Citation: Min WANG, Dehua XIN, Guoqiang TAN, Xiaolu WU, Wei ZHANG, Tong CHANG, Lijuan JIA, Yuchun WANG, Zhaorong LIU. Construction and full-spectrum-driven photocatalytic antibiotics degradation performance of Z-scheme nitrogen vacancy g-C3N4/Ti3C2Tx/W18O49 heterojunction[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(8): 1613-1626. doi: 10.11862/CJIC.20260086 shu

Construction and full-spectrum-driven photocatalytic antibiotics degradation performance of Z-scheme nitrogen vacancy g-C3N4/Ti3C2Tx/W18O49 heterojunction

Figures(9)

  • A nitrogen vacancy g-C3N4 (NVCN), Ti3C2Tx (TCT), and W18O49 (WO) composite heterojunction material (CN/TCT/WO) was synthesized by in-situ solvothermal method. The phase composition, microstructure, optical and photoelectrochemical properties, and photocatalytic degradation performance were systematically characterized using various advanced techniques. The results showed that the CN/TCT/WO heterojunction exhibited full-solar-spectrum absorption characteristics owing to the defect-induced surface plasmon resonance effect. Furthermore, the formation of multi-level heterogeneous interfaces and defect-induced localized electromagnetic enhancement collectively improved the separation efficiency of photogenerated electron-hole pairs while prolonging their lifetime. The transformation from a type-Ⅱ heterostructure to a Z-scheme mechanism, with Ti3C2Tx as the electron mediator, enhanced the driving force for surface redox reactions. Hence, the ternary heterojunction possessed markedly boosted photocatalytic degradation performance compared with the single-component material and binary heterojunction. Within 40 min of visible light irradiation and 180 min of near-infrared light irradiation, the mineralization efficiencies by the optimal heterojunction material for tetracycline could reach 82.9% and 72.3%, respectively. In addition, ciprofloxacin, ofloxacin, norfloxacin, and metronidazole could also be efficiently decomposed and mineralized. The results of cyclic experiments indicated that the CN/TCT/WO heterojunction material possessed excellent structural stability and reusability.
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