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Citation: Jinyang SUI, Zhonghao NIU, Hao XU, Jingli XIE. Zinc(Ⅱ) coordination polymers from mixed triazole and carboxylate ligands: Synthesis and properties for CO2 cycloaddition and photocatalytic dye degradation[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(8): 1603-1612. doi: 10.11862/CJIC.20260089 shu

Zinc(Ⅱ) coordination polymers from mixed triazole and carboxylate ligands: Synthesis and properties for CO2 cycloaddition and photocatalytic dye degradation

  • College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China

  • Corresponding author: Jingli XIE, jlxie@mail.zjxu.edu.cn
  • Received Date: 17 March 2026
    Revised Date: 28 May 2026

Figures(9)

  • An acid-base mixed-ligand strategy was employed by combining basic ligand {2,6-bis[4-(1,2,4-triazol-1-yl)styryl]cyclohexanone} (BTBCH) with aromatic dicarboxylic acids such as terephthalic acid (H2BDC), isophthalic acid (IPA), and 5-methylisophthalic acid (MP), achieving three novel coordination polymers [Zn(BTBCH)2(BDC)]n (1), [Zn(BTBCH)2(IPA)]n (2), and [Zn(BTBCH)(MP)]n (3), respectively. Complexes 1 and 2 exhibit one-dimensional chain structural character, while 3 features a neatly packed two-dimensional network structure, forming tunnels. Under mild conditions, those materials exhibited considerable catalytic activity toward the CO2 cycloaddition reaction. Meanwhile, they could efficiently catalyze the photodegradation of organic dyes. Notably, they could be reused for several cycles.
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    1. [1]

      SHEN H L, LI R X, LIU W S, LIU W. Crystal structure analysis and solid-state fluorescence properties of novel Pb(Ⅱ) coordination polymers[J]. J. Mol. Struct., 2025: 143960

    2. [2]

      XIA L L, WANG Q Y, HU M. Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly[J]. Beilstein J. Nanotechnol., 2022, 13(1): 763-777

    3. [3]

      WANG P, OTAKE K, HIRAIDE S, KUBOTA Y, KAWAGUCHI S, KITAGAWA S. Flexible porous coordination polymer with multiple configurations for guest recognition and switchable CO2 sorption properties[J]. Chem. Lett., 2024, 53(7): 128  doi: 10.1093/chemle/upae128

    4. [4]

      LIU J Q, LUO Z D, PAN Y, SINGH A K, TRIVEDI M, KUMAR A. Recent developments in luminescent coordination polymers: Designing strategies, sensing application and theoretical evidences[J]. Coord. Chem. Rev., 2020, 406: 213145  doi: 10.1016/j.ccr.2019.213145

    5. [5]

      CAO Y H, CHEN X G, LI X, WANG B. Tuning surface functionalization and pore structure of UiO-66 metal-organic framework nanoparticles for organic pollutant elimination[J]. ACS Appl. Nano Mater., 2021, 4(5): 5486-5495  doi: 10.1021/acsanm.1c00796

    6. [6]

      SANZ-PÉREZ E S, MURDOCK C R, DIDAS S A, JONES C W. Direct capture of CO2 from ambient air[J]. Chem. Rev., 2016, 116(19): 11840-11876  doi: 10.1021/acs.chemrev.6b00173

    7. [7]

      WANG D Y, YAO H C, YE J S, GAO Y, CONG H L, YU B. Metal-organic frameworks (MOFs): Classification, synthesis, modification, and biomedical applications[J]. Small, 2024, 20(47): 2404350  doi: 10.1002/smll.202404350

    8. [8]

      ZHANG Y, MA D D, LI J, ZHI C Q, ZHANG Y M, LIANG L, MAO S M, SHI J W. Recent research advances of metal organic frameworks (MOFs) based composites for photocatalytic H2 evolution[J]. Coord. Chem. Rev., 2024, 517: 215995  doi: 10.1016/j.ccr.2024.215995

    9. [9]

      DOAN T D, VU N N, HOANG T L G, NGUYEN-TRI P. Metal-organic framework (MOF)-based materials for photocatalytic antibacterial applications[J]. Coord. Chem. Rev., 2025, 523: 216298  doi: 10.1016/j.ccr.2024.216298

    10. [10]

      ZHOU D Y Y, GUO X T, ZHANG Q Y, SHI Y X, ZHANG H B, YU C, PANG H. Nickel-based materials for advanced rechargeable batteries[J]. Adv. Funct. Mater., 2022, 32(12): 2107928  doi: 10.1002/adfm.202107928

    11. [11]

      XU X M, LIANG H Q, ROSAS-HERNANDEZ A, DAASBJERG K. Electrochemical valorization of captured CO2: Recent advances and future perspectives[J]. Chem. Soc. Rev., 2025, 54(3): 1216-1250  doi: 10.1039/D4CS00480A

    12. [12]

      OTHMAN F E C, YUSOF N, ISMAIL A F, RUSHDAN A L, LOW H Y. Electrospun graphene carbon nanofibers for CO2 capture and storage: A review[J]. J. Environ. Chem. Eng., 2024, 12(2): 112014  doi: 10.1016/j.jece.2024.112014

    13. [13]

      WANG P F, LI Y, SUN N R, HAN S B, WANG X M, SU Q Q, LI Y J, HE J, YU X H, DU S Y, FRANCISCO J S, ZHU J L, ZHAO Y S. Hydrate technologies for CO2 capture and sequestration: Status and perspectives[J]. Chem. Rev., 2024, 124(18): 10363-10385  doi: 10.1021/acs.chemrev.2c00777

    14. [14]

      MOUCTAR M H, HASSAN M G, BIMBO N, ABBAS S Z, SHIGIDI I. Comparative assessment and deployment of zeolites, MOFs, and activated carbons for CO2 capture and geological sequestration applications[J]. Inventions, 2025, 10(5): 78  doi: 10.3390/inventions10050078

    15. [15]

      LI L, LIN R B, KRISHNA R, LI H, XIANG S, WU H, LI J, ZHOU W, CHEN B. Ethane/ethylene separation in a metal-organic framework with iron-peroxo sites[J]. Science, 2018, 362(6413): 443-446  doi: 10.1126/science.aat0586

    16. [16]

      SHEN Y M, DUAN W L, SHI M. Chemical fixation of carbon dioxide co-catalyzed by a combination of Schiff bases or phenols and organic bases[J]. Eur. J. Org. Chem., 2004, 2004(14): 3080-3089  doi: 10.1002/ejoc.200400083

    17. [17]

      PRAMUDITA R A, MOTOKURA K. Transformative reduction of carbon dioxide through organocatalysis with silanes[J]. Green Chem., 2018, 20(21): 4834-4843  doi: 10.1039/C8GC02052C

    18. [18]

      GHOSH S, MODAK A, SAMANTA A, KOLE K, JANA S. Recent progress in materials development for CO2 conversion: Issues and challenges[J]. Mater. Adv., 2021, 2(10): 3161-3187  doi: 10.1039/D1MA00107H

    19. [19]

      MAHMOUDI F, BACHAS L G. Application of metal-organic framework-based composite materials for photodegradation of dye pollutants in wastewater[J]. Water, 2024, 16(21): 3051  doi: 10.3390/w16213051

    20. [20]

      CAO W W, MA Z L, TIAN L. A multifunctional cobalt(Ⅱ) metal-organic framework with nanoporous channels for gas and dye absorption, and magnetic performance[J]. Chem. Res. Chinese Universities, 2023, 39(6): 915-920  doi: 10.1007/s40242-022-2263-y

    21. [21]

      ANSARI A, HUSSAIN K, AMAN A, NAVEED T, HAIDER M S. Treatment of synthetic textile sewage containing anthraquinone and azo based disperse dyes using bacterial consortium[J]. Int. J. Environ. Sci. Technol., 2025, 22(15): 15577-15591  doi: 10.1007/s13762-025-06649-1

    22. [22]

      AMMAR A H, GOUDA M A, ROUSHDY N, FARAG A A M. Characterization and light-responsive behavior of anthraquinone azo-dye thin films for optoelectronic device applications[J]. J. Mol. Struct., 2025: 142443

    23. [23]

      CHENG L M, ZHANG J Y, ZHAN C H, XU H, GONG C H, XIE J L. Metal-organic frameworks constructed using acid-base mixed ligands, carboxylic acids and N-containing chalcone, and their catalytic performance for Knoevenagel condensation[J]. New J. Chem., 2024, 48(19): 8597-8602  doi: 10.1039/D3NJ05164A

    24. [24]

      SHE J H, GONG C H, SUI J Y, ZHANG J Y, SHI H J, XU H, XIE J L. Metal-organic frameworks constructed with base-acid mixed ligands and its potential as dual-functional fluorescent probe toward Fe3+/Al3+ ions[J]. Inorg. Chem. Commun., 2024, 165: 112507  doi: 10.1016/j.inoche.2024.112507

    25. [25]

      WANG W C, GONG C H, ZHANG J Y, BI Y F, XU H, XIE J L. Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed ligands and their catalytic properties for CO2 cycloaddition reaction[J]. Chinese J. Inorg. Chem., 2024, 40(7): 1377-1386

    26. [26]

      CAO Y Z, PAN W, ZHOU C J, ZHANG J Y, XU H, GONG C H, XU H T, SHEN R P, LIU S J, XIE J L. A series of metal-organic frameworks based on mixed ligand strategy: Synthesis, structures, and properties[J]. Chinese J. Inorg. Chem., 2022, 38(11): 2143-2153

    27. [27]

      PAN W, MA C X, ZHOU C J, ZHANG L, ZHANG J Y, SHI Y B, XU H, ZHU D R, XIE J L. Synthesis and characterization of metal-organic framework based on 2,6-bis(4-carboxybenzylidene)cyclohexanone[J]. Chinese J. Inorg. Chem., 2021, 37(5): 953-960

    28. [28]

      SHELDRICK G M. SHELXT-Integrated space-group and crystal-structure determination[J]. Found. Crystallogr., 2015, 71(1): 3-8  doi: 10.1107/S2053273314026370

    29. [29]

      THALLAPALLY P K, NANGIA A. A Cambridge structural database analysis of the C—H···Cl interaction: C—H···Cl— and C—H···Cl—M often behave as hydrogen bonds but C—H···Cl—C is generally a van der Waals interaction[J]. CrystEngComm, 2001, 3(27): 114-119  doi: 10.1039/B102780H

    30. [30]

      LI P Z, WANG X J, LIU J, LIM J S, ZOU R Q, ZHAO Y L. A triazole-containing metal-organic framework as a highly effective and substrate size-dependent catalyst for CO2 conversion[J]. J. Am. Chem. Soc., 2016, 138(7): 2142-2145  doi: 10.1021/jacs.5b13335

    31. [31]

      SUN Y X, JIA X M, HUANG H L, GUO X Y, QIAO Z H, ZHONG C L. Solvent-free mechanochemical route for the construction of ionic liquid and mixed-metal MOF composites for synergistic CO2 fixation[J]. J. Mater. Chem. A, 2020, 8(6): 3180-3185  doi: 10.1039/C9TA10409G

    32. [32]

      PARMAR B, PATEL P, KURESHY R I, KHAN N U H, SURESH E. Sustainable heterogeneous catalysts for CO2 utilization by using dual ligand ZnⅡ /CdⅡ metal-organic frameworks[J]. Chem. Eur. J., 2018, 24(59): 15831-15839  doi: 10.1002/chem.201802387

    33. [33]

      FEI Y, LEI Q J, FAN L M, HU T P, QIN Q P, ZHANG X T. Deciphering metal-ion effects on CO2-epoxide cycloaddition: A DFT study using designed 2D metal-organic framework[J]. J. Catal., 2025, 24: 116580

    34. [34]

      RAJESH D, THIRUMAVALAVAN E, NAGARAJA C M. Design of bifunctional zinc(Ⅱ)-organic framework for efficient coupling of CO2 with terminal/internal epoxides under mild conditions[J]. Cryst. Growth Des., 2021, 22(1): 598-607

    35. [35]

      LIU N N, LIU T T, LIU G N, MI X N, LI Y W, YANG L, ZHOU Z, WANG S N. Two isostructural Zn/Co-MOFs with penetrating structures: Multifunctional properties of both luminescence sensing and conversion of CO2 into cyclic carbonates[J]. Dalton Trans., 2024, 53(8): 3654-3665  doi: 10.1039/D3DT03466F

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