Advanced Search

Citation: Mengxue WANG, Shan FAN, Wei DONG, Yichen REN, Yong ZHANG. Preparation and performance of Mo-doped MnO2 cathode materials for zinc-ion batteries[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(9): 2033-2040. doi: 10.11862/CJIC.20260111 shu

Preparation and performance of Mo-doped MnO2 cathode materials for zinc-ion batteries

  • College of Material Science and Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006, China

Figures(7)

  • The cathode material Mo-doped MnO2 (Mo-MnO2@CC) was prepared on carbon cloth (CC) by a one-step hydrothermal method. The effects of Mo doping on the lattice spacing of MnO2 and its implications for the insertion/exsertion of Zn2+ and the introduction of more active sites were confirmed by X-ray diffraction, X-ray photoelectron spectroscopy, and so on. The electrochemical performance of the material was significantly improved. When assembled into a button cell with Mo-MnO2@CC as the cathode material, it achieved an initial discharge capacity of 517.7 mAh·g-1 at a current density of 0.1 A·g-1. After 3 000 cycles at a current density of 1 A·g-1, the capacity retention rate of Mo-MnO2@CC still was 77.9%, demonstrating that Mo doping can enhance the specific capacity and cycling stability of the electrode.
  • 加载中
    1. [1]

      CHEN S Y, LIU Y B, CHEN W J, ZHAO X J, CHENG Z B, PAN X Y. Engineering stable amorphous-like MnO2 cathode via high-valent Mo6+ doping for aqueous zinc-ion batteries[J]. Appl. Mater. Today, 2025, 47: 102944  doi: 10.1016/j.apmt.2025.102944

    2. [2]

      BAATIYAH B, WUDIL Y S, GONDAL M A. Recent advances and challenges in MnO2-based composite cathodes for high-performance flexible zinc-ion batteries: A critical review[J]. J. Energy Storage, 2025, 125: 117000  doi: 10.1016/j.est.2025.117000

    3. [3]

      LIN G, LIU X C, YIN G L, XIAO S H. ZnCl2-induced surface texturing for long-cycling dendrite-free Zn anodes of aqueous zinc-ion batteries[J]. Colloids Surf. A‒Physicochem. Eng. Aspect., 2025, 726(P2): 137911

    4. [4]

      LI Y, LIU X X, JI T Y, ZHANG M, YAN X R, YAO M J, SHENG D W, LI S, LI S D, REN P P, SHEN Z X. Potassium ion doped manganese oxide nanoscrolls enhanced the performance of aqueous zinc-ion batteries[J]. Chin. Chem. Lett., 2025, 36(1): 109551  doi: 10.1016/j.cclet.2024.109551

    5. [5]

      SUN Y N, HUANG C J, LIU Y X, ZHAO X L, CAI K F. Poly(3, 4- ethylenedioxythiophene)-coated vanadium-doped MnO2 nanorods for high-performance flexible aqueous zinc-ion battery cathode[J]. ACS Appl. Mater. Interfaces, 2024, 16(39): 52373-52382  doi: 10.1021/acsami.4c10701

    6. [6]

      CHAN T T, LI X R, SHEN X X, DAI B B, XU Q J. Improving stability and reversibility of manganese dioxide cathode materials via nitrogen and sulfur doping for aqueous zinc-ion batteries[J]. J. Alloy. Compd., 2023, 943: 169068  doi: 10.1016/j.jallcom.2023.169068

    7. [7]

      XU J W, GAO Q L, XIA Y M, LIN X S, LIU W L, REN M M, KONG F G, WANG S J, LIN C. High-performance reversible aqueous zinc-ion battery based on iron-doped alpha-manganese dioxide coated by polypyrrole[J]. J. Colloid Interface Sci., 2021, 598: 419-429  doi: 10.1016/j.jcis.2021.04.057

    8. [8]

      LI X H, ZHOU Q C, YANG Z, ZHOU X, QIU D, QIU H J, HUANG X T, YU Y. Unraveling the Role of nitrogen-doped carbon nanowires incorporated with MnO2 nanosheets as high performance cathode for zinc-ion batteries[J]. Energy Environ. Mater., 2023, 6(3): e12378  doi: 10.1002/eem2.12378

    9. [9]

      LI Q G, WANG C, ZHU Y, DU W Z, LIU W X, YAO M, WANG Y Q, QIAN Y M, FENG S J. Unlocking the critical role of Mg doping in α-MnO2 cathode for aqueous zinc-ion batteries[J]. Chem. Eng. J., 2024, 485: 150077  doi: 10.1016/j.cej.2024.150077

    10. [10]

      ZHAO Z N, LI S, ZHAO B, ZHANG X L, WANG X Y, WEN Z S, JI S J, SUN J C. Joint influence of nitrogen doping and oxygen vacancy on manganese dioxide as a high-capacity cathode for zinc-ion batteries[J]. J. Phys. Chem. C, 2021, 125(37): 20195-20203  doi: 10.1021/acs.jpcc.1c05417

    11. [11]

      MA Q, CHEN J C, CHEN Y, LI Y, WU Q X, SUM B, GUO B S, YUAN Y K, LIAO W, WANG S L, MA Z Y, YU B. A review of energy storage mechanisms, modification strategies, and commercialization prospects of manganese dioxide cathodes in zinc-ion batteries[J]. J. Energy Storage, 2025, 132: 117869  doi: 10.1016/j.est.2025.117869

    12. [12]

      GOURLEY S W D, MILIANTE C M, IBARRA-ESPINOZ A, BAKER T, NOOR N, RUBEL O, ADAMS B D, HIGGINS D. The influence of nickel and alkali metal additives on manganese dioxide structure and performance for rechargeable zinc-ion batteries[J]. ACS Appl. Mater. Interfaces, 2025, 17(20): 29558-29569  doi: 10.1021/acsami.5c02907

    13. [13]

      LIU Y Q, HAN S G, LI X F, LUO Y H, WU Y B, LIN X M, ZHU Q L. Manganese dioxide cathode materials for aqueous zinc-ion battery: Development, challenges and strategies[J]. EnergyChem, 2025, 7(3): 100152  doi: 10.1016/j.enchem.2025.100152

    14. [14]

      LIU Y, LI Q P, ZHANG X Q, DONG Y X, CAO H, HUANG X M, LI Y X, ZHENG Q J, ZHAO J X, LIN D M. Tuning the distribution of zinc-ions by manganese dioxide ion sieve to realize the uniform deposition of zinc-ions on Zn metal anode of aqueous zinc-ion batteries[J]. Ceram. Int., 2023, 49(16): 27506-27513  doi: 10.1016/j.ceramint.2023.06.026

    15. [15]

      ZHANG Z N, LI S, ZHAO B, ZHANG X L, WANG X Y, WEN Z S, JI S J, SUN J C. Joint influence of nitrogen doping and oxygen vacancy on manganese dioxide as a high-capacity cathode for zinc-ion batteries[J]. J. Phys. Chem. C, 2021, 125(37): 20195-20203  doi: 10.1021/acs.jpcc.1c05417

    16. [16]

      LIU Y B, CHEN W J, SU J J, ZHAO X J, PAN X Y. Inhibition of phase transition from δ-MnO2 to α-MnO2 by Mo-doping and the application of Mo-doped MnO2 in aqueous zinc-ion batteries[J]. Phys. Chem. Chem. Phys., 2023, 25(44): 30663-30669  doi: 10.1039/D3CP04182D

    17. [17]

      LIU X, REN D S, HSU H J, FENG X N, XU G L, ZHUANG M H, GAO H, LU L G, HAN X B, CHU Z Y, LI J Q, HE X M, AMINE K, OUYANG M. Thermal runaway of lithium-ion batteries without internal short circuit[J]. Joule, 2018, 2(10): 2047-2064  doi: 10.1016/j.joule.2018.06.015

    18. [18]

      SONG A L, ZHAO J H, QIAO C T, DING Y L, TIAN G X, FAN Y Q, MA Z P, DAI L, SHAO G J, LIU Z P. High-capacity K⁺-pillared layered manganese dioxide as cathode material for high-rate aqueous zinc-ion battery[J]. J. Colloid Interface Sci., 2024, 674: 336-344  doi: 10.1016/j.jcis.2024.06.170

    19. [19]

      CHEN Q, LI J T, LIAO C, LIANG W L, LOU X, LIU Z, ZHANG J L, TANG Y P, MAI L Q, ZHOU L, AMINE K. High mass loading potassium ion stabilized manganese dioxide nanowire forests for rechargeable Zn batteries[J]. Nano Energy, 2024, 126: 109607  doi: 10.1016/j.nanoen.2024.109607

    20. [20]

      TU T C, CHEN L, LI L Y. The function of phenylphosphonic acid on diversifying the property of manganese dioxide applied in the aqueous zinc-ion battery[J]. Electrochim. Acta, 2024, 477: 143782  doi: 10.1016/j.electacta.2024.143782

    21. [21]

      REN Y J, ZHANG S W, YIN B S, LOH J R, DING Y X, HUANG X J, LI J Z, LI H, MA T Y. Boosting the stability of highly flexible cathodes in zinc-ion batteries via the pillaring effect of molybdenum in α-MnO2[J]. Batteries Supercaps, 2023, 6(7): e202300132  doi: 10.1002/batt.202300132

    22. [22]

      LIU Y, LI Q P, ZHANG X Q, DONG Y X, CAO H, HUANG X M, LI Y X, ZHENG Q J, ZHAO Q J, ZHAO J X, LIN D M. Tuning the distribution of zinc-ions by manganese dioxide ion sieve to realize the uniform deposition of zinc-ions on Zn metal anode of aqueous zinc-ion batteries[J]. Ceram. Int., 2023, 49(16): 27506-27513  doi: 10.1016/j.ceramint.2023.06.026

    23. [23]

      JIANG W W, WANG W, SHI H T, HU R Z, HONG J, TONG Y, MA J, LIANG C J, PENG J F, XU Z W. Homogeneous regulation of arranged polymorphic manganese dioxide nanocrystals as cathode materials for high-performance zinc-ion batteries[J]. J. Colloid Interface Sci., 2023, 647: 124-133  doi: 10.1016/j.jcis.2023.05.148

    24. [24]

      WU Y L, XU Z K, REN R Q, LI N, YANG J Y, ZHANG J Y, REN H, DONG S Y, DONG X C. Flexible ammonium-ion pouch cells based on a tunneled manganese dioxide cathode[J]. ACS Appl. Mater. Interfaces, 2023, 15(9): 12434-12442  doi: 10.1021/acsami.3c00146

    25. [25]

      CHAN T T, LI X R, SHEN X X, DAI B B, XU Q J. Improving stability and reversibility of manganese dioxide cathode materials via nitrogen and sulfur doping for aqueous zinc-ion batteries[J]. J. Alloy. Compd., 2023, 943: 169068  doi: 10.1016/j.jallcom.2023.169068

    26. [26]

      LI S, ZHANG J G, YAN Y Y, YU L L, ZHAO J T. Manganese valence state regulated β manganese dioxide porous nanoflowers as high-performance cathodes at large current densities for aqueous magnesium ions battery capacitor[J]. J. Energy Storage, 2023, 59: 106456  doi: 10.1016/j.est.2022.106456

    27. [27]

      LIANG Y X, KONG F G, WANG Z R, REN M M, CAI X X, LIU W L, YAO J S, ZHANG C B, ZHAO H. Long-term stable Zn metal anodes by electrodeposited manganese dioxide for aqueous rechargeable zinc-ion batteries[J]. J. Alloy. Compd., 2023, 936: 168378  doi: 10.1016/j.jallcom.2022.168378

    28. [28]

      DAI H H, ZHOU R C, ZHANG Z, ZHOU J Y, SUN G Z. Design of manganese dioxide for supercapacitors and zinc-ion batteries: Similarities and differences[J]. Energy Mater., 2022, 2(6): 200040  doi: 10.20517/energymater.2022.56

    29. [29]

      YADAV P, KUMARI N, RAI A K. A review on solutions to overcome the structural transformation of manganese dioxide‑based cathodes for aqueous rechargeable zinc-ion batteries[J]. J. Power Sources, 2023, 555: 232385  doi: 10.1016/j.jpowsour.2022.232385

    30. [30]

      NI Z J, LIANG X, ZHAO L M, ZHAO H, GE B, LI W Z. Tin doping manganese dioxide cathode materials with the improved stability for aqueous zinc-ion batteries[J]. Mater. Chem. Phys., 2022, 287: 126238  doi: 10.1016/j.matchemphys.2022.126238

    31. [31]

      CHONG S K, WU Y F, LIU C F, CHEN Y Z, GUO S W, LIU Y N, GUO G Z. Cryptomelane-type MnO2/carbon nanotube hybrids as bifunctional electrode material for high capacity potassium-ion full batteries[J]. Nano Energy, 2018, 54: 106-115  doi: 10.1016/j.nanoen.2018.09.072

    32. [32]

      HUANG J H, WANG Z, HOU M Y, DONG X L, LIU Y, WANG Y G, XIA Y Y. Polyaniline-intercalated manganese dioxide nanolayers as a high-performance cathode material for an aqueous zinc-ion battery[J]. Nat. Commun., 2018, 9: 2906  doi: 10.1038/s41467-018-04949-4

    33. [33]

      WANG Z. Production and performance research of δ-MnO2 cathodes for aqueous zinc-ion batteries[D]. Beijing: University of Science and Technology Beijing, 2025.

    34. [34]

      LIANG J R, ZHAO Y J, REN L T, LI M C, ZHANG Q L, WANG Y H, SUM X M, CHUAI M, WANG X S, LIU W. Dual anions doping enhanced conductivity and stability of layered δ-MnO2 cathode for aqueous zinc-ion battery[J]. Adv. Funct. Mater., 2025, 35(25): 2501135  doi: 10.1002/adfm.202501135

  • 加载中
    1. [1]

      Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO2 for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326

    2. [2]

      Xiaoying ZHENG , Shan FAN , Qinjin DAI , Wei DONG , Mengxue WANG , Yicheng REN , Yong ZHANG . Preparation of three-dimensional flower-like δ-MnO2 cathode materials and its aqueous zinc-ion battery performance. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 925-932. doi: 10.11862/CJIC.20250352

    3. [3]

      Yucheng Shan ,  Liming Xu ,  Peng Sun ,  Zhijing Zhu ,  Chenglong Wang ,  Jinliang Li ,  Guang Yang ,  Likun Pan . A data-driven approach for rapid revealing of metal doping in MnO2 cathodes for high-performance aqueous zinc-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(7): 100232-. doi: 10.1016/j.actphy.2025.100232

    4. [4]

      Li Peicai ,  Wang Xubin ,  Zhang Qinghua ,  Wang Bowen ,  Rong Xiaohui ,  Hu Yong-Sheng ,  Li Zhongtao . High-rate and long-cycling P2-type cathode material for sodium-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(5): 100214-. doi: 10.1016/j.actphy.2025.100214

    5. [5]

      Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS2 nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339

    6. [6]

      Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

    7. [7]

      Qiang Huang ,  Yue Wang ,  Xuejie Wang ,  Lyubov G. Bulusheva ,  Tao Liu . La-Ce双掺杂调控电子结构及离子传输增强Na4Fe3(PO4)2P2O7正极的超快储钠性能. Acta Physico-Chimica Sinica, 2026, 42(11): 100339-. doi: 10.1016/j.actphy.2026.100339

    8. [8]

      Qianli Ma , Tianbing Song , Tianle He , Xirong Zhang , Huanming Xiong . Sulfur-doped carbon dots: a novel bifunctional electrolyte additive for high-performance aqueous zinc-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100106-0. doi: 10.1016/j.actphy.2025.100106

    9. [9]

      Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-0. doi: 10.3866/PKU.WHXB202406014

    10. [10]

      Wang Shuang ,  Fu Xiaoqi ,  Yao Shanshan . Synergistic optimization of ion migration and electron transfer in sodium-ion battery cathode materials. Acta Physico-Chimica Sinica, 2026, 42(5): 100206-. doi: 10.1016/j.actphy.2025.100206

    11. [11]

      Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270

    12. [12]

      Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na3.5−xMn0.5V1.5−xZrx (PO4)3/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-0. doi: 10.3866/PKU.WHXB202407023

    13. [13]

      Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085

    14. [14]

      Lingbang Qiu , Jiangmin Jiang , Libo Wang , Lang Bai , Fei Zhou , Gaoyu Zhou , Quanchao Zhuang , Yanhua Cui . In Situ Electrochemical Impedance Spectroscopy Monitoring of the High-Temperature Double-Discharge Mechanism of Nb12WO33 Cathode Material for Long-Life Thermal Batteries. Acta Physico-Chimica Sinica, 2025, 41(5): 100040-0. doi: 10.1016/j.actphy.2024.100040

    15. [15]

      Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149

    16. [16]

      Ziying YUAN , Zhen DUAN , Dan LIU , Jingrui NIU , Feiyan LAI , Xiaohui ZHANG , Guangchang YANG . Modification of O3-type Na0.86Ni1/3Fe1/3Mn1/3O2 cathode material via Ti4+/P5+ dual-site co-doping. Chinese Journal of Inorganic Chemistry, 2026, 42(8): 1647-1657. doi: 10.11862/CJIC.20260041

    17. [17]

      Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368

    18. [18]

      Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252

    19. [19]

      Guangnan SHAN , Yuhui WANG , Yueru WU . Preparation and electrochemical performance of α-MnO2 electrode material for aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 479-487. doi: 10.11862/CJIC.20250292

    20. [20]

      Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-0. doi: 10.3866/PKU.WHXB202310034

Get Citation
PDF
XML
Metrics
  • PDF Downloads(2)
  • Abstract views(338)
  • HTML views(60)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return