fuel.2014.09.046
23. [23]
  BAI Z, WANG L Y, CAO H W, ZHANG X W, LI G Z. Symbiosis of 1T and 2H phases in the basal plane of defective MoS₂ nanoflowers for efficient hydrodesulfurization[J]. Fuel, 2022,322124252. doi: 10.1016/j.fuel.2022.124252
24. [24]
  BAO W J, HUANG T T, WANG C Z, MA S Y, GUO H L, PAN Y, LIU Y Q, LIU C G, SUN D F, LU Y K. Controlled synthesis of efficient NiWS active phases derived from lacunary polyoxometalate and the application in hydrodesulfurization[J]. J. Catal., 2022,413:374-387. doi: 10.1016/j.jcat.2022.06.036
25. [25]
  HUANG T T, HE S S, CHANG J Y, XU J D, FAN Y. Preparation of a superior Co4Mo12/Al₂O₃ hydrodesulfurization catalyst by the hydrothermal deposition of heteropoly compounds on Al₂O₃[J]. Catal. Commun., 2019,122:68-72. doi: 10.1016/j.catcom.2019.01.021
26. [26]
  LIANG J L, WU W J, WU M M, HUA J W, LIU Y Q, LIU C G. Construction of hydrodesulfurization catalyst with Anderson structure Ni-Mo heteropolyacid molecules[J]. Petrochemical Technology, 2023,52(11):1505-1512.
27. [27]
  ZHAO P F, JI S F, WEI N, LIU H, LI C Y. Preparation, characterization and hydrodesulphurization catalytic performance of Al-Ni₂P/SBA-15 catalysts[J]. Chinese J. Inorg. Chem., 2010,26(12):2273-2279.
1. [1]
  Débora Ferreira dos Santos Morais , José Luis Tirado , Carlos Pérez-Vicente , Fabiana Villela da Motta , Pedro Lavela , Mauricio Bomio , Sergio Lavela . Unlocking the performance of sodium-ion batteries by coating Na₃V₂(PO₄)₃ with Nb₂O₅. Acta Physico-Chimica Sinica, 2026, 42(2): 100180-0. doi: 10.1016/j.actphy.2025.100180
2. [2]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
3. [3]
  Jia JI , Tengqi YAO , Wenqian DENG , Wenjing SHI , Xuan LÜ , Lin TIAN , Xiaoyan XIN , Yinling HOU . Structures, antibacterial activities, and interactions with DNA of two nickel complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 78-86. doi: 10.11862/CJIC.20250141
4. [4]
  Yachao HUANG , Chuanwang ZENG , Guiyong LIU , Jinming ZENG , Chao LIU , Xiaopeng QI . Oxygen vacancies and phosphorus doping enhanced metal-organic framework derived nitrogen-doped carbon-coated Co₃O₄ bifunctional electrocatalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2251-2260. doi: 10.11862/CJIC.20250133
5. [5]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
6. [6]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
7. [7]
  Xintong Zhu , Bin Cao , Chong Yan , Cheng Tang , Aibing Chen , Qiang Zhang . Advances in coating strategies for graphite anodes in lithium-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100096-0. doi: 10.1016/j.actphy.2025.100096
8. [8]
  Yuan GAO , Yiming LIU , Chunhui WANG , Zhe HAN , Chaoyue FAN , Jie QIU . A hexanuclear cerium oxo cluster stabilized by furoate: Synthesis, structure, and remarkable ability to scavenge hydroxyl radicals. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 491-498. doi: 10.11862/CJIC.20240271
9. [9]
  Xue Xiao , Jiachun Li , Xiangtong Meng , Jieshan Qiu . Sulfur-Doped Carbon-Coated Fe_0.95S_1.05 Nanospheres as Anodes for High-Performance Sodium Storage. Acta Physico-Chimica Sinica, 2024, 40(6): 2307006-0. doi: 10.3866/PKU.WHXB202307006
10. [10]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
11. [11]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
12. [12]
  Yixuan Wang , Canhui Zhang , Xingkun Wang , Jiarui Duan , Kecheng Tong , Shuixing Dai , Lei Chu , Minghua Huang . Engineering Carbon-Chainmail-Shell Coated Co₉Se₈ Nanoparticles as Efficient and Durable Catalysts in Seawater-Based Zn-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2305004-0. doi: 10.3866/PKU.WHXB202305004
13. [13]
  Chen Pu , Daijie Deng , Henan Li , Li Xu . Fe_0.64Ni_0.36@Fe₃NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability. Acta Physico-Chimica Sinica, 2024, 40(2): 2304021-0. doi: 10.3866/PKU.WHXB202304021
14. [14]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-0. doi: 10.3866/PKU.WHXB202407020
15. [15]
  Zhimin Sun , Wenyu Xue , Shuangshuang Yang , Chaoyang Zhang , Bo Yu , Xingwei Wang , Qiangliang Yu , Feng Zhou , Weimin Liu . Multifunctional coating for marine applications: simultaneously achieving corrosion resistance, microwave absorption, and drag reduction via fluorosilane-encapsulated CIPs. Acta Physico-Chimica Sinica, 2026, 42(11): 100292-0. doi: 10.1016/j.actphy.2026.100292
16. [16]
  Jiang Liu , Can Hu , Shunli Li . Design and practical exploration of teaching cases for metal-oxygen clusters: an introduction to the inorganic chemistry teaching case under the Chemistry “101 Plan”. University Chemistry, 2026, 41(6): 30-34. doi: 10.12461/PKU.DXHX202510023
17. [17]
  Ziliang KANG , Jiamin ZHANG , Hong AN , Xiaohua LIU , Yang CHEN , Jinping LI , Libo LI . Preparation and water adsorption properties of CaCl₂@MOF-808 in-situ composite moulded particles. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2133-2140. doi: 10.11862/CJIC.20240282
18. [18]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
19. [19]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
20. [20]
  Bo YAN , Wenjuan JI , Lu XU , Wenzhuang LEI , Haiying YANG , Yunlong FU . Highly sensitive electrochemical detection for 4-aminophenol based on pore-confined nitrogen-rich tetranuclear cobalt-oxo cluster metal-organic framework. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1175-1189. doi: 10.11862/CJIC.20250375

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(26)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142