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Citation: Mengxue WANG, Shan FAN, Wei DONG, Yichen REN, Yong ZHANG. Preparation and performance of Mo-doped MnO2 cathode materials for zinc-ion batteries[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(9): 2033-2040. doi: 10.11862/CJIC.20260111 shu

Preparation and performance of Mo-doped MnO2 cathode materials for zinc-ion batteries

  • College of Material Science and Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006, China

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  • The cathode material Mo-doped MnO2 (Mo-MnO2@CC) was prepared on carbon cloth (CC) by a one-step hydrothermal method. The effects of Mo doping on the lattice spacing of MnO2 and its implications for the insertion/exsertion of Zn2+ and the introduction of more active sites were confirmed by X-ray diffraction, X-ray photoelectron spectroscopy, and so on. The electrochemical performance of the material was significantly improved. When assembled into a button cell with Mo-MnO2@CC as the cathode material, it achieved an initial discharge capacity of 517.7 mAh·g-1 at a current density of 0.1 A·g-1. After 3 000 cycles at a current density of 1 A·g-1, the capacity retention rate of Mo-MnO2@CC still was 77.9%, demonstrating that Mo doping can enhance the specific capacity and cycling stability of the electrode.
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